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Chemical Research in Chinese Universities

, Volume 35, Issue 2, pp 171–178 | Cite as

Microwave Assisted Hydrothermal Way Towards Highly Crystalized N-Doped Carbon Quantum Dots and Their Oxygen Reduction Performance

  • He Huang
  • Chen Liang
  • Haoyan Sha
  • Ying Yu
  • Yue Lou
  • Cailing Chen
  • Chunguang LiEmail author
  • Xiaobo Chen
  • Zhan ShiEmail author
  • Shouhua Feng
Article
  • 12 Downloads

Abstract

We proposed a green microwave-assisted hydrothermal way to synthesize highly crystalized N-doped carbon quantum dots(N-CQDs). The N-CQDs obtained by this microwave method have good crystalline degree(ID/IG=0.6) and a high molar ratio of N/C(11.1%) comparing with those obtained from traditional top-down method. The experimental results show that glycerine plays a key role in the formation of highly crystalized N-CQDs. The as-prepared N-CQDs have good luminescent property and may be utilized as fluorescent probe to detect ions or mark cells. As the majority of N atoms in the N-CQDs were pyridinic type(64.8%), the as-prepared N-CQDs were used as a catalyst for the oxygen reduction reaction(ORR) electrocatalysis in the anode of the fuel cell(the onset potential is–0.121 V), which was a 4e-transfer procedure and the catalyst showed good stability after 100 cycles.

Keywords

Carbon-dot Nitrogen-dopping Highly-crystalized Oxygen reduction reaction(ORR) 

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Supplementary material

40242_2019_8343_MOESM1_ESM.pdf (832 kb)
A Microwave method towards highly crystalized N-doped carbon quantum dots and their Oxygen reduction performance

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2019

Authors and Affiliations

  • He Huang
    • 1
  • Chen Liang
    • 1
  • Haoyan Sha
    • 3
  • Ying Yu
    • 1
  • Yue Lou
    • 1
  • Cailing Chen
    • 1
  • Chunguang Li
    • 1
    Email author
  • Xiaobo Chen
    • 2
  • Zhan Shi
    • 1
    Email author
  • Shouhua Feng
    • 1
  1. 1.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of ChemistryJilin UniversityChangchunP. R. China
  2. 2.School of EngineeringRMIT UniversityCarltonAustralia
  3. 3.Department of Chemical EngineeringUniversity of CaliforniaDavisUSA

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