Rapid thermal cycling of three phase change materials (PCMs) for cooking applications

  • A. B. ShoboEmail author
  • A. Mawire
  • M. Aucamp
Technical Paper


The suitability of the use of acetanilide, meso-erythritol and In-48Sn as phase change materials (PCMs) in latent heat thermal storage systems (LHTES) for cooking applications has been investigated under high charging and heat retrieval conditions. In-48Sn showed the greatest thermal stability up to 289.68 °C with meso-erythritol showing stability up to 177.03 °C, while acetanilide is thermally stable up to 133.33 °C. Thermal properties of acetanilide remained within stable limits with rapid thermal cycles, but rapid mass degradation was observed. Two forms of meso-erythritol were manifested with different melting points with the solidification temperature that showed considerable variations while the enthalpy of solidification remained reasonably stable. Acetanilide and meso-erythritol exhibited large degrees of supercooling below 100 °C making them undesirable to be used in a LHTES unit for cooking applications under rapid heating and cooling cycles. With the solidification temperature of In-48Sn above 100 °C throughout the thermal cycles, it proved to be a promising PCM for cooking applications under rapid heating and cooling cycles. The residues of the PCMs after thermal cycling showed no structural changes as compared with the fresh samples while the health hazards related to the PCMs were all within acceptable limits. Though the cost implication of utilizing In-48Sn is much higher as compared with the other two PCMs, its good cycling stability and its average solidification temperature being within desired cooking temperature makes it a preferred PCM candidate under fast heat retrieval condition than acetanilide and meso-erythritol.


Phase change materials (PCM) Thermal stability Cycling stability Acetanilide Meso-erythritol In-48Sn 



The authors wish to acknowledge the support provided by the Material Science Innovation and Modeling (MaSIM) research focus area, Faculty of Natural and Agricultural Sciences at the North West University, South Africa. The authors also wish to acknowledge the National Research Foundation, South Africa, through the Incentive Funding for Rated Researchers (IFRR-Grant Nos.: 90638, 95574) scheme.


