Skip to main content
Log in

Carbonization and graphitization of poly-p-phenylene sulphide (PPS) film

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Oriented poly-p-phenylene sulphide (PPS) films (thickness 12 and 75 μm) and PPS powder were carbonized/graphitized after stabilizing by oxidation, in order to examine the effect of sulphur on graphitizability of the resulting carbons. The films and the powder resulted in carbons with a high and a low graphitizability respectively. An “in-plane oriented structure” of the PPS film was the most predominant factor to lead to a high graphitizability, and sulphur in the precursor did not lower the graphitizability when it was subjected to solid-phase carbonization. These phenomena are discussed on the basis of analytical data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Burger, E. Fitzer, M. Heym and B. Terwiesch, Carbon 13 (1975) 149;

    Article  Google Scholar 

  2. Y. Hishiyama, S. Sanada, A. Yoshida and M. Inagaki, J. Mater. Sci. 23 (1988) 3272.

    Article  CAS  Google Scholar 

  3. M. Murakami, H. Yasujima, Y. Yumoto, S. Mizogami and S. Yoshimura, Solid State Commun. 45 (1983) 1085.

    Article  CAS  Google Scholar 

  4. T. Ohnishi, I. Murase, T. Noguchi and M. Hirooka, Synth. Met. 14 (1986) 207.

    Article  CAS  Google Scholar 

  5. J. I. Kipling, P. V. Shooter and R. N. Young, Carbon 4 (1966) 333.

    Article  CAS  Google Scholar 

  6. S. Otani and A. Oya, Kogyo Kagaku Zasshi 73 (1979) 493.

    Article  Google Scholar 

  7. E. Fitzer and S. Weisenburger, Carbon 14 (1976) 195.

    Article  CAS  Google Scholar 

  8. B. J. Tabor, E. P. Magre and J. Boon, Euro. Polymer J. 7 (1971) 1127.

    Article  CAS  Google Scholar 

  9. F. Tuinstra and J. L. Koenig, J. Chem. Phys. 53 (1970) 1126.

    Article  CAS  Google Scholar 

  10. G. F. L. Ehlers, K. R. Fisch and W. R. Powell, J. Polym. Sci. A-1 7 (1969) 2955.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Oya, A., Arai, K. & Fujita, K. Carbonization and graphitization of poly-p-phenylene sulphide (PPS) film. Journal of Materials Science 29, 4477–4480 (1994). https://doi.org/10.1007/BF00376269

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00376269

Keywords

Navigation