Abstract
The reaction of oxides (epichlorohydrin, glycidol methyl ether, and ethylene oxide) with oxazolid-2-one and 2-imino-5-methyloxazolidine has been studied. It has been established that the oxides add in position 3 of the oxazolidine ring with the formation of the corresponding S-(β-hydroxyalkyl) derivatives, the alkaline cleavage of which leads to mixed secondary amino alcohols.
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References
I. S. Matveev and A. E. Kretov, ZhOKh, 32, 3320, 1962.
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A. E. Kretov and I. S. Matveev, ZhOKh, 32, 471, 1962.
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Matveev, I.S. Synthesis of mixed secondary amino alcohols from oxazolidine derivatives. Chem Heterocycl Compd 5, 441–442 (1969). https://doi.org/10.1007/BF00470251
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DOI: https://doi.org/10.1007/BF00470251