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Conformational analysis of the stereoisomers of 3-methyl-2-oxo-2-thiabicyclo[4.4.0]decane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The conditions for the separation of the stereoisomeric sulfones and sulfoxides of 3-methyl-2-thiabicyclo[4.4.0]decane were found by means of capillary gas-liquid chromatography, and the relative thermodynamic stabilities of the latter were determined. The configuration of the stereoisomeric sulfoxides was established on the basis of oxidation data, the characteristics of the physicochemical properties, and the Kerr effect.

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    E. N. Karaulova, L. M. Petrova, G. D. Gal'pern & S. G. Vul'fson

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch of the Academy of Sciences of the USSR, USSR

    E. N. Karaulova, L. M. Petrova, G. D. Gal'pern & S. G. Vul'fson

Authors
  1. E. N. Karaulova
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  2. L. M. Petrova
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  3. G. D. Gal'pern
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  4. S. G. Vul'fson
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 621–624, May, 1976.

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Karaulova, E.N., Petrova, L.M., Gal'pern, G.D. et al. Conformational analysis of the stereoisomers of 3-methyl-2-oxo-2-thiabicyclo[4.4.0]decane. Chem Heterocycl Compd 12, 520–523 (1976). https://doi.org/10.1007/BF00470103

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  • DOI: https://doi.org/10.1007/BF00470103

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