Ba4M(CO3)2(BO3)2 (M=Ba, Sr): two borate-carbonates synthesized by open high temperature solution method

  • Xueyan Zhang (张雪艳)
  • Hongping Wu (吴红萍)
  • Hongwei Yu (俞洪伟)
  • Zhihua Yang (杨志华)
  • Shilie Pan (潘世烈)Email author


Two borate-carbonates Ba4M(CO3)2(BO3)2 (M = Ba, Sr) have been successfully synthesized in the open air representing the first examples of borate-carbnate complex. Their structures were determined by single crystal X-ray diffraction and they both crystallize in same space group, Pnma. Their structures feature a Ba/Sr-based three dimensional framework composed of the BaO8 polyhedra (the SrO8 polyhedra), isolated BO3 and CO3 triangles. Detailed structure analysis shows that the intergrowth of [Ba3(BO3)2]/[Ba2Sr(BO3)2] and [BaCO3] layers favors the formation of these two borate-carbonates. In addition, their syntheses, spectroscopic properties and thermal behaviors were investigated.


borate-carbonates open air intergrowth 

Ba4M(CO3)2(BO3)2 (M=Ba, Sr): 在开放体系下通过高温溶液法合成两种硼酸-碳酸盐


本文中, 我们成功合成了两种复合的硼酸-碳酸盐Ba4M(CO3)2(BO3)2 (M = Ba, Sr). 这是第一例在开放体系下合成的硼酸-碳酸盐. 它们的结构由单晶X射线衍射确定, 结晶在相同的Pnma空间群. 它们的晶体结构是由BaO8多面体(SrO8多面体), 孤立的BO3和CO3三角形组成的三维网络结构. 通过详细的结构分析表明共生长的[Ba3(BO3)2]/[Ba2Sr(BO3)2]和[BaCO3]层是有利于这两种硼酸-碳酸盐的合成的. 此外, 还研究了它们的合成、 光谱性质和热行为.



This work was supported by the Key Research Project of Frontier Science of CAS (QYZDB-SSW-JSC049), the Western Light Foundation of CAS (2016-QNXZ-A-2), Xinjiang International Science & Technology Cooperation Program (2017E01014).

Supplementary material

40843_2018_9390_MOESM1_ESM.pdf (646 kb)
Ba4M(CO3)2(BO3)2 (M = Ba, Sr): Two Borate-carbonates Synthesized by Open High Temperature Solution Method


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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Xueyan Zhang (张雪艳)
    • 1
    • 2
  • Hongping Wu (吴红萍)
    • 1
    • 2
  • Hongwei Yu (俞洪伟)
    • 1
    • 2
  • Zhihua Yang (杨志华)
    • 1
    • 2
  • Shilie Pan (潘世烈)
    • 1
    • 2
    Email author
  1. 1.CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & ChemistryCASUrumqiChina
  2. 2.Xinjiang Key Laboratory of Electronic Information Materials and DevicesUrumqiChina

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