Advertisement

Pomegranate Aqueous Extract (PAE) as an Eco-Friendly Inhibitor for Carbon Steel Used in Sanitation Plants: Kinetics and Bacteria Effect

  • A. S. FoudaEmail author
  • M. Eissa
  • M. Fakih
Article
  • 15 Downloads

Abstract

This study examines the use of pomegranate aqueous extract (PAE) for improvement of corrosion resistance of carbon steel (CS) in polluted NaCl solution (3.5% NaCl and 16 ppm Na2S). Mass loss, potentiodynamic polarization, electrochemical impedance spectroscopy, and electrochemical frequency modulation measurements were employed to study the corrosion behavior of CS in polluted NaCl solution. These electrochemical measurements improved that the presence of PAE decreased the corrosion rate, corrosion current densities (icorr), and double-layer capacities (Cdl). The inhibition efficiency (% IE) increases with the increase of extract concentration. The extract molecules were adsorbed physically on the metal surface following Temkin adsorption isotherm. The CS surface was analyzed by different techniques. The biological study of the extract on Escherichia coli activity showed that this extract can be applied safely without any harmful effect on the bacterial activity.

Keywords

Carbon steel PAE Polluted NaCl solution Temkin isotherm Escherichia coli 

References

  1. 1.
    El-Sayed A, Mohran HS, Abd El-Lateef HM (2012) Efficient complex surfactants from the type of fatty acids as corrosion inhibitors for mild steel C1018 in CO2-environments. J Korean Chem Soc 51(1):25–34Google Scholar
  2. 2.
    Mangale Sapana M, Chonde Sonal G, Raut PD (2012) Use of Moringa oleifera (Drumstick) seed as natural adsorbent and an antimicrobial agent for ground water treatment. Res J Recent Sci 1(3):31–40Google Scholar
  3. 3.
    Philippe S, Souabou F, Paulin A, Issaka Y, Dominique S (2012) In vitro antifungal activities of essential oils extracted from fresh leaves of Cinnamomum zeylanicum and Ocimum gratissimum against foodborne pathogens for their use as Traditional Cheese Wagashi conservatives. Res J Recent Sci 1(9):67–73Google Scholar
  4. 4.
    Trabanelli G (1991) Inhibition effect of potassium iodide on the corrosion of carbon steel (XC 38) in acidic medium. J Mater Environ Sci 47:410–419Google Scholar
  5. 5.
    Rahiman AF, Sethumanickam S (2017) Corrosion inhibition, adsorption and thermodynamic properties of poly (vinyl alcoholcysteine) in molar HCl. Arab J Chem 10:S3358–S3366Google Scholar
  6. 6.
    Loto RT, Loto CA, Joseph O, Olanrewaju G (2016) Adsorption and corrosion inhibition properties of thiocarbanilide on the electrochemical behavior of high carbon steel in dilute acid solutions. Results Phys 6:305–314Google Scholar
  7. 7.
    Sangeetha M, Rajendran S, Muthumegala TS, Krishnaveni A (2011) Green corrosion inhibitors-an overview, asafoetida extract (ASF) as green corrosion inhibitor for mild steel in sea water. Zastita Mater 52:3–19Google Scholar
  8. 8.
    Vijayalakshmi PR, Rajalakshmi R, Subhashini S (2011) Corrosion inhibition of aqueous extract of Cocos nucifera—coconut palm—petiole extract form destructive distillation for the corrosion of mild steel in acidic medium. Port Electrochim Acta 29(1):9–21Google Scholar
  9. 9.
    Lahhit N, Bouyanzer A, Desjobert JM (2010) fennel (foeniculum vulgare) essential oil as green corrosion inhibitor of carbon steel in hydrochloric acid solution. Port Electrochim Acta 29(2):127–138Google Scholar
  10. 10.
