Skip to main content
Log in

Gelatin layers for holographic purposes: an X-ray diffraction study

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

In order to overcome uniformity problems in large u.v. holoconcentrators recorded in dichromated gelatin, the structure of hardened gelatin layers has been studied. X-ray diffraction patterns show that layers are formed by individual gelatin chains partly associated as triple-stranded helical rods as those found in native collagen. These rods, in turn, may form fibrillar aggregates. Helical rods and microfibrils are, to a great extent, parallel to the layer surface and their relative amount and packing depend on the hardener as well as on temperature and drying time after coating. X-ray diffraction offers the possibility of estimating in a simple manner the relative amount of triple-helical rods in crystallographic register within the gelatin layers. From these results, a method for obtaining uniform large holograms by means of a slow layer drying process is proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Crespo, M. Pardo, M. A. Satorre and J. A. Quintana, Appl. Opt. 32 (1993) 3068.

    Article  CAS  Google Scholar 

  2. M. Djabourov, J. Leblond and P. Papon, J. Phys. France 49 (1988) 319.

    Article  CAS  Google Scholar 

  3. Yu. B. Melnichenko, Yu. P. Gomza, V. V. Shilov and S. I. Osipov, Polym. Int. 25 (1991) 153.

    Article  CAS  Google Scholar 

  4. S. B. Ross-Murphy, Polymer 33 (1992) 2622.

    Article  CAS  Google Scholar 

  5. J. E. Jolley, Photogr. Sci. Engng. 14 (1970) 3068.

    Google Scholar 

  6. I. Pezron, M. Djabourov, L. Bosio and J. Leblond, J. Polym. Sci. part B: Polym. Phys. 28 (1990) 1823.

    Article  CAS  Google Scholar 

  7. P. G. Boj, J. Crespo, M. A. Satorre and J. A. Quintana, Appl. Opt. 33 (1994) 2917.

    Article  CAS  Google Scholar 

  8. B. J. Chang and C. D. Leonard, ibid. 18 (1979) 2407.

    Article  CAS  Google Scholar 

  9. M. A. Rougvie and R. S. Bear, J. Amer. Leather Chem. Assoc. 48 (1953) 735.

    CAS  Google Scholar 

  10. G. N. Ramachandran, in “Treatise in collagen”, Vol. 1, edited by G. N. Ramachandran (Academic Press, London, 1967) Ch. 3.

    Google Scholar 

  11. I. V. Yannas, J. Macromol. Sci.-Revs. Macromol. Chem. C7 (1972) 49.

    Article  Google Scholar 

  12. A. Miller, Trends Biochem. Sci. 7 (1982) 13.

    Article  Google Scholar 

  13. D. J. S. Mulmes, Proc. Natl. Acad. Sci. USA 78 (1981) 3567.

    Article  Google Scholar 

  14. I. Tomka, J. Photogr. Sci. 23 (1975) 97.

    Article  Google Scholar 

  15. G. C. Wrighton and H. K. Herglotz, ibid. 28 (1980) 49.

    Article  CAS  Google Scholar 

  16. E. Bradbury and C. Martin, Proc. Roy. Soc. (London) Ser. A 214 (1952) 183.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Crespo, J., Satorre, M.A., Quintana, J.A. et al. Gelatin layers for holographic purposes: an X-ray diffraction study. Journal of Materials Science 30, 6145–6150 (1995). https://doi.org/10.1007/BF00369660

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00369660

Keywords

Navigation