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Removal of carbamazepine, ciprofloxacin and ibuprofen in real urban wastewater by using light-driven advanced oxidation processes

  • A. Monteoliva-García
  • J. Martín-Pascual
  • M. M. Muñío
  • J. M. PoyatosEmail author
Original Paper
  • 20 Downloads

Abstract

This study focuses on the use of advanced oxidation processes as a tertiary treatment in wastewater treatment plants to degrade contaminants of emerging concern at the natural pH of the biologically treated wastewater. Different peroxide dosages and initial concentrations of a mix of three pharmaceuticals commonly present in wastewater (carbamazepine, ciprofloxacin and ibuprofen) were tested in a batch photoreactor. The addition of Fe2+ and TiO2 as catalysts was also tested with the aim of improving the degradation rate of the pharmaceuticals. Among the contaminants tested, ciprofloxacin was the pollutant that showed the best degradation. It was completely removed from water after 20 min of treatment under any of the experimental conditions assessed. High degradation percentages, between 89.83 and 100%, were achieved for ibuprofen, while carbamazepine shows the lowest degradation, ranging from 80.14 to 100%. In terms of global efficiency, a complete degradation was achieved when the concentration of the tested contaminants was similar to current concentration levels in urban wastewater effluents. The addition of the catalysts did not significantly improve the degradation rates.

Keywords

Advanced oxidation processes Emerging contaminants Heterogeneous photocatalysis Kinetics Pharmaceuticals Photo-Fenton Urban wastewater reuse 

Notes

Acknowledgements

This work was supported by EMASAGRA.

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Copyright information

© Islamic Azad University (IAU) 2019

Authors and Affiliations

  1. 1.Department of Civil Engineering and Institute of Water ResearchUniversity of GranadaGranadaSpain
  2. 2.Department of Chemical EngineeringUniversity of GranadaGranadaSpain

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