    Fouda AS, Al-Zehry H, Elsayed M (2018) Synergistic effect of potassium iodide with Cassia italica extract on the corrosion inhibition of carbon steel used in cooling water systems in 0.5 M H2SO4. J Bio Tribo Corros 4:1–17Google Scholar
  11. 11.
    Fouda AS, ElAwady GY, El Behairy WT (2018) Prosopis julifora plant extract as potential corrosion inhibitor for low carbon steel in 1 M HCl solution. J Bio Tribo Corros 4:1–12Google Scholar
  12. 12.
    Anupama KK, Joseph A (2018) Experimental and theoretical studies on Cinnamomum verum leaf extract and one of its major components, eugenol as environmentally benign corrosion inhibitors for mild steel in acid media. J Bio Tribo Corros 4:1–14Google Scholar
  13. 13.
    Tiwari P, Srivastava M, Mishra R, Ji G Prakash R (2018) Economic use of waste Musa paradisica peels for effective control of mild steel loss in aggressive acid solutions. J Environ Chem Eng 6:4773–4783Google Scholar
  14. 14.
    Kathiravan S, Ragul R, Raja G, Ravichandran J (2018) Theoretical and experimental studies about the inhibitive action of Ruellia tuberosa L on mild steel in hcl medium. J Bio Tribo Corros 4:46Google Scholar
  15. 15.
    Praveen BM, Prasanna BM, Narayana H, Kumar PS, Jagadeesh MR (2018) Experimental and Theoretical studies on inhibition efect of the Praziquantel on mild steel corrosion in 1 M HCl. J Bio Tribo Corros 4:21Google Scholar
  16. 16.
    Anupama KK, Joseph A (2018) Experimental and theoretical studies on Cinnamomum verum leaf extract and one of its major components, eugenol as environmentally benign corrosion inhibitors for mild steel in acid media. J Bio Tribo Corros 4:30Google Scholar
  17. 17.
    Rajendran S, Jeyasundari J, Selvi JA, Narayanasamy B, Regis APP, Rengan P (2009) Corrosion behaviour of aluminium in the presence of an aqueous extract of Hibiscus rosa-sinensis”. Port Electrochim Acta 27(2):153–164Google Scholar
  18. 18.
    Rajendran S, Paulraj J, Rengan P, Jeyasunbdari J, Manivannan M (2009) Corrosion behaviour of metals in artificial saliva in presence of spirulina powder”. J Dent Oral Hyg 1(1):1–8Google Scholar
  19. 19.
    Sirbharathy V, Rajendran S, Sathyabama J (2011) Inhibition of mild steel corrosion sea water by “DAUCUS CAROTA”. Int J Chem Sci Technol 1(3):108–115Google Scholar
  20. 20.
    Abdel-Rehim SS, Khaled KF, Abd-Elshafi NS (2006) Chemical and electrochemical investigations of l-arginine as corrosion inhibitor for steel in hydrochloric acid solutions. Electrochim Acta 51:3269–3277Google Scholar
  21. 21.
    Bosch RW, Hubrecht J, Bogaerts WF, Syrett BC (2001) Corrosion behaviour of some low chromium-molybdenum steels in sulphamic acid, electrochemical technique for online corrosion monitoring. Corrosion 57:60–70Google Scholar
  22. 22.
    Hussin MH, Kassim MJ (2011) The corrosion inhibition and adsorption behavior of Uncaria gambir extract on mild steel in 1 M HCl. Mater Chem Phys 125:461–468Google Scholar
  23. 23.
    Bentiss F, Traisnel M, Chaibi N, Mernari B, Vezin H, Lagrenee M (2002) 2,5-Bis(n-methoxyphenyl)-1,3,4-oxadizoles used as corrosion inhibitors in acidic media correlation between inhibition efficiency and chemical structure. Corros Sci 44:2271–2289Google Scholar
  24. 24.
    Fils J, Zakroczymski T (2012) Role of some phenylthiourea derivatives as corrosion inhibitors for carbon steel in HCl solution. J Korean Chem Soc 56(2):264–273Google Scholar
  25. 25.
    Fouda AS, Al-Sarawy AA, Ahmed FS, El-Addasy HM (2011) Effect of β-blocker inhibitors on aluminum corrosion. J Korean Chem Soc 55(2):268–278Google Scholar
  26. 26.
