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1,2,4- and 1,2,5-oxadiazoles

1. Polarographic reduction of methyl- and phenyloxadiazoles in anhydrous dimethylformamide

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

It is shown that the first step in the reduction of the investigated oxadiazoles on a dropping mercury cathode in dimethylformamide corresponds to two-electron cleavage of the N-O bond. The degree of reduction is determined by the nature and position of the substituents in the oxadiazole ring and by the rate of protonation of the intermediately formed particles.

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Authors and Affiliations

  1. S. Ordzhonikidze All-Union Scientific-Research Pharmaceutical-Chemistry Institute, 119815, USSR

    I. G. Markova, M. K. Polievktov & S. D. Sokolov

Authors
  1. I. G. Markova
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  2. M. K. Polievktov
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  3. S. D. Sokolov
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 38–40, January, 1979.

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Markova, I.G., Polievktov, M.K. & Sokolov, S.D. 1,2,4- and 1,2,5-oxadiazoles. Chem Heterocycl Compd 15, 31–33 (1979). https://doi.org/10.1007/BF00471193

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  • DOI: https://doi.org/10.1007/BF00471193

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