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Chemical Composition and Green Anticorrosive Potential of Thymus broussonnetii Boiss subsp. broussonnetii Essential Oils in Hydrochloric Acid Medium

  • H. ChebliEmail author
  • M. Zaafrani
  • A. Batah
  • M. Berrabah
  • A. Mziouid
  • N. Heimeur
  • B. Chebli
  • R. Salghi
Article
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Abstract

The chemical composition of the essential oils of Thymus broussonnetii Boiss subsp. broussonnetii was carried out using GC/MS. The essential oils were characterized by carvacrol (39.51%) as the main constituent. The other components were benzene, 1-methyl-2-(1-methylethyl) (14.80%), gamma-terpinene (10.32%), alpha-pinene (9.7%), thymol (7.9%), and 3-cyclohexen-1-ol, 4-methyl-1-(1-methylethyl) (3.22%). The T. broussonnetii essential oils were tested for their potential to inhibit the corrosion of C38 steel in acidic environment. The effect of inhibition was studied using weight loss measurements and electrochemical techniques [potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS)] in the presence of different concentrations of T. broussonnetii essential oils ranging from 0.05 to 2 g/L. We obtained 82.35% of the inhibition efficiency at 2 g/L of the essential oils using the EIS test. The polarization studies showed that T. broussonnetii essential oils inhibit both cathodic hydrogen reduction reactions and anodic metal dissolution, and they act as mixed-type inhibitors of corrosion. The inhibition efficiency increases with increasing the temperature. The highest inhibition efficiency was 90% reached at 328 K. Adsorption of T. broussonnetii essential oils on the surface of the steel follows the isotherm of Langmuir. T. broussonnetii essential oils are a natural and environmentally eco-friendly inhibitor; they can be used as an alternative to toxic chemical inhibitors especially in acidic medium.

Keywords

Thymus broussonnetii Corrosion Potentiometric polarization Essential oils 

Notes

Compliance with Ethical Standards

Conflict of interest

The authors declare that there are no conflicts of interest.

