Studies on the Thoria Fuel Recycling Loop Using Triflic Acid: Effects of Powder Characteristics, Solution Acidity, and Radium Behavior
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A convenient recycling loop is one of the key factors that will help to implement the thorium-based nuclear fuel cycle in the future. Herein, a study is presented concerning the recycling loop of thoria production scrap using dissolution with trifluoromethanesulfonic (triflic) acid and recovery by precipitation with oxalic acid. The kinetics of thoria powders and pellet dissolution was assessed and compared with the THOREX process. The effect of the triflic acid concentration on the recovery yield of thorium during oxalate precipitation was examined, as well as the behavior of radium during this reaction. Finally, the effect of the triflic acid concentration on the recovered thoria morphology was investigated. The triflic acid has minimal effect on the recovery yield during oxalate precipitation even in the case of high acid concentrations. In general, the solubility of radium(II) oxalate is higher than for thorium(IV) and has a maximum at a triflic acid solution of 4 M. An interesting observation was that a stable dihydrate of thorium(IV) oxalate is formed in solution of high triflic acid concentration. It might be explained by the hygroscopic medium during precipitation of the oxalate. All above mentioned observations confirm the benefits of usage of the triflic acid-based closed recycling loop for thorium dioxide-based nuclear fuel.
KeywordsNuclear fuel Radium Solvometallurgy Scrap Thoria Triflic acid
The authors are grateful to Peter Dries and Koen Vanaken (SCK·CEN) for assistance in the laboratory. The authors are also grateful to Lesley Adriaensen and Magda Ooms for the gamma spectroscopy measurements and Andrew Dobney and Prisca Verheyen for the ICP-MS. The supply of thorium(IV) nitrate solution by the company Solvay S.A. is gratefully acknowledged.
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Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
- 1.IAEA-TECDOC-1115 (1999) Minimization of waste from uranium purification, enrichment and fuel fabrication, ViennaGoogle Scholar
- 5.Lyczko K, Lyczko M, Herdzik I, Zielinska B (2011) Method of dissolution of thorium oxide. E.P. Office (ed) European Patent Office, EP2397443A3Google Scholar
- 16.Kurnakova AG, Shubochkin LK (1963) Solubility of Th(C2O4)2·6H2O in aqueous HNO3 and H2C2O4 at 25 °C. Russ J Inorg Chem 8:647–650Google Scholar
- 17.Pazhukhin EM, Smirnova EA, Krivokhatskii AS, Pazukhina YL, Kochergin SM (1985) Optimization of conditions of thorium oxalate precipitation. I. Solubility of thorium oxalate in the presence of like ions. Sov Radiochem 27:606–611Google Scholar
- 21.Horlait D, Clavier N, Dacheux N, Cavalier R, Podor R (2012) Synthesis and characterization of Th(1−x)Ln(x)O(2-x/2) mixed-oxides. Mater Res Bull 47:4017–4025. https://doi.org/10.1016/j.materresbull.2012.08.068 CrossRefGoogle Scholar
- 23.Kirgintsev AN, Nikashina TA (1966) Solubility of barium and strontium oxalates in nitric acid. Russ J Inorg Chem 11:1191–1193Google Scholar