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Squid By-product Gelatin Polymer as an Eco-friendly Corrosion Inhibitor for Carbon Steel in 0.5 M H2SO4 Solution: Experimental, Theoretical, and Monte Carlo Simulation Studies

  • Ahmed A. FaragEmail author
  • Amr S. Ismail
  • M. A. Migahed
Article
  • 12 Downloads

Abstract

A squid by-product (SBP) gelatinous protein polymer has been extracted, characterized, and examined as eco-friendly inhibitor for carbon steel in 0.5 M H2SO4 media by weight loss and electrochemical techniques. It was found that the SBP acts as a good corrosion inhibitor. The inhibition efficiency increases with increasing inhibitor concentration, but the temperature has hardly affected on the inhibition efficiency of SBP. Thermodynamic data clearly show that the adsorption mechanism of SBP on the carbon steel surface in 0.5 M H2SO4 solution is mainly physical adsorption. Moreover, the adsorption of the SBP molecules was found to follow a Langmuir adsorption isotherm. Results of potentiodynamic polarization measurements revealed that the SBP acts as mixed-type inhibitor. Data obtained from electrochemical impedance spectroscopy studies were analyzed to model inhibition process through appropriate equivalent circuit model. Theoretical parameters derived from quantum chemical calculations as well as binding energy derived from molecular dynamics simulation studies adequately corroborate the trend of experimental inhibition efficiencies of the studied inhibitors.

Keywords

Carbon steel Eco-friendly inhibitor Adsorption Weight loss EIS Quantum chemical calculations Molecular dynamics simulations 

Notes

Acknowledgements

The authors are greatly thankful to the Egyptian Petroleum Research Institute (EPRI) for fund and support.

