Abstract
It is shown that the benzene ring is opened (via the scheme of the Beckmann rearrangement) during the nitrosation of 6-hydroxyquinoline and subsequent reaction with acylating agents; the products are β-(3-cyano-2-pyridyl)acrylic acids.
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See [1] for communication I.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 504–508, April. 1971.
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Kost, A.N., Zhukauskaite, L.N. & Stankevichus, A.P. Nitrosophenols and their rearrangement products. Chem Heterocycl Compd 7, 469–473 (1971). https://doi.org/10.1007/BF00471487
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DOI: https://doi.org/10.1007/BF00471487