    Umoren SA, Eduok UM, Solomon MM, Udoh AP (2012) Corrosion inhibition and adsorption behaviour of Cocos nucifera L. coir dust for mild steel in 1 M HCl: synergistic effect of iodide ions. Int J Adv Sci Technol Res 1(2):338–360Google Scholar
  27. 27.
    Kamis E (1990) The effect of temperature on the acidic dissolution of steel in the presence of inhibitors corrosion. Int J Adv Sci Technol Res 46:476–484Google Scholar
  28. 28.
    El-Rehim SS, Ibrahim MAM, Khaled KF (1999) 4-Aminoantipyrine as an inhibitor of mild steel corrosion in HCl solution. J Appl Electrochem 29:593–599Google Scholar
  29. 29.
    Bataineh TT, Al-Qudah MA, Nawafleh EM, Al-Rawashdeh NAF (2014) Sinapis Alba extract as green corrosion inhibitor for aluminum in alkaline media. Int J Electrochem Sci 9:3543–3557Google Scholar
  30. 30.
    Maayta AK, Al-Rawashdeh NAF (2004) Inhibition of acidic corrosion of pure aluminum by some organic compounds. Corros Sci 46:1129–1140Google Scholar
  31. 31.
    Khadraoui A, Khelifa A, Boutoumi H, Hamitouche H, Mehdaoui R, Hammouti B, Al-Deyab SS (2014) Adsorption and inhibitive properties of Ruta chalepensis L. oil as a green inhibitor of steel in 1 M hydrochloric acid medium. Int J Electrochem Sci 9:3334–3348Google Scholar
  32. 32.
    Fouda AS, El-desoky AM, Ead DM (2013) Anhydride derivatives as corrosion inhibitors for carbon steel in hydrochloric acid solutions. Int J Electrochem Sci 8:8823–8847Google Scholar
  33. 33.
    Benali O, Ouazene M (2013) Inhibition effect of 3-bromo-2-phenylimidazol [1,2- α]pyridine towards C38 steel corrosion in 0.5M H2SO4 solution. Arab J Chem 4:443–448Google Scholar
  34. 34.
    Larabi L, Benali O, Harek Y (2007) Inhibition effect of 3-bromo-2 phenylimidazol[1,2- α] pyridine towards C38 steel corrosion in 0.5M H2SO4 solution. Mater Lett 61:3287–3291Google Scholar
  35. 35.
    Larabi L, Harek Y, Benali O, Ghalem S (2005) Application of some oligopolymers as effective corrosion inhibitors for mild steel in 1 M HCl: gravimetric, thermodynamic and electrochemical analysis. Prog Org Coat 54:256–262Google Scholar
  36. 36.
    Sherif EM, Erasmus RM, Comins JD (2006) Corrosion of copper in aerated acidic pickling solutions and its inhibition by 3-amino-1,2,4-triazole-5-thiol. Colloid Int Sci 306:96–104Google Scholar
  37. 37.
    Umoren SA, Solomon MM (2013) Kinetics of corrosion inhibition of aluminum in acidic media by water-soluble natural polymeric pectates as anionic polyelectrolyte inhibitors. Materials 6:2436–2451Google Scholar
  38. 38.
    Fouda AS, El-Desoky AM, Diab MA, Soliman AH (2014) Corrosion protection of carbon steel in hydrochloric acid solutions using heterocyclic compounds. Int J Adv Res 2(3):606–628Google Scholar
  39. 39.
    Abd El-Rehim SS, Refaey SA, Taha F, Saleh MB, Ahmed RA (2001) Inhibition of low carbon steel pipes of heat exchangers in industrial water medium by some plants extract. J Appl Electrochem 31:429–435Google Scholar
  40. 40.
    Gao B, Zhang X, Sheng Y (2008) Studies on preparing and corrosion inhibition behaviour of quanternized polyethyleneimine for low carbon steel in sulfuric acid. Mater Chem Phys 108:375–381Google Scholar
  41. 41.
    Benali O, Larabi L, Mekelleche SM, Harek Y (2006) Corrosion inhibition of mild steel by 4-Allyl-5-pyridin-4-yl-4H-1,2,4-triazole-3-thiol. J Mater Sci 41:7064–7073Google Scholar
  42. 42.
    Ammar IA, Darwish S (2011) Thermodynamic and quantum chemistry study for dimethylol-5-methyl hydantoin and its derivatives as corrosion inhibitors for carbon steel N-80 in raw water (cooling water system). J Mater Environ Sci 2(2):128–147Google Scholar
