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Effect of 1,3,4-Thiadiazole Scaffold on the Corrosion Inhibition of Mild Steel in Acidic Medium: An Experimental and Computational Study

  • Taghried A. Salman
  • Dhafer S. Zinad
  • Shaimaa H. Jaber
  • Moafaq Al-Ghezi
  • Ahmed Mahal
  • Mohd S. Takriff
  • Ahmed A. Al-AmieryEmail author
Article
  • 15 Downloads

Abstract

The optimal inhibition efficiency of DBTA (4-Dimethylamino-benzylidene)-[1, 3, 4]thiadiazol-2-yl-amine) for MS (mild steel) in 1.0 M hydrochloric acid solution was achieved through employing electrochemical impedance spectroscopy (EIS) and weight loss techniques in addition to Scanning Electron Microscopy (SEM). Theoretical calculations based on Density functional theory (DFT) method were carried out for DBTA. Investigations of the mechanism for the corrosion inhibition for MS with DBTA in acidic solution by molecular simulations were performed. The results demonstrated that DBTA is an excellent corrosion inhibitor for MS in corrosive solution, and the inhibitory effectiveness was 91%, much higher than that expected at the highest concentration of DBTA. Spontaneous process of adsorption of DBTA on the mild steel surface was proved based on Langmuir adsorption isotherm.

Keywords

Mild steel Acid corrosion inhibition Thiadiazole moiety DFT DBTA 

Notes

Acknowledgements

The authors gratefully acknowledge the support provided by the UKM-YSD Chair on Sustainable Development for the Grant 020–2017’Malaysia’ to carry out this research.

Compliance with Ethical Standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  1. 1.Chemistry Department, College of ScienceAl-Nahrain UniversityBaghdadIraq
  2. 2.Applied Sciences DepartmentUniversity of TechnologyBaghdadIraq
  3. 3.Chemistry Department, College of ScienceAl-Mustansiriya UniversityBaghdadIraq
  4. 4.Energy and Renewable Energies Technology CenterUniversity of TechnologyBaghdadIraq
  5. 5.Key Laboratory of Plant Resources Conservation and Sustainable Utilization and Guangdong Provincial Key Laboratory of Applied Botany, South China Botanical GardenChinese Academy of SciencesGuangzhouPeople’s Republic of China
  6. 6.Guangzhou HC Pharmaceutical Co., LtdGuangzhouPeople’s Republic of China
  7. 7.Department of Chemical & Process Engineering, Faculty of Engineering & Built EnvironmentUniversiti Kebangsaan MalaysiaBangiMalaysia

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