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Influence of annealing on microstructure and hydrogen storage properties of V48Fe12Ti15Cr25 alloy

  • Long Luo
  • Xuan Bian
  • Wen-yuan WuEmail author
  • Ze-ming Yuan
  • Yong-zhi Li
  • Ting-ting Zhai
  • Feng Hu
Original Paper
  • 18 Downloads

Abstract

V48Fe12Ti15Cr25 alloy was prepared using vacuum arc melting and was subsequently annealed for 10 h at 1273 K. The effects of annealing on the hydrogen storage properties and microstructure of the V48Fe12Ti15Cr25 alloys were investigated. The results indicated that the alloy consisted of main body-centered cubic, Ti-rich, and TiFe phases. After annealing, the kinetic properties of the alloy were improved but its hydrogen storage capacity was slightly reduced. The kinetic mechanisms of the hydrogen absorption and desorption of the alloys were studied. The dehydrogenation enthalpy of the alloy was decreased by 2.57 kJ/mol after annealing. Differential scanning calorimetry indicated that the hydride decomposition temperature of the annealed alloy was decreased. The hydrogen desorption activation energies of the as-cast and annealed alloys were calculated to be 79.41 and 71.25 kJ/mol, respectively. The results illustrated that annealing was a beneficial method of improving the kinetic and thermodynamic properties of the hydrogen absorption/desorption of the alloy.

Keywords

V-based solid solution alloy Annealing Microstructure Hydrogen storage Kinetic mechanism 

Notes

Acknowledgements

This study was funded by the National Natural Science Foundation of China (Grant No. 51901105) and Natural Science Foundation of Inner Mongolia, China (Grant Nos. 2018LH05010, 2019BS05005, and 2017BS0507).

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Copyright information

© China Iron and Steel Research Institute Group 2019

Authors and Affiliations

  • Long Luo
    • 1
    • 2
  • Xuan Bian
    • 1
  • Wen-yuan Wu
    • 1
    Email author
  • Ze-ming Yuan
    • 2
  • Yong-zhi Li
    • 2
  • Ting-ting Zhai
    • 2
  • Feng Hu
    • 2
  1. 1.School of MetallurgyNortheastern UniversityShenyangChina
  2. 2.Analytical and Testing CenterInner Mongolia University of Science and TechnologyBaotouChina

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