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Design and Fabrication of Long-Term Stable Dye-Sensitized Solar Cells: Effect of Water Contents in Electrolytes on the Performance

  • Jongwoo Park
  • Phillip LeeEmail author
  • Min Jae KoEmail author
Regular Paper
  • 37 Downloads

Abstract

The effects of water-containing I/I3 liquid electrolytes on the photovoltaic performance and long-term stability of ruthenium based complex Z907 dye was examined in dye-sensitized solar cells (DSSCs). Despite of high water content up to 60 vol% in organic solvent-based liquid electrolyte, the photovoltaic properties and long-term stability measured under the standard global (G) air-mass (AM) 1.5 solar irradiation were not significantly affected. The underlying correlation between the effects of water and the photovoltaic performances were identified by UV–visible spectroscopy and electrochemical impedance spectroscopy. We investigated the long-term stability of performance for DSSCs in conjunction with I/I3 redox electrolytes in different water compositions. The findings revealed that the competitive photovoltaic performance and long-term stability of water-containing DSSCs mainly depends on the hydrophobicity of dye as well as the transport phenomena of I3 throughout the electrolytes. The water-based DSSCs proposed herein are free from water permeation issues and these results will provide great insight into the development of less expensive and more environmental friendly DSSCs.

Keywords

Dye-sensitized solar cells Water-containing liquid electrolytes Dye Photovoltaic performance Long-term stability 

Notes

Acknowledgement

Authors acknowledge the funding support by development program “Development of high drapability of textile type dye-sensitized solar cell materials and outdoor applications. (project NO. 10052064)” funded by MOTIE and the Technology Development Program to Solve Climate Changes (2015M1A2A2056824) funded by the National Research Foundation under the Ministry of Science an ICT, Korea.

