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Direct Pyrolysis of Molybdophosphate-based Ionic Salt for One-step Synthesis of N,P Co-doped Carbon/MoO3-x Hybrids with Superior Lithium Storage Performance

  • Lifeng ZhangEmail author
  • Kechao Shen
  • Yongtao Jiang
  • Yu Guo
  • Yi Liu
  • Shouwu GuoEmail author
Article
  • 1 Downloads

Abstract

N,P co-doped carbon/MoO3-x hybrids(NPC/MoO3-x) were synthesized via one-step pyrolysis of molyb-dophosphate-based ionic salt precursor. Doped carbon and oxygen vacancies(OVs) were synchronously introduced into the NPC/MoO3-x hybrids without any other redundant procedure. As anodes for lithium-ion batteries, the NPC/MoO3-x hybrids delivered a high initial Coulombic efficiency(ICE) of 81% as well as high charge capacity of 516 mA·h/g after 100 cycles at 1 A/g, indicating the excellent reversibility and rate capability. The enhanced lithium storage performance was attributed to the rational combination of surface engineering and OVs, which is beneficial to the more active sites and fast ionic/electronic transport.

Keywords

Lithium ion battery Anode Molybdenum oxide Doped carbon Oxygen vacancy 

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Supplementary material

40242_2019_9149_MOESM1_ESM.pdf (521 kb)
En">Direct pyrolysis of molybdophosphate-based ionic salt to one-step synthesize N, P co-doped carbon/MoO3-X hybrids with superior lithium storage performance

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2019

Authors and Affiliations

  1. 1.School of Materials Science and EngineeringShaanxi University of Science and TechnologyXi’anP. R. China
  2. 2.Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic MaterialsShaanxi University of Science and TechnologyXi’anP. R. China
  3. 3.School of Electronic Information and Electrical EngineeringShanghai Jiao Tong UniversityShanghaiP. R. China

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