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Influnce of pH on the sorption of cadmium ions on calcium hydroxyapatite

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Abstract

Sorption of cadmium ions from aqueous solutions on calcium hydroxyapatite was studied as a function of pH. The concentration of cadmium, [Cd]s, in the solid increases with pH. The total mean concentration of cations of the solid increases with pH even without cadmium, but this effect is increased in the presence of cadmium. The composition tends to the stoichiometric value of 20 eq. cations/mol apatite for the highest pH and [Cd]s values. The sorption of cadium is therefore controlled by two processes: cationic exchange and protonation-deprotonation.

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References

  1. T. Miyahara, M. Miyakoshi, Y. Saito and H. Kozuka, Toxicol. Appl. Pharmacol. 55 (1980) 477.

    Article  CAS  Google Scholar 

  2. J. Christoffersen, M. R. Christoffersen, R. Larsen, E. Rostrup, P. Tingsgaard, O. Andersen and P. Grandjean, Calcif. Tissue Int. 42 (1988) 331.

    Article  CAS  Google Scholar 

  3. A. Bigi, M. Gazzano, A. Ripamonti, E. Foresti and N. Roveri, J. Chem. Dalton Trans. (1986) 241.

  4. A. Panda and B. Sahu, J. Mater. Sci. Lett. 10 (1991) 638.

    Article  CAS  Google Scholar 

  5. A. Nounah, J. Szylagyi and J. L. Lacout, Ann. Chim. Fr. 15 (1990) 409.

    CAS  Google Scholar 

  6. A. Nounah, J. L. Lacout and J. M. Savariault, J. Alloys Compounds 186 (1992) 141.

    Article  Google Scholar 

  7. P. P. Mahapatra, D. S. Sarangi and B. Mishra, Indian J. Chem. 32A (1993) 525.

    CAS  Google Scholar 

  8. T. Suzuki, T. Hatsushika and Y. Hayakawa, J. Chem. Soc. Farad. Trans. I 77 (1981) 1059.

    Article  CAS  Google Scholar 

  9. T. Suzuki, K. Ischigaki and M. Miyake, ibid. 78 (1982) 3605.

    Article  CAS  Google Scholar 

  10. Idem, ibid. 80 (1984) 3157.

    Article  CAS  Google Scholar 

  11. T. Suzuki, K. Ischigaki and N. Ayuzawa, Chem. Eng. Commun. 34 (1985) 143.

    Article  CAS  Google Scholar 

  12. Y. Takeuchi, T. Suzuki and H. Arai, J. Chem. Eng. Jpn 21 (1988) 98.

    Article  CAS  Google Scholar 

  13. Y. Takeuchi and H. Arai, ibid. 23 (1990) 75.

    Article  CAS  Google Scholar 

  14. T. Suzuki, T. Hatsushika and M. Miyake, “New Developments in Ion Exchange”, Proceedings of the International Conference on Ion Exchange, ICIE'91, Tokyo, Japan, 2–4 October 1991, edited by M. Abe, T. Kataoka and T. Suzuki (Kodansha, Tokyo and Elsevier, Amsterdam, 1991) p. 401.

    Google Scholar 

  15. J. J. Middelburg and R. N. J. Comans, Chem. Geol. 90 (1991) 45.

    Article  Google Scholar 

  16. U. Vincent, J. Jeanjean and M. Fedoroff, J. Solid State Chem. 108 (1994) 68.

    Article  Google Scholar 

  17. Y. Xu, F. W. Schwartz and S. J. Traina, Environ. Sci. Technol 28 (1994) 1472.

    Article  CAS  Google Scholar 

  18. W. R. Busing, K. O. Martin and H. A. Levy, ‘A Cristallographic Least Squares Program,” ORFLS AFFINE (1984).

  19. Idem, “A Cristallographic Function and Error Program”, ORFFE, report ORNL, TM306 (1964).

  20. C. A. Beevers and D. B. Mcintyre, Miner. Mag. 27 (1945) 254.

    Google Scholar 

  21. J. M. Hughes, M. Cameron and K. D. Crowley, Am. Mineral. 74 (1989) 870.

    CAS  Google Scholar 

  22. M. I. Kay, R. A. Young and A. S. Posner, Nature 204 (1964) 1050.

    Article  CAS  Google Scholar 

  23. J. C. Trombe, Ann. Chim. Fr. 8 (1973) 251.

    CAS  Google Scholar 

  24. J. C. Trombe and G. Montel, J. Inorg. Nucl. Chem. 40 (1978) 15.

    Article  CAS  Google Scholar 

  25. G. R. Fisher, P. Bardhan and J. E. Geiger, J. Mater. Sci. Lett. 2 (1983) 577.

    Article  Google Scholar 

  26. A. S. Posner, A. Perloff and A. F. Diorio, Acta Crystallogr. 11 (1958) 308.

    Article  CAS  Google Scholar 

  27. R. W. G. Wyckoff, “Crystal Structures”, Vol. 3 (Wiley, New York, 1964) p. 232.

    Google Scholar 

  28. E. E. Berry, J. Inorg. Nucl. Chem. 29 (1967) 1585.

    Article  CAS  Google Scholar 

  29. L. Winand, Ann. Chim. Fr. 562 (1961) 941.

    Google Scholar 

  30. R. Zapanta-Legeros, Nature 206 (1965) 403.

    Article  CAS  Google Scholar 

  31. B. O. Fowler, Inorg. Chem. 13 (1974) 194.

    Article  CAS  Google Scholar 

  32. Idem, ibid. 13 (1974) 207.

    Article  CAS  Google Scholar 

  33. E. E. Berry, J. Inorg. Nucl. Chem. 29 (1967) 317.

    Article  CAS  Google Scholar 

  34. I. Petrov, B. Soptrajanov, N. Fuson and J. R. Lawson, Spectrochim. Acta 23A (1967) 2637.

    Article  Google Scholar 

  35. T. M. Gregory, E. C. Moreno and W. E. Brown, J. Res. Nat. Bur. Stand. A Phys. Chem. 74A (1970) 461.

    Article  Google Scholar 

  36. H. McDowell, T. M. Gregory and W. E. Brown, ibid. 81A (1977) 273.

    Article  CAS  Google Scholar 

  37. R. M. H. Verbeek, H. Steyaer, H. P. Thun and F. Verbeek, J. Chem. Soc. Farad. Trans. I 76 (1980) 209.

    Article  CAS  Google Scholar 

  38. J. Kragten, “Atlas of Metal-Ligand Equilibria in Aqueous Solution” (Ellis Horwood, Chichester, 1978).

    Google Scholar 

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Authors and Affiliations

  1. Centre National de la Recherche Scientifique, Centre d'Etudes de Chimie Métallurgique, 15 rue Georges Urbain, 94407, Vitry-sur-Seine, France

    J. Jeanjean, M. Fedoroff, F. Faverjon & U. Vincent

  2. Centre National de la Recherche Scientifique, Laboratoire de Spectrométrie Infra-Rouge et Raman, 2 rue Henri Dunant, 94320, Thiais, France

    J. Corset

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  1. J. Jeanjean
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  2. M. Fedoroff
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Jeanjean, J., Fedoroff, M., Faverjon, F. et al. Influnce of pH on the sorption of cadmium ions on calcium hydroxyapatite. Journal of Materials Science 30, 6156–6160 (1995). https://doi.org/10.1007/BF00369662

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