References

  1. 1.
    Pakiet M et al (2018) Influence of different counterions on gemini surfactants with polyamine platform as corrosion inhibitors for stainless steel AISI 304 in 3 M HCl. J Mol Liq 268:824–831CrossRefGoogle Scholar
  2. 2.
    Kaczerewska O et al (2018) Effectiveness of O-bridged cationic gemini surfactants as corrosion inhibitors for stainless steel in 3 M HCl: experimental and theoretical studies. J Mol Liq 249:1113–1124CrossRefGoogle Scholar
  3. 3.
    Odewunmi NA, Umoren SA, Gasem ZM (2015) Watermelon waste products as green corrosion inhibitors for mild steel in HCl solution. J Environ Chem Eng 3(1):286–296CrossRefGoogle Scholar
  4. 4.
    Behzadi H, Forghani A (2017) Correlation between electronic parameters and corrosion inhibition of benzothiazole derivatives—NMR parameters as important and neglected descriptors. J Mol Struct 1131:163–170CrossRefGoogle Scholar
  5. 5.
    Li X, Deng S, Fu H, Xie X (2014) Synergistic inhibition effects of bamboo leaf extract/major components and iodide ion on the corrosion of steel in H3PO4 solution. Corros Sci 78:29–42CrossRefGoogle Scholar
  6. 6.
    Li X, Deng S, Fu H (2010) Adsorption and inhibition effect of vanillin on cold rolled steel in 30 M H3PO4. Prog Org Coat 67(4):420–426CrossRefGoogle Scholar
  7. 7.
    Cui M et al (2018) Novel nitrogen doped carbon dots for corrosion inhibition of carbon steel in 1 M HCl solution. Appl Surf Sci 443:145–156CrossRefGoogle Scholar
  8. 8.
    Alvarez PE et al (2018) Rollinia occidentalis extract as green corrosion inhibitor for carbon steel in HCl solution. J Ind Eng Chem 58:92–99CrossRefGoogle Scholar
  9. 9.
    Farag AA, Ismail AS, Migahed MA (2018) Environmental-friendly shrimp waste protein corrosion inhibitor for carbon steel in 1 M HCl solution. Egypt J Pet.  https://doi.org/10.1016/j.ejpe.2018.05.001 CrossRefGoogle Scholar
  10. 10.
    Mohamed HA, Farag AA, Badran BM (2010) Friendly to environment heterocyclic adducts as corrosion inhibitors for steel in water-borne paints. J Appl Polym Sci 117:1270–1278Google Scholar
  11. 11.
    Mohamed HA, Farag AA, Badran BM (2008) Corrosion inhibition of mild steel using emulsified thiazole adduct in different binder systems. Eurasian Chem 10(1):67–77Google Scholar
  12. 12.
    Haldhar R, Prasad D, Saxena A (2018) Myristica fragrans extract as an eco-friendly corrosion inhibitor for mild steel in 05 M H2SO4 solution. J Environ Chem Eng 6(2):2290–2301CrossRefGoogle Scholar
  13. 13.
    Saxena A et al (2018) Use of Sida cordifolia extract as green corrosion inhibitor for mild steel in 05 M H2SO4. J Environ Chem Eng 6(1):694–700CrossRefGoogle Scholar
  14. 14.
    Hooshmand Zaferani S et al (2013) Application of eco-friendly products as corrosion inhibitors for metals in acid pickling processes—a review. J Environ Chem Eng 1(4):652–657CrossRefGoogle Scholar
  15. 15.
    Saxena A, Prasad D, Haldhar R (2018) Investigation of corrosion inhibition effect and adsorption activities of Cuscuta reflexa extract for mild steel in 05 M H2SO4. Bioelectrochemistry 124:156–164CrossRefGoogle Scholar
  16. 16.
    Zhang K et al (2018) Amino acids modified konjac glucomannan as green corrosion inhibitors for mild steel in HCl solution. Carbohydr Polym 181:191–199CrossRefGoogle Scholar
  17. 17.
    Liu H et al (2019) Effects of hairy crab breeding on drinking water quality in a shallow lake. Sci Total Environ 662:48–56CrossRefGoogle Scholar
  18. 18.
    Alemán A et al (2011) Squid gelatin hydrolysates with antihypertensive, anticancer and antioxidant activity. Food Res Int 44(4):1044–1051CrossRefGoogle Scholar
  19. 19.
    Alemán A et al (2011) Contribution of Leu and Hyp residues to antioxidant and ACE-inhibitory activities of peptide sequences isolated from squid gelatin hydrolysate. Food Chem 125(2):334–341CrossRefGoogle Scholar
  20. 20.
    Bang JH, Lee EJ (2019) Differences in crab burrowing and halophyte growth by habitat types in a Korean salt marsh. Ecol Indic 98:599–607CrossRefGoogle Scholar
  21. 21.
    Parlapani FF et al (2019) Bacterial communities and potential spoilage markers of whole blue crab (Callinectes sapidus) stored under commercial simulated conditions. Food Microbiol.  https://doi.org/10.1016/j.fm.2019.03.011 CrossRefGoogle Scholar
  22. 22.
    Noll L, Zhang S, Wanek W (2019) Novel high-throughput approach to determine key processes of soil organic nitrogen cycling: gross protein depolymerization and microbial amino acid uptake. Soil Biol Biochem 130:73–81CrossRefGoogle Scholar
  23. 23.
    ASTM International (1999) Standard practice for preparing, cleaning, and evaluating corrosion test. Significance 90(Reapproved 2011):1–9Google Scholar
  24. 24.
    Hamdi M et al (2017) Chitin extraction from blue crab (Portunus segnis) and shrimp (Penaeus kerathurus) shells using digestive alkaline proteases from P. segnis viscera. Int J Biol Macromol 101:455–463CrossRefGoogle Scholar
