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Science China Materials

, Volume 62, Issue 12, pp 1821–1830 | Cite as

Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis

  • Xiao-Xue Wang (王晓雪)
  • Xiao-Bao Li (李小宝)
  • Chun-Li Hu (胡春丽)
  • Fang Kong (孔芳)Email author
  • Jiang-Gao Mao (毛江高)Email author
Articles
  • 62 Downloads

Abstract

Explorations of new second harmonic generation materials in Ag+-Hg2+/Bi3+-selenites systems afforded three new silver selenium oxides, namely, Ag4Hg(SeO3)2(SeO4) (1), Ag2Bi2(SeO3)3(SeO4) (2) and Ag5Bi(SeO3)4 (3). They exhibit flexible crystal chemistry. Compounds 1 and 2 are mixed valence selenium oxides containing Se(IV) and Se(VI) cations simultaneously. Compounds 1 and 3 exhibit a 3D open framework with 4-, 6- and 8-member polyhedral ring tunnels along a, b and c axes. Compound 1 crystallized in a polar space group and could display a subtle frequency doubling efficiency about 35% of the commercial KH2PO4 (KDP). UV-vis-NIR spectra reveal that compounds 1–3 are wide-band semiconductors with the optical bandgaps of 3.11, 3.65, 3.58 eV respectively. Theoretical calculations disclose that compounds 2 and 3 are indirect band gap structures and their bandgaps are determined by Ag, Bi, Se and O atoms together.

Keywords

SHG material in situ synthesis mixed valence selenium oxide selenite 

Ag4Hg(SeO3)2(SeO4): 原位合成法制备的混价硒氧化物类新型倍频材料

摘要

我们在Ag+-Hg2+/Bi3+-SeO32−体系探索合成新型非线性光学材料时获得了三例结构新颖的银硒氧化物: Ag4Hg(SeO3)2(SeO4)(1), Ag2Bi2(SeO3)3(SeO4) (2) 和 Ag5Bi(SeO3)4 (3). 它们展现了丰富的晶体化学: 1和2 为同时含六价和四价硒的混价氧化物; 1和3为在a, bc轴含四, 六或八元环孔道的三维开放式骨架结构; 1结晶于非心和极性空间群, 并且可以显示出明显的倍频信号, 约为商用KDP的35%. 紫外漫反射光谱表明这三例化合物均为宽带隙半导体, 其光学带隙分别为3.11, 3.65和3.58 eV. 理论计算发现材料. 2和3为间接带隙半导体, 其带隙是由Ag, Bi, Se和O原子共同决定的.

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21773244 and 21875248), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB20000000), and the Natural Science Foundation of Fujian Province (2018J01025).

Conflict of interest The authors declare that they have no conflict of interest.

Supplementary material

40843_2019_1193_MOESM1_ESM.pdf (29.4 mb)
Ag4Hg(SeO3)2(SeO4): A Novel SHG Material Created in Mixed Valent Selenium Oxides by In Situ Synthesis

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Xiao-Xue Wang (王晓雪)
    • 1
    • 2
  • Xiao-Bao Li (李小宝)
    • 1
    • 2
  • Chun-Li Hu (胡春丽)
    • 2
  • Fang Kong (孔芳)
    • 2
    Email author
  • Jiang-Gao Mao (毛江高)
    • 2
    Email author
  1. 1.College of ChemistryFuzhou UniversityFuzhouChina
  2. 2.State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhouChina

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