  1. 1.
    Fernandes D, Pitie F, Caceres G, Baeyens J (2012) Thermal energy storage: “How previous findings determine current research priorities”. Energy 39:246–257CrossRefGoogle Scholar
  2. 2.
    Sharma A, Tygi VV, Chen CR, Buddhi D (2009) Review on thermal energy storage with phase change materials and application. Renew Sustain Energy Rev 13:318–345CrossRefGoogle Scholar
  3. 3.
    Miro L, Barreneche C, Ferrer G, Sole A, Martorell I (2016) Health hazard, cycling and thermal stability as key parameters when selecting a suitable phase change material (PCM). Thermochim Acta 627–629:39–47CrossRefGoogle Scholar
  4. 4.
    Muthusivagami RM, Velraj R, Sethumadhavan R (2010) Solar cookers with and without thermal storage—a review. Renew Sustain Energy Rev 14:691–701CrossRefGoogle Scholar
  5. 5.
    Sharma SD, Buddhi D, Sawhney RL, Sharma A (2000) Design, development and performance evaluation of a latent heat storage unit for evening cooking in a solar cooker. Energy Convers Manag 41(14):1497–1508CrossRefGoogle Scholar
  6. 6.
    Domanski R, El-Sebaii AA, Jaworski M (1995) Cooking during off-sunshine hours using PCMs as storage media. Energy 20(7):607–616CrossRefGoogle Scholar
  7. 7.
    Choudhari KS, Shende MD (2015) Solar cooker using PCM material. J Basic Appl Eng Res 2(17):1449–1453Google Scholar
  8. 8.
    Saxena A, Lath S, Tirth V (2013) Solar cooking by using PCM as a thermal heat storage. MIT Int J Mech Eng 3(2):91–95Google Scholar
  9. 9.
    Buddhi D, Sharma SD, Sharma A (2003) Thermal performance evaluation of a latent heat storage unit for late evening cooking in a solar cooker having three reflectors. Energy Convers Manag 44:809–817CrossRefGoogle Scholar
  10. 10.
    Sharma SD, Iwata T, Kitano H, Sagara K (2005) Thermal performance of a solar cooker based on an evacuated tube solar collector with a PCM storage unit. Sol Energy 78:416–426CrossRefGoogle Scholar
  11. 11.
    Hussein HMS, El-Ghetany HH, Nada SA (2008) Experimental investigation of novel indirect solar cooker with indoor PCM thermal storage and cooking unit. Energy Convers Manag 49:2237–2246CrossRefGoogle Scholar
  12. 12.
    Mussard M, Gueno A, Nydal OJ (2013) Experimental study of solar cooking using heat storage in comparison with direct heating. Sol Energy 98:375–383CrossRefGoogle Scholar
  13. 13.
    Lecuona A, Nogueira J, Ventas R, Rodríguez-Hidalgo M, Legrand M (2013) Solar cooker of the portable parabolic type incorporating heat storage based on PCM. Appl Energy 111:1136–1146CrossRefGoogle Scholar
  14. 14.
    Nandwani SS (1997) Experimental study of multipurpose solar hot box at Freiburg, Germany. Renew Energy 12(1):1–20CrossRefGoogle Scholar
  15. 15.
    Buddhi D, Sahoo LK (1997) Solar cooker with latent heat storage: design and experimental testing. Energy Convers Manag 38(5):493–498CrossRefGoogle Scholar
  16. 16.
    Liu Z, Chung DDL (2001) Calorimetric evaluation of phase change materials for use as thermal interface materials. Thermochimita Acta 366:135–147CrossRefGoogle Scholar
  17. 17.
    Ge H, Li H, Mei S, Liu J (2013) Low melting point liquid metal as a new class of phase change material: an emerging frontier in energy area. Renew Sustain Energy Rev 21:331–346CrossRefGoogle Scholar
  18. 18.
    Kotzé JP, von Backström TW (2013) High temperature thermal energy storage utilizing metallic phase change materials and metallic heat transfer fluids. J Sol Energy Eng 135:035001CrossRefGoogle Scholar
  19. 19.
    Kenisarin M, Mahkamov K (2007) Solar energy storage using phase change materials. Renew Sustain Energy Rev 11:1913–1965CrossRefGoogle Scholar
  20. 20.
    Sharma SD, Sagara K (2005) Latent heat storage materials and systems: a review. Int J Green Energy 2:1–56CrossRefGoogle Scholar
  21. 21.
    Saini P, Sharma V, Singh C (2014) Performance evaluation of thermal storage unit based on parabolic dish collector for indoor cooking application. J Acad Ind Res 3(7):304–310Google Scholar
  22. 22.
    El-Sebaii AA, Al-Amir S, Al-Marzouki FM, Faidah AS, Al-Ghamdi AA, Al-Heniti S (2009) Fast thermal cycling of acetanilide and magnesium chloride hexahydrate for indoor solar cooking. Energy Convers Manag 50:3104–3111CrossRefGoogle Scholar
  23. 23.
    El-Sabaii AA, Al-Agel F (2012) Fast thermal cycling of acetanilide as a storage material for solar energy applications. ASME J Sol Energy Eng 135(2):024502CrossRefGoogle Scholar
  24. 24.
    Gunasekara SN, Pan R, Chiu JN, Martin V (2014) Polyols as phase change materials for low-grade excess heat storage. Energy Procedia 61:664–669CrossRefGoogle Scholar
  25. 25.
    Kaizawa A, Marouka N, Kawai A, Kamano H, Jozuka T, Senda T, Akiyama T (2008) Thermophysical and heat transfer properties of phase change material candidate for waste heat transportation system. Heat Mass Transf 44:763–769CrossRefGoogle Scholar
  26. 26.
    Agyenim F, Rhodes M, Knight I (2007) The use of phase change material (PCM) to improve the coefficient of performance of a chiller for meeting domestic cooling in Wales. In: Proceedings of 2nd PALENC conference and 28th AIVC conference on building low energy cooling and advanced technologies in the 21st century, Crete IslandGoogle Scholar
  27. 27.
    Puupponen S, Mikkola V, Ala-Nissila T, Seppala A (2016) Novel microstructured polyol-polystrene composite for seasonal heat storage. Appl Energy 172:96–106CrossRefGoogle Scholar
  28. 28.
    Nomura T, Tsubota M, Oya T, Okinaka N, Akiyama T (2013) Heat release performance of direct-contact heat exchanger with erythritol as phase change material. Appl Therm Eng 61:28–35CrossRefGoogle Scholar
  29. 29.
    Kakiuchi H, Yamazaki M, Yabe M, Chihara S, Terunuma Y, Sakata Y, Usami T (1998) A study of Erythritol as phase change material, In: Chemical Engineering and Technology, Royal Institute of Technology. IEA Annex 10-PCMs and chemical reactions for thermal energy storage, second workshop, SofiaGoogle Scholar
  30. 30.
    Shukla A, Buddhi D, Sawhney RL (2008) Thermal cycling test of few selected inorganic and organic phase change materials. Renew Energy 33:2606–2614CrossRefGoogle Scholar
  31. 31.
    Myers B, Chaudhuri AK, Burns JH (2003) Thermally-capacitive phase change encapsulant for electronic devices, US Patent; US20030157342; 2003Google Scholar
  32. 32.
  33. 33.
  34. 34.
  35. 35.
    Jesus AJL, Nunes SCC, Silva M, Beja AM, Redinha JS (2010) Erythritol: crystal growth from melt. Int J Pharm 388:129–135CrossRefGoogle Scholar
  36. 36.
    Yaws CL (1995) Handbook of Thermal conductivity, organic compounds C8 to C28. Gulf Publishing Company, HoustonGoogle Scholar
  37. 37.

Copyright information

© The Brazilian Society of Mechanical Sciences and Engineering 2018

Authors and Affiliations

  1. 1.Department of Mathematics, Science and Sports EducationUniversity of NamibiaOshakatiNamibia
  2. 2.Department of Physics and ElectronicsNorthwest University (Mafikeng Campus)MmabathoSouth Africa
  3. 3.Faculty of Health Sciences, Center of Excellence for Pharmaceutical SciencesNorthwest University (Potchefstroom Campus)PotchefstroomSouth Africa

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