  25. 25.
    Shahidi F, Synowiecki J (1991) Isolation and characterization of nutrients and value-added products from snow crab (Chinoecetes opilio) and shrimp (Pandalus borealis) processing discards. J Agric Food Chem 39(8):1527–1532CrossRefGoogle Scholar
  26. 26.
    Chan-Higuera JE et al (2016) Squid by-product gelatines: effect on oxidative stress biomarkers in healthy rats. Czech J Food Sci 34(2):105–110CrossRefGoogle Scholar
  27. 27.
    Nekrasov AN et al (2019) A minimum set of stable blocks for rational design of polypeptide chains. Biochimie 160:88–92CrossRefGoogle Scholar
  28. 28.
    Pal PD, Dongre PM, Chitre AV (2018) Volume exclusion influences in spectral characteristics of DNA–amino acids complexes. Vib Spectrosc 99:137–145CrossRefGoogle Scholar
  29. 29.
    Barth A (2001) The infrared absorption of amino acid side chains. Prog Biophys Mol Biol 74:141–173CrossRefGoogle Scholar
  30. 30.
    Liu J et al (2018) The effects of nitrogen and water stresses on the nitrogen-to-protein conversion factor of winter wheat. Agric Water Manag 210:217–223CrossRefGoogle Scholar
  31. 31.
    Li L et al (2015) The discussion of descriptors for the QSAR model and molecular dynamics simulation of benzimidazole derivatives as corrosion inhibitors. Corros Sci 99:76–88CrossRefGoogle Scholar
  32. 32.
    Al-Moubaraki AH et al (2017) Role of aqueous extract of celery (Apium graveolens L.) seeds against the corrosion of aluminium/sodium hydroxide systems. J Environ Chem Eng 5(5):4194–4205CrossRefGoogle Scholar
  33. 33.
    Hamani H et al (2017) 1-(4-Nitrophenylo-imino)-1-(phenylhydrazono)-propan-2-one as corrosion inhibitor for mild steel in 1 M HCl solution: weight loss, electrochemical, thermodynamic and quantum chemical studies. J Electroanal Chem 801:425–438CrossRefGoogle Scholar
  34. 34.
    Gürten AA et al (2015) The effect of temperature and concentration on the inhibition of acid corrosion of carbon steel by newly synthesized Schiff base. J Ind Eng Chem 27:68–78CrossRefGoogle Scholar
  35. 35.
    Mall ID et al (2005) Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses. Colloids Surf A 264(1):17–28CrossRefGoogle Scholar
  36. 36.
    Dkhireche N et al (2010) Corrosion and scale inhibition of low carbon steel in cooling water system by 2-propargyl-5-o-hydroxyphenyltetrazole. Mater Chem Phys 122:1–9CrossRefGoogle Scholar
  37. 37.
    Moschona A et al (2018) Corrosion protection of carbon steel by tetraphosphonates of systematically different molecular size. Corros Sci 145(October):135–150CrossRefGoogle Scholar
  38. 38.
    Zhang QB, Hua YX (2009) Corrosion inhibition of mild steel by alkylimidazolium ionic liquids in hydrochloric acid. Electrochim Acta 54(6):1881–1887CrossRefGoogle Scholar
  39. 39.
    Saranya J et al (2016) N-heterocycles as corrosion inhibitors for mild steel in acid medium. J Mol Liq 216:42–52CrossRefGoogle Scholar
  40. 40.
    Tourabi M et al (2013) Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole. Corros Sci 75:123–133CrossRefGoogle Scholar
  41. 41.
    Olasunkanmi LO, Sebona MF, Ebenso EE (2017) Influence of 6-phenyl-3(2H)-pyridazinone and 3-chloro-6-phenylpyrazine on mild steel corrosion in 05 M HCl medium: experimental and theoretical studies. J Mol Struct 1149:549–559CrossRefGoogle Scholar
  42. 42.
    Farsak M, Keleş H, Keleş M (2015) A new corrosion inhibitor for protection of low carbon steel in HCl solution. Corros Sci 98:223–232CrossRefGoogle Scholar
  43. 43.
    Rugmini Ammal P, Prajila M, Joseph A (2018) Effect of substitution and temperature on the corrosion inhibition properties of benzimidazole bearing 1, 3, 4-oxadiazoles for mild steel in sulphuric acid: physicochemical and theoretical studies. J Environ Chem Eng 6(1):1072–1085CrossRefGoogle Scholar
  44. 44.
    Finšgar M, Jackson J (2014) Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: a review. Corros Sci 86(Supplement C):17–41CrossRefGoogle Scholar
  45. 45.
    Li X, Deng S, Fu H (2012) Inhibition of the corrosion of steel in HCl, H2SO4 solutions by bamboo leaf extract. Corros Sci 62:163–175CrossRefGoogle Scholar
  46. 46.
    Qu Q et al (2008) Synergistic inhibition between dodecylamine and potassium iodide on the corrosion of cold rolled steel in 0 1 M phosphoric acid. Mater Corros 59(11):883–888CrossRefGoogle Scholar
  47. 47.
    Szauer T, Brandt A (1981) Adsorption of oleates of various amines on iron in acidic solution. Electrochim Acta 26(9):1253–1256CrossRefGoogle Scholar
  48. 48.
    Satapathy AK et al (2009) Corrosion inhibition by Justicia gendarussa plant extract in hydrochloric acid solution. Corros Sci 51(12):2848–2856CrossRefGoogle Scholar
  49. 49.
