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A study of furan compounds

XXXVI. Formation and hydrogenation of polyalkyl substituted 2-methoxy-1, 6-dioxaspiro [4.4]nonenes-3

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

This communication describes the electrolytic methoxylation of secondary and tertiary γ-furylalkanoles containing a methyl group in position 5 of the furan ring and also in certain cases the gem-dimethyl group at the first carbon atom from the ring in the side chain. During this process previously unknown derivations of 2-methyl-2-methoxy spirononenes were obtained. Catalytic hydrogenation of the latter at room temperature leads mainly to the formation of the corresponding spirononane and the tetrahydrofuranic ketone, which indicates that hydrogenolysis readily proceeds at the carbon-oxygen bonds.

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Authors and Affiliations

  1. Chernyshevskii Saratow State University, USSR

    A. A. Ponomarev, A. D. Peshekhonova & I. A. Markushina

Authors
  1. A. A. Ponomarev
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  2. A. D. Peshekhonova
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  3. I. A. Markushina
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Additional information

For part XXXV, see [1].

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Ponomarev, A.A., Peshekhonova, A.D. & Markushina, I.A. A study of furan compounds. Chem Heterocycl Compd 5, 296–299 (1969). https://doi.org/10.1007/BF00471128

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  • DOI: https://doi.org/10.1007/BF00471128

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