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Corrosion Resistance of Niobium-Coated Carbon Steel

  • Paloma Detlinger
  • Brian Utri
  • Everson do Prado BanczekEmail author
Article
  • 24 Downloads

Abstract

In this work, the effectiveness of niobium coatings for the corrosion protection of carbon steel was studied. Three niobium resins, containing different molar proportions of citric acid:ethylene glycol, were coated separately onto samples of carbon steel (SAE 1020). The niobium layers were obtained by the polymeric precursor method (Pechini). Potentiodynamic polarization curves (anodic and cathodic) and electrochemical impedance spectroscopy were used to evaluate the corrosion resistance of the niobium-coated carbon steel samples in a 0.5 mol L−1 NaCl electrolyte solution. X-ray diffraction analysis of the niobium layers showed that they are composed of the niobates: NbO, NbO2 and Fe0.998Nb0.002. Surface observation by scanning electron microscopy revealed a uniformly deposited niobium coating on the surface. The electrochemical results showed that niobium was effective in the corrosion protection of the carbon steel substrate. The results also suggested that niobium can be coated onto the substrate to form a layer with advantageous corrosion properties.

Keywords

Pechini method Corrosion Niobium ammonium oxalate 

Notes

Acknowledgements

The authors are grateful for FUNDAÇÃO ARAUCÁRIA financial support provided to this research and also for CBMM for the Nb2O5 used in this study. This study was financed in part by the Coordnação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001.

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Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  1. 1.Departamento de QuímicaUniversidade Estadual do Centro-Oeste, UNICENTROGuarapuavaBrazil

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