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Microporous polymer based on hexaazatriphenylene-fused triptycene for CO2 capture and conversion

  • Hui Ma (马辉)
  • Zhen Wang (王震)
  • Yu-Hang Zhao (赵宇航)
  • Qiang Ou (欧强)
  • Bien Tan (谭必恩)
  • Chun Zhang (张春)Email author
Articles
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Abstract

Chemical conversion of carbon dioxide (CO2) to value-added useful chemicals like cyclic carbonates represents one potential solution to climate warming. Here, a kind of porous organic polymer (HAT-TP) with large surface area and excellent carbon dioxide uptake capacity is prepared via a condensation reaction to introduce hexaazatriphenylene (HAT) units into triptycene (TP)-based microporous polymer. HAT-TP can coordinate with zinc ions, and the resulting polymer (Zn/HAT-TP) can be utilized as an efficient recyclable catalyst for chemical conversion of CO2 into cyclic carbonates with epoxides.

Keywords

microporous polymer CO2 capture CO2 conversion triptycene hexaazatriphenylene 

六氮杂苯并菲扩环三蝶烯微孔聚合物的合成及其 在二氧化碳捕获与催化转化领域的应用

摘要

作为二氧化碳化学转化的研究热点, 利用二氧化碳作为原料 合成有机小分子化合物被认为是解决温室效应的有效途径之一. 本文合成了一种基于六氮杂苯并菲扩环三蝶烯的有机微孔聚合物 (HAT-TP). 该多孔聚合物表现出较高比表面积以及较好的二氧化 碳吸附性能力. 通过与锌离子配位, Zn/HAT-TP聚合物还能够作为 一类良好的非均相催化剂催化二氧化碳与环氧化物反应生成对应 的环状碳酸酯.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21875079 and 21672078). We thank the Analytical and Testing Center of Huazhong University of Science and Technology for related analysis. We also thank Dr. Yu Yao and Wuhan National High Magnetic Field Center for analysis of solid-state NMR.

Author contributions

Zhang C and Ma H conceived, coordinated the research, and designed the experiments. Zhang C acquired funding. Ma H conducted all experiments, analyzed the data and wrote the manuscript. Zhang C supervised the whole project. All the authors participated in discussions of the research.

Supplementary material

40843_2019_1196_MOESM1_ESM.pdf (1.1 mb)
Microporous polymer based on hexaazatriphenylene-fused triptycene for CO2 capture and conversion

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Hui Ma (马辉)
    • 1
  • Zhen Wang (王震)
    • 1
  • Yu-Hang Zhao (赵宇航)
    • 1
  • Qiang Ou (欧强)
    • 1
  • Bien Tan (谭必恩)
    • 2
  • Chun Zhang (张春)
    • 1
    Email author
  1. 1.College of Life Science and Technology, National Engineering Research Center for NanomedicineHuazhong University of Science and TechnologyWuhanChina
  2. 2.School of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhanChina

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