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Chemical Research in Chinese Universities

, Volume 34, Issue 6, pp 1009–1013 | Cite as

Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O

  • Zimei Ding
  • Wenli Cao
  • Hui Zheng
  • Jie HuangEmail author
  • Kangzhen Xu
  • Jirong Song
Article
  • 30 Downloads

Abstract

[Zn(phen)3] ZTO 6H2O(1) and [Cu(phen)3] ZTO 6H2O(2) were synthesized by the reaction of Zn(NO3)2 6H2O/Cu(NO3)2 3H2O with 4,4-azo-1H-1,2,4-triazol-5-one(ZTO) and 1,10-phenanthroline(phen). The two compounds were characterized by elemental analysis and IR spectrum analysis, respectively. Compound 1 was also characterized by single crystal X-ray diffraction analysis. For compound 1, the coordination geometry around the Zn2+ is a distorted octahedron, with the bite angles of 76.7(3)°―77.6(4)° for all three phen ligands. Moreover, the thermal behaviors and thermal decomposition kinetics were studied and analyzed. Besides, thermal stability and safety parameters(TSADT, Tb) are 164.7 and 166.4 °C for compound 1, and 149.6 and 150.8 °C for compound 2, respectively.

Keywords

Azo-triazole [Zn(phen)3] ZTO 6H2[Cu(phen)3] ZTO 6H2Crystal structure Thermal behavior 

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Supplementary material

40242_2018_8051_MOESM1_ESM.pdf (118 kb)
Synthesis, Structure characteristic and Thermal behavior of two new metal-organic azo-triazole compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Zimei Ding
    • 1
  • Wenli Cao
    • 1
  • Hui Zheng
    • 1
  • Jie Huang
    • 1
    Email author
  • Kangzhen Xu
    • 1
  • Jirong Song
    • 1
    • 2
  1. 1.Department of Chemical EngineeringNorthwest UniversityXi’anP. R. China
  2. 2.Conservation Technology Departmentthe Palace MuseumBeijingP. R. China

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