References

  1. 1.
    El Kashoury E, El Askary HI, Kandil ZA, Salem MA (2013) Botanical and genetic characterization of Mentha suaveolens Ehrh. cultivated in Egypt. Pharacogn J 5:228–237CrossRefGoogle Scholar
  2. 2.
    Karousou R, Balta M, Hanlidou E, Kokkini S (2007) “Mints” smells and traditional uses in Thessaloniki (Greece) and other Mediterranean countries. J Ethnopharmacol 109:248–257CrossRefGoogle Scholar
  3. 3.
    El Kashoury EA, El Askary HI, Kandi ZA, Ezzat SM, Salem MA, Sleem AA (2014) Chemical and biological study of Mentha suaveolens Ehrh. cultivated in Egypt. J Med Plants Res 8:747–755CrossRefGoogle Scholar
  4. 4.
    Moreno L, Bello R, Primo Yúfera E, Esplugues J (2002) Pharmacological properties of the methanol extract from Mentha suaveolens Ehrh. Phytother Res 16:10–13CrossRefGoogle Scholar
  5. 5.
    Angiolella L, Vavala E, Sivric S, Diodata DAF, Ragno R (2010) In vitro activity of Mentha suaveolens essential oil against Cryptococcus neoformans and dermatophytes. Int J Essent Oil Ther 4:35–36Google Scholar
  6. 6.
    Ashassi Sorkhabi H, Nabavi Amri SA (2002) Polarization and impedance methods in corrosion inhibition study of carbon steel by amines in petroleum water mixtures. Electrochim Acta 47:2239–2244CrossRefGoogle Scholar
  7. 7.
    Bousskri A, Lgaz H, Jodeh S, Salghi R, Anejjar A, Messali M, Benali O (2016) Influence of pyridazinium derivative on copper corrosion in H3PO4/0.3 NaCl medium: electrochemical and molecular modeling. Appl J Envir En Sci 2(1):1–10Google Scholar
  8. 8.
    Ammar IA, El Khorafi FM (1973) Adsorbability of thiourea on iron cathodes. Werkstsf Korros 24(8):702–707CrossRefGoogle Scholar
  9. 9.
    Lgaz H, Salghi R, Jodeh S, Hammouti B (2017) Effect of clozapine on inhibition of mild steel corrosion in 0 M HCl medium. J Mol Liquids 225:271–280CrossRefGoogle Scholar
  10. 10.
    Abed Y, Hammouti B, Taleb M, Kertit S (2002) Corrosion inhibition of brass in nitric acid solution by Boc-phenylalanine. Trans SAEST 37:92–102Google Scholar
  11. 11.
    Abed Y, Kissi M, Hammouti B, Taleb M, Kertit S (2004) Peptidic compound as corrosion inhibitor for brass in nitricacid solution. Prog Org Coat 50:144–147CrossRefGoogle Scholar
  12. 12.
    Zarrok H, Zarrouk A, Hammouti B, Salghi R, Jama C, Bentiss F (2012) Corrosion control of carbon steel in phosphoric acid by purpald-weight loss, electrochemical and XPS studies. Corr Sci 64:243–252CrossRefGoogle Scholar
  13. 13.
    Eddy NO, Ebenso EE (2008) Adsorption and inhibitive properties of ethanol extracts of Musa sapientum peels as a green corrosion inhibitor for mild steel in H2SO4. Afr J Pure Appl Chem 2(6):46–54Google Scholar
  14. 14.
    Afia L, Salghi R, Bazzi EH, Zarrouk A, Hammouti B, Bouri M, Zarrouk H, Bazzi L, Bammou L (2012) Argan hulls extract: green inhibitor of mild steel corrosion in 1 M HCl solution. Res Chem Intermed 38:1707–1717CrossRefGoogle Scholar
  15. 15.
    El Ouariachi El M, Paolini J, Bouyanzer A, Tomi P, Hammouti B, Salghi R, Majidi L, Costa J (2011) Chemical composition and antioxidant activity of essential oils and solvent extracts of Thymus capitatus (L) Hoffmanns and link from Morocco. J Med Plants Res 5:5773–5778Google Scholar
  16. 16.
    Chetouani A, Hammouti B (2004) Thyme as a natural corrosion inhibitor for iron in HCl solutions. Bull Electrochem 20:343–345Google Scholar
  17. 17.
    Bothi RP, Sethuraman MG (2008) Inhibitive effect of black pepper extract on the sulphuric acid corrosion of mild steel. Mater Lett 62:2977–2979CrossRefGoogle Scholar
  18. 18.
    Bouyanzer A, Hammouti B, Majidi L, Haloui B (2010) Testing natural Fenugreek as an ecofriendly inhibitor for steel corrosion in 1 M HCl. Port Electrochim Acta 28:165–172CrossRefGoogle Scholar
  19. 19.
    Bouklah M, Hammouti B (2006) Thermodynamic characterisation of steel corrosion for the corrosion inhibition of steel in sulphuric acid solutions by Artemisia. Portug Electrochim Acta 24(4):457–468CrossRefGoogle Scholar
  20. 20.
    Emeka EO (2008) Corrosion inhibitive effect and adsorption behaviour of Hibiscus sabdariffa extract on mild steel in acidic Media. Portug Electrochim Acta 26:303–314Google Scholar
  21. 21.
    Bouyanzer A, Majidi L, Hammouti B (2007) Inhibition de la corrosion d’un acier en milieu HCl 1 M par l’huile essentielle du cèdre. Phys Chem News 37:70–74Google Scholar
  22. 22.
    Chetouani A, Hammouti B, Benkaddour M (2004) Corrosion inhibition of iron in hydrochloric acid solution by jojoba oil. Pigm Resin Technol 33(1):26–31CrossRefGoogle Scholar
  23. 23.
    Benabdellah M, Benkaddour M, Hammouti B, Bendahhou M, Aouniti A (2006) Inhibition of steel corrosion in 2 M H3PO4 by artemisia oil. Appl Surf Sci 252:6212–6217CrossRefGoogle Scholar
  24. 24.
    Bouyanzer A, Hammouti B, Majidi L (2006) Pennyroyal oil from Mentha pulegium as corrosion inhibitor for steel in 1 M HCl. Mater Lett 60:2840–2843CrossRefGoogle Scholar
  25. 25.
    Ben Hmamou D, Salghi R, Bazzi L, Hammouti B, Al Deyab SS, Bammou L, Bazzi L, Bouyanzer A (2012) Prickly pear seed oil extract: a novel green inhibitor for mild steel corrosion in 1 M HCl solution. Int J Electrochem Sci 7:1303–1318Google Scholar
  26. 26.
    Bouyanzer A, Majidi L, Hammouti B (2006) Effect of eucalyptus oil on the corrosion of steel in 1 M HCl. Bull Electrochem 22:321–324Google Scholar
