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Acta Metallurgica Sinica (English Letters)

, Volume 32, Issue 1, pp 41–51 | Cite as

Effect of Mo Addition on Corrosion Behavior of High-Entropy Alloys CoCrFeNiMox in Aqueous Environments

  • Xu-Liang Shang
  • Zhi-Jun WangEmail author
  • Qing-Feng Wu
  • Jin-Cheng Wang
  • Jun-Jie Li
  • Jia-Kang Yu
Article
  • 105 Downloads

Abstract

The corrosion behavior of CoCrFeNiMox alloys was investigated in aqueous environments, NaCl and H2SO4 solutions, respectively, to simulate typical neutral and acidic conditions. The cyclic polarization curves in NaCl and the potentiodynamic curves in H2SO4 clearly reveal the beneficial effects of Mo and the detrimental effect of σ-phase on the corrosion resistance. The X-ray photoelectron spectroscopy results of CoCrFeNiMox alloys in H2SO4 solution indicate that Cr and Mo predominate the corroded surface of the alloys, where Mo primarily exists in the form of MoO3.

Keywords

High-entropy alloys Corrosion σ-phase Molybdenum 

Notes

Acknowledgement

The work was supported financially by the National Natural Science Foundation of China (Nos. 51471133 and 51771149).

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Copyright information

© The Chinese Society for Metals and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Xu-Liang Shang
    • 1
  • Zhi-Jun Wang
    • 1
    Email author
  • Qing-Feng Wu
    • 1
  • Jin-Cheng Wang
    • 1
  • Jun-Jie Li
    • 1
  • Jia-Kang Yu
    • 1
  1. 1.State Key Laboratory of Solidification ProcessingNorthwestern Polytechnical UniversityXi’anChina

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