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Methanolysis and hydrolysis of derivatives of methyl 2,5- and 4,5-dihydrofuran-2-carboxylates

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Methyl 2,5-dimethoxy-2,5-dihydrofuran-2-carboxylate is formed in the reaction of HCl-CH3OH with methyl 5-nitro-2-acetoxy-2,5-, 5-nitro-4-acetoxy-4,5-, and 2,5-diacetoxy-2,5-dihydrofuran-2-carboxylates, whereas methyl 2,5-dioxo-3-pentenoate bis(2,4-dinitrophenylhydrazone) and 4-oxo-2-penten-1,5-dioic acid 2,4-dinitrophenylhydrazone are isolated in the presence of 2,4-dinitrophenylhydrazine. Methyl 5-nitrofuran-2-carboxylate is formed by treatment of methyl 5-nitro-2-acetoxy-2,5-dihydrofuran-2-carboxylate with aqueous solutions of acetic or phosphoric acid.

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Literature cited

  1. R. Marquis, Ann. Chim. Phys., 4, 196 (1905).

    Google Scholar 

  2. R. Kimura, Yakugaku Zasshi, 75, 1175 (1955).

    Google Scholar 

  3. N. Clauson-Kaas and J. Fakstorp, Acta Chem. Scand., 1, 210 (1947).

    Google Scholar 

  4. J. Srogl and J. Peterek, Coll. Czech. Chem. Commun., 31, 1578 (1966).

    Google Scholar 

  5. D. O. Lolya, K. K. Venter, É. É. Liepin'sh, and S. A. Giller, Khim. Geterotsikl. Soedin., No. 7, 883 (1975).

    Google Scholar 

  6. D. O. Lolya, K. K. Venter, and S. A. Giller, Izv. Akad. Nauk Latv. SSR, Ser. Khim., No. 4, 431 (1976).

    Google Scholar 

  7. N. Clauson-Kaas and F. Limborg, Acta Chem. Scand., 6, 551 (1952).

    Google Scholar 

  8. M. Murakami, S. Senoh, and Y. Hata, Mem. Inst. Sci. Ind. Res. Osaka Univ., 13, 173 (1956); Chem. Abstr., 51, 5745 (1957).

    Google Scholar 

  9. Y. Hachihama and T. Shono, Technol. Repts. Osaka Univ., 7, 177 (1957).

    Google Scholar 

  10. M. Marakami and K. Takaishi, Japanese Patent No. 9031 (1960); Chem. Abstr., 55, 9428 (1961).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, 226006, Riga

    D. O. Lolya & K. K. Venter

Authors
  1. D. O. Lolya
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  2. K. K. Venter
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1600–1603, December, 1977.

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Lolya, D.O., Venter, K.K. Methanolysis and hydrolysis of derivatives of methyl 2,5- and 4,5-dihydrofuran-2-carboxylates. Chem Heterocycl Compd 13, 1274–1277 (1977). https://doi.org/10.1007/BF00469879

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  • DOI: https://doi.org/10.1007/BF00469879

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