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Recent advances in selective C-C bond coupling for ethanol upgrading over balanced Lewis acid-base catalysts

  • Jingjing Dai (戴菁菁)
  • Hongbo Zhang (张洪波)Email author
Reviews Special Issue: Celebrating the 100th Anniversary of Nankai University
  • 26 Downloads

Abstract

Ethanol is a considerable platform molecule in biomass conversion, which could be acquired in quantity through acetone-butanol-ethanol (ABE) fermentation. People have been working on the upgrading of ethanol to value added chemicals for decades. In the meantime, 1-butanol and a series of value added products have been selectively generated through C-C bond coupling. In this mini-review, we focus on the recent advances in selective C-C bond formation over balanced Lewis acid-base catalysts such as modified metal oxide, mixed metal oxide, hydroxyapatite and zeolite confined transition metal oxide catalysts. Among them, Pd-MgAlOx and Sr-based hydroxyapatite exhibit >70% 1-butanol selectivity, while ZnxZryOz and Ta-SiBEA zeolite achieve >80% of isobutene and butadiene selectivity respectively. The mechanism and reaction pathway of C-C bond formation in each reaction system are described in detail. The correlation between C-C bond coupling and the acidity/basicity of the Lewis acid-base pairs from the surface of the catalysts are also discussed.

Keywords

balanced Lewis acid-base pair aldol condensation ethanol upgrading C-C bond formation metal oxide 

平衡Lewis酸碱催化剂催化乙醇转化形成C-C键的 最新进展

摘要

乙醇是生物质转化过程中重要的平台分子, 可以通过ABE (丙酮-丁醇-乙醇)发酵过程大量获得. 近几十年来, 人们一直致力 于将乙醇升级为高附加值化学品. 通过C-C键生成过程, 选择性地 生成了1-丁醇和一系列高附加值产品. 本文总结了近年来在平衡 Lewis酸碱催化剂上选择性生成C-C键的研究进展, 包括金属氧化 物催化剂、混合金属氧化物催化剂、羟基磷灰石和沸石分子筛限 域过渡金属氧化物催化剂. 其中Pd-MgAlOx和Sr基羟基磷灰石催化 剂对应1-丁醇的选择性>70%, ZnxZryOz和Ta-SiBEA沸石对异丁烯 和丁二烯的选择性>80%. 本文详细介绍了各反应体系中C-C键形 成的机理和反应路径, 并讨论了C–C键生成与催化剂表面Lewis 酸、碱强度的关系.

Notes

Acknowledgements

The work was supported by the “111 Project” of China (B18030) and Nankai University.

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Jingjing Dai (戴菁菁)
    • 1
  • Hongbo Zhang (张洪波)
    • 1
    Email author
  1. 1.School of Materials Science and Engineering & National Institute for Advanced MaterialsNankai UniversityTianjinChina

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