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Chemical Research in Chinese Universities

, Volume 35, Issue 2, pp 340–344 | Cite as

Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

  • Ying Wang
  • Qiliao Wang
  • Liman Hou
  • Mingdong ZhouEmail author
  • Dewen Dong
  • Ning ZhangEmail author
Article
  • 10 Downloads

Abstract

Poly(ethylene phosphonate) was synthesized via the living ring-opening polymerization of cyclic phosphonate monomer catalyzed by organocatalyst. The pendant vinyl functionalities were employed to perform the photochemical click reactions with thiols. We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains, enabling the rapid and efficient functionalization of polyphosphoesters( PPE).

Keywords

Cyclic phosphonate Ring-opening polymerization Thiol-ene click reaction Post modification 

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2019

Authors and Affiliations

  1. 1.School of Chemistry and Materials ScienceLiaoning Shihua UniversityFushunP. R. China
  2. 2.CAS Key Laboratory of High-performance Synthetic Rubber and Its Composite Materials, Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchunP. R. China
  3. 3.University of Science and Technology of ChinaHefeiP. R. China

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