  43. 43.
    Fouda AS, Eldesoky AM, Elmorsi MA, El Sheik MY, El Said IA (2014) Benzamide, acetamide and acrylamide as corrosion inhibitors for carbon steel in hydrochloric acid solutions. Int J Adv Res 2(2):4–24Google Scholar
  44. 44.
    Tsuru T, Haruyama S, Gijutsu B (1978) Corrosion inhibition performance of 3,5-diamino-1,2,4-triazole for protection of copper in nitric acid solution. J Jpn Soc Corros Eng 27:573–581Google Scholar
  45. 45.
    Bentiss F, Lagrenee M, Traisnel M, Hornez JC (2003) The inhibition of benzimidazole derivatives on corrosion of iron in 1 M HCl solutions. Electrchim Acta 48:2493–/2503Google Scholar
  46. 46.
    Ramachandran S, Tsai M, Blanco M, Chen H, Tang WA (2003) Langmuir, molecular simulation, quantum chemical calculations and electrochemical studies for inhibition of mild steel by triazoles. Electrochim Acta 53:3484–3492Google Scholar
  47. 47.
    Avci G (2008) The inhibition of mild steel corrosion in 1 N HCl by imidazole derivatives. Colloid Surf A 317:730–736Google Scholar
  48. 48.
    Fouda AS, Abdallah M, Ahmed IS, Eissa M (2014) Corrosion inhibition of aluminum in NaOH solutions using some bidentate azo dyes compounds and synergistic action with some metal ions. Int J Electrochem Sci 9:4747–4760Google Scholar
  49. 49.
    Li Y, Guo C, Yang J, Wei J, Xu J, Cheng S (2006) Evaluation of antioxidant properties of Pomegranate extract in comparison with pomegranate pulp extract. Food Chem 96:254–260Google Scholar
  50. 50.
    Saleh RM, Ismail AA, El Hosary AA (1982) Corrosion inhibition by naturally occurring substances: VII. The effect of aqueous extracts of some leaves and fruit-peels on the corrosion of steel, Al, Zn and Cu in acids. Br Corros J 17(3):131–135Google Scholar
  51. 51.
    Shah AM, Rahim AA, Hamid SA, Yahya S (2013) Green inhibitors for copper corrosion by mangrove tannin. Int J Electrochem Sci 8:2140–2153Google Scholar
  52. 52.
    Anuradha K, Vimala R, Narayanasamy B, Selvi JA, Susai R (2007) Corrosion inhibition of carbon steel in low chloride media by an aqueous extract of hibiscus Rosa sinensis Linn. Chem Eng Commun 195(3):352–366Google Scholar
  53. 53.
    Sangeetha M, Rajendran S, Sathiyabama J, Prabhakar P (2012) Eco friendly extract of Banana peel as corrosion inhibitor for carbon steel in sea water. J Nat Prod Plant Resour 2(5):601–610Google Scholar
  54. 54.
    Abd-El-Nabey BA, El-Housseiny S, El-Naggar GA, Matter EA, Esmail G (2015) Inhibitive action of Alhagi maurorum plant extract on the corrosion of copper in 0.5 M H2SO4. Phys Chem 5(3):49–62Google Scholar
  55. 55.
    Deyab MA (2015) Egyptian licorice extract as a green corrosion inhibitor for copper in hydrochloric acid solution. J Ind Eng Chem 22:384–389Google Scholar
  56. 56.
    Flores-De los Ríos JP, Sánchez-Carrillo M, Nava-Dino CG, Chacón-Nava JG, González Rodríguez Z, Huape-Padilla E, Neri-Flores MA, Martínez-Villafañe A (2015) Opuntia ficusindica extract as green corrosion inhibitor for carbon steel in 1 M HCl solution. J. Spectroscopy 2015:14692–14701Google Scholar

Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of ScienceMansoura UniversityMansouraEgypt
  2. 2.Higher Institute of Engineering & Technology, KMA, Alex, Egypt and College of Science & Humanities- HarimlaeShaqra UniversityShaqraaSaudi Arabia
  3. 3.Talkha Sanitation PlantWater and Wastewater CompanyDaqahliaEgypt

Personalised recommendations