    Salhi A et al (2017) Keto-enol heterocycles as new compounds of corrosion inhibitors for carbon steel in 1 M HCl: weight loss, electrochemical and quantum chemical investigation. J Mol Liq 248:340–349CrossRefGoogle Scholar
  50. 50.
    Fernandes CM et al (2019) Green synthesis of 1-benzyl-4-phenyl-1H-1,2,3-triazole, its application as corrosion inhibitor for mild steel in acidic medium and new approach of classical electrochemical analyses. Corros Sci.  https://doi.org/10.1016/j.corsci.2019.01.019 CrossRefGoogle Scholar
  51. 51.
    Aljourani J, Raeissi K, Golozar MA (2009) Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1 M HCl solution. Corros Sci 51(8):1836–1843CrossRefGoogle Scholar
  52. 52.
    Fadhil AA et al (2019) (S)-6-phenyl-2, 3, 5, 6-tetrahydroimidazo[2,1-b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: gravimetrical, electrochemical, surface morphology and theoretical simulation. J Mol Liq 276:503–518CrossRefGoogle Scholar
  53. 53.
    Cao C (1996) On electrochemical techniques for interface inhibitor research. Corros Sci 38:2073–2082CrossRefGoogle Scholar
  54. 54.
    Riggs OL Jr, Nathan CC (1973) Corrosion inhibitors. CC Nathan, HoustonGoogle Scholar
  55. 55.
    Elemike EE et al (2017) Synthesis, structures, spectral properties and DFT quantum chemical calculations of (E)-4-(((4-propylphenyl)imino)methyl)phenol and (E)-4-((2-tolylimino)methyl)phenol; their corrosion inhibition studies of mild steel in aqueous HCl. J Mol Struct 1141:12–22CrossRefGoogle Scholar
  56. 56.
    Bayol E et al (2008) Interactions of some Schiff base compounds with mild steel surface in hydrochloric acid solution. Mater Chem Phys 112(2):624–630CrossRefGoogle Scholar
  57. 57.
    Elbelghiti M et al (2016) Experimental, quantum chemical and Monte Carlo simulation studies of 3, 5-disubstituted-4-amino-1, 2, 4-triazoles as corrosion inhibitors on mild steel in acidic medium. J Mol Liq 218:281–293CrossRefGoogle Scholar
  58. 58.
    Migahed MA et al (2011) Synthesis of a new family of Schiff base nonionic surfactants and evaluation of their corrosion inhibition effect on X-65 type tubing steel in deep oil wells formation water. Mater Chem Phys.  https://doi.org/10.1016/j.matchemphys.2010.08.082 CrossRefGoogle Scholar
  59. 59.
    Han P et al (2018) Synergistic effect of mixing cationic and nonionic surfactants on corrosion inhibition of mild steel in HCl: experimental and theoretical investigations. J Colloid Interface Sci 516:398–406CrossRefGoogle Scholar
  60. 60.
    Verma C et al (2015) Aryl sulfonamidomethylphosphonates as new class of green corrosion inhibitors for mild steel in 1 M HCl: electrochemical, surface and quantum chemical investigation. J Mol Liq 209:306–319CrossRefGoogle Scholar
  61. 61.
    Saha SK et al (2016) Novel Schiff-base molecules as efficient corrosion inhibitors for mild steel surface in 1 M HCl medium: experimental and theoretical approach. Phys Chem Chem Phys 18(27):17898–17911CrossRefGoogle Scholar
  62. 62.
    Herrag L et al (2010) Adsorption properties and inhibition of mild steel corrosion in hydrochloric solution by some newly synthesized diamine derivatives: experimental and theoretical investigations. Corros Sci 52(9):3042–3051CrossRefGoogle Scholar
  63. 63.
    Daoud D et al (2015) Corrosion inhibition of mild steel by two new S-heterocyclic compounds in 1 M HCl: experimental and computational study. Corros Sci 94:21–37CrossRefGoogle Scholar
  64. 64.
    Torres VV et al (2014) Study of thioureas derivatives synthesized from a green route as corrosion inhibitors for mild steel in HCl solution. Corros Sci 79:108–118CrossRefGoogle Scholar
  65. 65.
    Ahamad I, Prasad R, Quraishi MA (2010) Inhibition of mild steel corrosion in acid solution by Pheniramine drug: experimental and theoretical study. Corros Sci 52(9):3033–3041CrossRefGoogle Scholar
  66. 66.
    Xu B et al (2014) Experimental and theoretical evaluation of two pyridinecarboxaldehyde thiosemicarbazone compounds as corrosion inhibitors for mild steel in hydrochloric acid solution. Corros Sci 78:260–268CrossRefGoogle Scholar
  67. 67.
    Caleyo F et al (2009) Probability distribution of pitting corrosion depth and rate in underground pipelines: a Monte Carlo study. Corros Sci 51(9):1925–1934CrossRefGoogle Scholar
  68. 68.
    Ismail KM (2007) Evaluation of cysteine as environmentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions. Electrochim Acta 52(28):7811–7819CrossRefGoogle Scholar
  69. 69.
    Matos JB et al (2004) Effect of cysteine on the anodic dissolution of copper in sulfuric acid medium. J Electroanal Chem 570(1):91–94CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Petroleum Applications DepartmentEgyptian Petroleum Research InstituteCairoEgypt
  2. 2.Petrochemicals DepartmentEgyptian Petroleum Research InstituteCairoEgypt

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