Abstract
Sulfolanethiols, which were oxidized to 3,3′-disulfolanyl disulfide and 3,3′-bis(4-hydroxysulfolanyl) disulfide, were obtained by reaction of 3-sulfolene and 4-hydroxy-2-sulfolene with sodium hydrosulfide. Previously unknown cleavage of the sulfolanyl sulfides at the C-S bond of the sulfolane ring was observed during their oxidative chlorination and alkaline hydrolysis.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 188–191, February, 1975.
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Bezmenova, T.É., Varshavets, T.N. & Matyash, L.T. Synthesis and some properties of thiols, sulfides, and disulfides of the sulfolane series. Chem Heterocycl Compd 11, 159–162 (1975). https://doi.org/10.1007/BF00471388
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DOI: https://doi.org/10.1007/BF00471388