References

  1. 1.
    Smalley, R. E. (2005). Future global energy prosperity: The terawatt challenge. MRS Bulletin, 30(6), 412–417.CrossRefGoogle Scholar
  2. 2.
    Choi, J.-H., Moon, Y., Lee, S.-H., In, J.-H., & Jeong, S. (2016). Wavelength dependence of the ablation characteristics of Cu (In, Ga) Se2 solar cell films and its effects on laser induced breakdown spectroscopy analysis. International Journal of Precision Engineering and Manufacturing-Green Technology, 3(2), 167–171.CrossRefGoogle Scholar
  3. 3.
    O’Regan, B., & Grätzel, M. (1991). A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 353(6346), 737–740.CrossRefGoogle Scholar
  4. 4.
    O’Regan, B., & Grätzel, M. (1991). A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 353(6346), 737–740.CrossRefGoogle Scholar
  5. 5.
    Chang, H., Kuo, C.-G., & Chou, C.-Y. (2015). Highly-ordered arrays of TiO2 thin film for dye-sensitized solar cells fabricated by anodic oxidation process. International Journal of Precision Engineering and Manufacturing, 16(7), 1251–1255.CrossRefGoogle Scholar
  6. 6.
    Kim, Y.-W., Kang, B.-S., & Lee, D.-W. (2015). Improving efficiency of dye-sensitized solar cell by micro reflectors. International Journal of Precision Engineering and Manufacturing, 16(7), 1257–1261.CrossRefGoogle Scholar
  7. 7.
    Gong, H. H., Park, S. H., Lee, S.-S., & Hong, S. C. (2014). Facile and scalable fabrication of transparent and highperformance Pt/reduced graphene oxide hybrid counter electrode for dye-sensitized solar cells. International Journal of Precision Engineering and Manufacturing, 15(6), 1193–1199.CrossRefGoogle Scholar
  8. 8.
    Mathew, S., Yella, A., Gao, P., Humphry-Baker, R., Curchod, B. F., Ashari-Astani, N., et al. (2014). Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nature Chemistry, 6(3), 242–247.CrossRefGoogle Scholar
  9. 9.
    Komiya, R., Fukui, A., Murofushi, N., Koide, N., Yamanaka, R., & Katayama, H. (2011). Improvement of the conversion efficiency of a monolithic type dye-sensitized solar cell module. In Technical Digest of the 21st International Photovoltaic Science and Engineering Conference, 2C-5O-08, Fukuoka, Japan.Google Scholar
  10. 10.
    Nazeeruddin, M. K., De, A. F., Fantacci, S., Selloni, A., Viscardi, G., Liska, P., et al. (2005). Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers. Journal of the American Chemical Society, 127(48), 16835–16847.CrossRefGoogle Scholar
  11. 11.
    Cao, Y. M., Bai, Y., Yu, Q. J., Cheng, Y. M., Liu, S., Shi, D., et al. (2009). Dye-sensitized solar cells with a high absorptivity ruthenium sensitizer featuring a 2-(hexylthio)thiophene conjugated bipyridine. Journal of Physical Chemistry C, 113(15), 6290–6297.CrossRefGoogle Scholar
  12. 12.
    Muhammad, I. A., Kati, M., Janne, H., Paula, V., Minna, T., Kerttu, A., et al. (2010). Review of stability for advanced dye solar cells. Energy & Environmental Science, 3(4), 418–426.CrossRefGoogle Scholar
  13. 13.
    Egbert, F., & Anders, H. (2004). Are dye-sensitized nano-structured solar cells stable? An overview of device testing and component analyses. International Journal of Photoenergy, 6(3), 127–140.CrossRefGoogle Scholar
  14. 14.
    Law, C., Pathirana, S. C., Li, X., Anderson, A. Y., Barnes, P. R., Listorti, A., et al. (2010). Water-based electrolytes for dye-sensitized solar cells. Advanced Materials, 22(40), 4505–4509.CrossRefGoogle Scholar
  15. 15.
    Yelena, G. T., & Noel, G. H. (1997). Activated rate theory treatment of oxygen and water transport through silicon oxide/poly(ethylene terephthalate) composite barrier structures. Journal of Physical Chemistry, 101(13), 2259–2266.CrossRefGoogle Scholar
  16. 16.
    Wang, P., Zakeeruddin, S. M., Moser, J. E., Nazeeruddin, M. K., Sekiguchi, T., & Grätzel, M. (2003). A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nature Materials, 2(7), 498–498.CrossRefGoogle Scholar
  17. 17.
    Ito, S., Murakami, T. N., Comte, P., Liska, P., Graetzel, C., Nazeeruddin, M. K., et al. (2008). Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10%. Thin Solid Films, 516(14), 4613–4619.CrossRefGoogle Scholar
  18. 18.
    Park, S.-J., Yoo, K., Kim, J.-Y., Kim, J.-Y., Lee, D.-K., Kim, B., et al. (2013). Water-based thixotropic polymer gel electrolyte for dye-sensitized solar cells. ACS Nano, 7(5), 4050–4056.CrossRefGoogle Scholar
  19. 19.
    Mikoshiba, S., Murai, S., Sumino, H., Kado, T., Kosugi, D., & Hayase, S. (2005). Ionic liquid type dye-sensitized solar cells: Increases in photovoltaic performances by adding a small amount of water. Current Applied Physics, 5(2), 152–158.CrossRefGoogle Scholar
  20. 20.
    Liu, Y., Hagfeldt, A., Xiao, X. R., & Lindquist, S. E. (1998). Investigation of influence of redox species on the interfacial energetics of a dye-sensitized nanoporous TiO2 solar cell. Solar Energy Materials Solar Cells, 55(3), 267–281.CrossRefGoogle Scholar
  21. 21.
    Weidmann, J., Dittrich, T., Konstantinova, E., Lauermann, I., Uhlendorf, I., & Koch, F. (1999). Influence of oxygen and water related surface defects on the dye sensitized TiO2 solar cell. Solar Energy Materials Solar Cells, 56(2), 153–165.CrossRefGoogle Scholar
  22. 22.
    Hahlin, M., Johansson, E. M. J., Scholin, R., Siegbabn, H., & Rensmo, H. (2011). Influence of water on the electronic and molecular surface structures of ru-dyes at nanostructured TiO2. Journal of Physical Chemistry C, 115(24), 11996–12004.CrossRefGoogle Scholar
  23. 23.
    Yang, Y., Zhang, J., Zhou, C. H., Wu, S. J., Xu, S., Liu, W., et al. (2008). Effect of lithium iodide addition on poly (ethylene oxide)−poly (vinylidene fluoride) polymer-blend electrolyte for dye-sensitized nanocrystalline solar cell. Journal of Physical Chemistry B, 112(21), 6594–6602.CrossRefGoogle Scholar
  24. 24.
    Fabregat-Santiago, F., Bisquert, J., Garcia-Belmonte, G., Boschloo, G., & Hagfeldt, A. (2005). Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy. Solar Energy Materials Solar Cells, 87(1–4), 117–131.CrossRefGoogle Scholar
  25. 25.
    Park, J., Choi, I., Lee, M.-J., Kim, M.-H., Lim, T., Park, K.-H., et al. (2014). Effect of fluoroethylene carbonate on electrochemical battery performance and the surface chemistry of amorphous MoO2 lithium-ion secondary battery negative electrodes. Electrochimica Acta, 132, 338–346.CrossRefGoogle Scholar
  26. 26.
    Wyss, P., Moehl, T., Zakeeruddin, S. M., & Grätzel, M. (2012). Influence of cations of the electrolyte on the performance and stability of dye sensitized solar cells. Journal of Materials Chemistry, 22(46), 24424–24429.CrossRefGoogle Scholar
  27. 27.
    Pan, L., Zou, J. J., Zhang, X. W., & Wang, L. (2011). Water-mediated promotion of dye sensitization of TiO2 under visible light. Journal of the American Chemical Society, 133(26), 10000–10002.CrossRefGoogle Scholar
  28. 28.
    Park, S. I., Quan, Y.-J., Kim, S.-H., Kim, H., Kim, S., Chun, D.-M., et al. (2016). A review on fabrication processes for electrochromic devices. International Journal of Precision Engineering and Manufacturing-Green Technology, 3(4), 397–421.CrossRefGoogle Scholar

Copyright information

© Korean Society for Precision Engineering 2019

Authors and Affiliations

  1. 1.School of Chemical and Biomolecular EngineeringGeorgia Institute of TechnologyAtlantaUSA
  2. 2.Photo-Electronic Hybrids Research CenterKorea Institute of Science and Technology (KIST)SeoulRepublic of Korea
  3. 3.Department of Chemical EngineeringHanyang UniversitySeoulRepublic of Korea

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