Abstract
Yield behaviour of metal injection moulding (MIM) feedstocks was studied using a cone and plate controlled stress rheometer. Four feedstocks consisting of 58 vol % carbonyl iron (with 2 wt % nickel) in different ethylene vinyl acetate (EVA):beeswax ratio binder systems were studied at six temperatures ranging from 130 to 180‡C. The yield stress was found by extrapolating to zero shear rate of the measured data obtained using a controlled stress rheometer over low shear rate regime. The yield stress, ρy, was found to increase with decreasing temperature. An Arrhenius equation was used to relate the dependence of yield stress on temperature and the corresponding activation energy for yield, E y, can be determined. For a given temperature, feedstocks with higher EVA content exhibited higher Τy and E y. Moreover, the effect of temperature on yield stress was found to be greater for feedstocks with higher EVA content.
Similar content being viewed by others
References
R. A. PETT, V. D. N. RAO and S. B. A. QADERI, US Patent 4 158 689 (1979).
R. D. RIVERS, US Patent 4 113 480 (1978).
R. E. WIECH Jr, US Patent 4 197 118 (1980).
Idem, US Patent 4 415 528 (1983).
K. P. JOHNSON, US Patent 4 765 950 (1988).
R. L. BILLIET, US Patent 4 795 598 (1989).
Y. KIYOTA, US Patent 4 867 943 (1989).
T. NAGAI, H. YAMANASHI and H. HACHIMORI, US Patent 4 898 902 (1990).
M. NAKANISHI and T. MIHO, US Patent 4 968 739 (1990).
C. A. SUNDBACK, B. E. NOVICH, A. E. KARAS and R. W. ADAMS, US Patent 5 047 182 (1991).
R. M. German, “Powder Injection Molding” (Metal Powders Industries Federation, NJ, 1990) p. 176.
M. J. Edirisinghe and J. R. G. Evans, J. Mater. Sci. 22 (1987) 269.
R. M. German, “Powder Injection Molding” (Metal Powders Industries Federation, NJ, 1990) p. 160.
Idem, ibid. p. 158, 173, 231.
B.O. RHEE, PhD thesis, Renssalaer Polytechnic Institute (1992).
E. Windhab, “Proceedings of the Tenth International Congress on Rheology, Sydney”, edited by P. H. T. Uhlherr (Society of Rheology, Sydney, 1988) p. 372.
Q. D. Nguyen and D. V. Boger, Ann. Rev. Fluid Mech. 24 (1992) 47.
J. P. Harnett and R. Y. Z. Hu, J. Rheol. 33(4) (1989) 671.
D. D. Kee and C. F. Chan Man Fong, J. Rheol. 37(4) (1993) 775.
D. D. Kee and C. J. Durning, in “Polymer Rheology and Processing”, edited by A. A. Collyer and L. A. Utracki (Elsevier Science Publishers, England, 1990) p. 177.
Q. D. Nguyen and D. V. Boger, J. Rheol. 29(3) (1985) 335.
Idem, ibid. 27(4) (1983) 321.
D. M. Kalyon, P. Yaras, B. Aral and U. Yilmazer, ibid. 37(1) (1993) 35.
L. Bohlin, in “Proceedings of the Tenth International Congress on Rheology, Sydney”, edited by P. H. T. Uhlherr (Society of Rheology, Sydney, 1988) p. 191.
P. J. Hansen and M. C. Williams, Polym. Eng. Sci. 27(8) (1987) 586.
A. Magnin and J. M. Piau, J. Non-Newtonian Fluid Mech. 36 (1990) 85.
Idem, ibid. 23 (1987) 91.
A. S. Yoshimura, R. K. Prud'homme and H. M. Princen, J. Rheol. 31(8) (1987) 699.
E. C. Bingham, “Fluidity and Plasticity” (McGraw-Hill, New York, 1922).
W. H. Herschel and R. Bulkley, Proc. ASTM 26 (1926) 621.
W. Casson, in “Rheology of Dispersed Systems”, edited by C. C. Mill (Pergamon, London, 1959) p. 84.
M. Henderson, IEEE Electrical Insulation Mag. 9(1) (1993) 30.
B. O. Rhee and C. I. Chung, “Proceedings of the Fourth APP Annual Meeting” (Metal Powders Industries Fed., NJ, 1990).
C. I. Chung, M. Y. Cao and B. O. Rhee, ibid.“.
“Instruction Manual for the Carri-Med CSL Controlled Stress Rheometer”, edited by CarriMed Ltd, UK.
D. M. Husband, N. Aksel and W. Gieissle, J. Rheol. 37(2) (1993) 215.
N. Ohl and W. Gleissle, ibid. 37(2) (1993) 381.
A. Y. Malkin, Adv. Polym. Sci. 96 (1990) 70.
H. Tanaka and J. L. White, J. Non-Newtonian Fluid Mech. 7 (1980) 333.
Idem, Polym. Eng. Sci. 20(14) (1980) 949.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Foong, M.L., Tam, K.C. & Loh, N.H. Yield stress behaviour of metal injection moulding suspensions at elevated temperatures. JOURNAL OF MATERIALS SCIENCE 30, 3625–3632 (1995). https://doi.org/10.1007/BF00351876
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00351876