  27. 27.
    Houbairi S, Essahli M, Lamiri A (2013) Inhibition of copper corrosion in 2 M HNO3 by the essential oil of thyme Morocco. Port Electrochim Acta 31:221–233CrossRefGoogle Scholar
  28. 28.
    Bammou L, Chebli B, Salghi R, Bazzi L, Hammouti B, Mihit M, El Idrissi H (2010) Thermodynamic properties of Thymus satureioides essential oils as corrosion inhibitor of tinplate in 0.5 M HCl: chemical characterization and electrochemical study Green. Chem Lett Rev 3:173–178CrossRefGoogle Scholar
  29. 29.
    Afia L, Salghi R, Bazzi E, Bazzi L, Errami M, Jbara O, Al Deyab SS, Hammouti B (2011) Testing natural compounds: Argania spinosa kernels extract and cosmetic oil as ecofriendly inhibitors for steel corrosion in 1 M HCl. Int J Electrochem Sci 6:5918–5939Google Scholar
  30. 30.
    Afia L, Salghi R, Bammou L, Bazzi EH, Hammouti B, Bazzi L, Bouyanzer A (2014) Anti-corrosive properties of Argan oil on C38 steel in molar HCl solution. J Saudi Chem Soc 18:19–25CrossRefGoogle Scholar
  31. 31.
    Mounir F, El-Issami S, Bazzi L, Eddine AC, Jbara O, Hilali M, Salghi R, Bazzi L (2014) Application of cosmetic argan oil as green corrosion inhibitor for copper in phosphoric acid medium. J Mater Environ Sci 5:2478–2483Google Scholar
  32. 32.
    French Pharmacopoeia (1983) Maisonnneuve S.A. Moulins, Les MetzGoogle Scholar
  33. 33.
    Adams RP (2007) Identification of essential oil components by gas chromatography/mass spectrometry. Allured Publishing Corporation, Illinois, p 804Google Scholar
  34. 34.
    Anejjar A, Salghi R, Zarrouk A, Zarrok H, Benali O, Hammouti B, Selim Al Deyab S, Benchat NE, Saddik R (2015) Investigation of inhibition by 6-bromo-3-nitroso-2-phenylimidazol[1,2-α]pyridine of the corrosion of C38 steel in 1 M HCl. Res Chem Intermed 41:913–925CrossRefGoogle Scholar
  35. 35.
    Karzazi Y, Belghiti ME, El Hajjaji F, Boudra S, Hammouti B (2016) Density functional theory modeling and Monte Carlo simulation assessment of inhibition performance of two quinoxaline derivatives for steel corrosion. J Mater Environ Sci 7(11):4011–4023Google Scholar
  36. 36.
    Bouoidina A, El Hajjaji F, Chaouch M, Abdellaoui A, Elmsellem H, Rais Z, Filali Baba M, Lahkimi A, Hammouti B, Taleb M (2016) Inhibition of mild steel corrosion using the extract of Foeniculum vulgare in acid medium. Der Pharma Chemica 8(13):149–157Google Scholar
  37. 37.
    Singh AK, Quraishi MA (2011) Investigation of the effect of disulfiram on corrosion of mild steel in hydrochloric acid solution. Corros Sci 53:1288–1297CrossRefGoogle Scholar
  38. 38.
    El Hajjaji F, Greche H, Taleb M, Chetouani A, Aouniti A, Hammouti B (2016) Application of essential oil of Thyme vulgaris as green corrosion inhibitor for mild steel in 1 M HCl. J Mater Environ Sci 7(2):566–578Google Scholar
  39. 39.
    Mansfeld F, Kending MW, Tsai S (1982) Recording and analysis of AC impedance data for corrosion studies. Corrosion 37:301CrossRefGoogle Scholar
  40. 40.
    Noor EA (2007) Temperature effects on the corrosion inhibition of mild steel in acidic solutions by aqueous extract of fenugreek leaves. Int J Electrochem Sci 2:996–1017Google Scholar
  41. 41.
    Batah A, Anejjar A, Belkhaouda M, Bammou L, Salghi R, Bazzi L, Hammouti B, chetouani A (2017) Electrochemical and thermodynamic study of the inhibitory efficacy of Methanol extracts of the Rind and Leaves of Grapefruit plant on the corrosion of carbon steel in an acidic medium. Mor J Chem 5(3):404–416Google Scholar
  42. 42.
    Gomma GK, Wahdan MH (1995) Schiff bases as corrosion inhibitors for aluminium in hydrochloric acid solution. Mater Chem Phys 39:209–213CrossRefGoogle Scholar
  43. 43.
    Antonijevic MM, Petrovic MB (2008) Copper corrosion inhibitors a review. Intern J Electrochem Sci 3:1–28Google Scholar
  44. 44.
    Li X, Mu G (2005) Tween-40 as corrosion inhibitor for cold rolled steel in sulphuric acid: weight loss study, electrochemical characterization, and AFM. Appl Surf Sci 252(5):1254 1265Google Scholar
  45. 45.
    Larabi L, Benali O, Harek Y (2007) Corrosion inhibition of cold rolled steel in 1 M HClO4 solutions by N-naphtyl N′-phenylthiourea. Mater Lett 61(14–15):3287–3291CrossRefGoogle Scholar
  46. 46.
    Ben Hmamou D, Aouad MR, Salghi R, Zarrouk A, Assouag M, Benali O, Messali M, Zarrok H, Hammouti B (2012) Inhibiting effects 4,5-diphenyl-1H-imidazole-2-thiol for C38 steel in 1 M HCl: electrochemical study. J Chem Pharm Res 4(7):3489–3497Google Scholar
  47. 47.
    Caprioli F, Martinelli A, Di Castro V, Decker F (2013) Effect of various terminal groups on long-term protective properties of aromatic SAMs on copper in acidic environment. J Electroanal Chem 693:86–94CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  • H. Chebli
    • 1
    Email author
  • M. Zaafrani
    • 1
  • A. Batah
    • 1
  • M. Berrabah
    • 2
  • A. Mziouid
    • 1
  • N. Heimeur
    • 1
  • B. Chebli
    • 1
  • R. Salghi
    • 1
  1. 1.Laboratory of Mechanic, Process Energy and Environment, ENSAIbn Zohr UniversityAgadirMorocco
  2. 2.Laboratory of Solid Mineral and Analytical Chemistry, Department of Chemistry, Faculty of SciencesMohammed Premier UniversityOujdaMorocco

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