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Topics in Current Chemistry

, 376:39 | Cite as

Cross-Dehydrogenative C–H/S–H Coupling Reactions

  • Akram Hosseinian
  • Sheida Ahmadi
  • Fatemeh Alsadat Hosseini Nasab
  • Robab Mohammadi
  • Esmail Vessally
Review
  • 180 Downloads

Abstract

Carbon–sulfur bond formation represents a key step in the synthesis of thioethers, which are a common structural motif in many pharmaceutically compounds. The direct cross-dehydrogenative coupling of C–H/S–H bonds has become a powerful tool for C–S bond formation. As these coupling reactions avoid pre-functionalization of the starting materials, they are more atom-economical, practical, and environmentally friendly than traditional cross-coupling reactions. In this review, we will highlight the most important developments in this novel and interesting research arena with the emphasis on the mechanistic aspects of the reactions. The review is divided into three major sections: (1) C(sp3)-H/S–H bonds coupling reactions; (2) C(sp2)-H/S–H bonds coupling reactions; and (3) C(sp)-H/S–H bonds coupling reactions.

Keywords

Cross-dehydrogenative couplings Sulfenylation Thioethers Thiol C–H bond S–H bond Catalyst 

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Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  • Akram Hosseinian
    • 1
  • Sheida Ahmadi
    • 2
  • Fatemeh Alsadat Hosseini Nasab
    • 3
  • Robab Mohammadi
    • 2
  • Esmail Vessally
    • 2
  1. 1.School of Engineering Science, College of EngineeringUniversity of TehranTehranIran
  2. 2.Department of ChemistryPayame Noor UniversityTehranIran
  3. 3.Department of ChemistryHormozgan UniversityBandar AbbasIran

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