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Regioselectivity of the allylation of benzothiophene

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The reaction of benzothiophene with allyl halides in the presence of silver trichloroacetate in chlorine-containing hydrocarbons was investigated. It was established by gas-liquid chromatography and 13C NMR and mass spectrometry that 3-allylbenzothiophene and diallylbenzothiophene are formed in this case. The 13C NMR spectra were interpreted on the basis of an additive scheme with the utilization of benzothiophene, thiophene, and 2- and 3-allylthiophenes as models.

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, 117234, Moscow

    A. V. Anisimov, Yu. N. Luzikov, V. M. Nikolaeva, Yu. N. Radyukin, É. A. Karakhanov & E. A. Viktorova

Authors
  1. A. V. Anisimov
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  2. Yu. N. Luzikov
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  3. V. M. Nikolaeva
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  4. Yu. N. Radyukin
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  5. É. A. Karakhanov
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  6. E. A. Viktorova
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1625–1627, December, 1977.

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Anisimov, A.V., Luzikov, Y.N., Nikolaeva, V.M. et al. Regioselectivity of the allylation of benzothiophene. Chem Heterocycl Compd 13, 1296–1298 (1977). https://doi.org/10.1007/BF00469887

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  • DOI: https://doi.org/10.1007/BF00469887

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