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Low-cost adsorbent prepared from poplar sawdust for removal of disperse orange 30 dye from aqueous solutions

  • U. Tezcan UnEmail author
  • F. Ates
Original Paper
  • 105 Downloads

Abstract

In this study, the applicability of char generated from poplar sawdust as an inexpensive adsorbent for the removal of a textile dye is investigated. Adsorbent samples were generated through pyrolysis at temperatures of 500, 600, 700 and 800 °C. The structural features of the char samples were illuminated by elemental analyses, FTIR, BET and SEM analyses. The effect of operating parameters such as initial dye concentration, pH and temperature were investigated and optimal values extracted. The adsorbent generated at 800 °C showed maximum adsorption efficiency of 83.4% at operating condition of pH 2, initial dye concentration of 50 ppm and temperature of 67 °C. We experimentally obtained equilibrium isotherms for the adsorption of the dye. The results were modeled using Langmuir, Freundlich and the Redlich–Peterson equations with corresponding parameters being determined. The mechanism was better represented by the Redlich–Peterson isotherm.

Keywords

Poplar sawdust Adsorbent Pyrolysis Isotherm Dye removal 

Notes

Acknowledgements

The authors wish to thank all who assisted in conducting this work.

References

  1. (2012) Outline for national reports on activities related to poplar and willow cultivation exploitation and utilization. National Poplar Commission of TurkeyGoogle Scholar
  2. Acar FN, Eren Z (2006) Removal of Cu(II) ions by activated poplar sawdust (Samsun Clone) from aqueous solutions. J Hazard Mater 137(2):909–914CrossRefGoogle Scholar
  3. Açıkalın K, Karaca F, Bolat E (2012) Pyrolysis of pistachio shell: effects of pyrolysis conditions and analysis of products. Fuel 95:169–177CrossRefGoogle Scholar
  4. Ahmad AA, Hameed BH, Ahmad AL (2009) Removal of disperse dye from aqueous solution using waste-derived activated carbon: optimization study. J Hazard Mater 170(2):612–619CrossRefGoogle Scholar
  5. Aksu Z, Dönmez G (2003) A comparative study on the biosorption characteristics of some yeasts for Remazol Blue reactive dye. Chemosphere 50(8):1075–1083CrossRefGoogle Scholar
  6. Aksu Z, Tatlı Aİ, Tunç Ö (2008) A comparative adsorption/biosorption study of Acid Blue 161: effect of temperature on equilibrium and kinetic parameters. Chem Eng J 142(1):23–39CrossRefGoogle Scholar
  7. Alhashimi HA, Aktas CB (2017) Life cycle environmental and economic performance of biochar compared with activated carbon: a meta-analysis. Resour Conserv Recycl 118(Suppl C):13–26CrossRefGoogle Scholar
  8. Arami-Niya A, Daud WMAW, Mjalli FS (2011) Comparative study of the textural characteristics of oil palm shell activated carbon produced by chemical and physical activation for methane adsorption. Chem Eng Res Des 89(6):657–664CrossRefGoogle Scholar
  9. Ates F, Tezcan Un U (2013) Production of char from hornbeam sawdust and its performance evaluation in the dye removal. J Anal Appl Pyrol 103(Suppl C):159–166CrossRefGoogle Scholar
  10. Ates F, Un UT (2013) Production of char from hornbeam sawdust and its performance evaluation in the dye removal. J Anal Appl Pyrol 103:159–166CrossRefGoogle Scholar
  11. Ateş F, Pütün AE, Pütün E (2006) Pyrolysis of two different biomass samples in a fixed-bed reactor combined with two different catalysts. Fuel 85(12):1851–1859Google Scholar
  12. Belhachemi M, Addoun F (2012) Adsorption of congo red onto activated carbons having different surface properties: studies of kinetics and adsorption equilibrium. Desalin Water Treat 37(1–3):122–129CrossRefGoogle Scholar
  13. Chan L, Cheung W, Allen S, McKay G (2012) Error analysis of adsorption isotherm models for acid dyes onto bamboo derived activated carbon. Chin J Chem Eng 20(3):535–542CrossRefGoogle Scholar
  14. Dawood S, Sen TK (2012) Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: equilibrium, thermodynamic, kinetics, mechanism and process design. Water Res 46(6):1933–1946CrossRefGoogle Scholar
  15. Fan S, Tang J, Wang Y, Li H, Zhang H, Tang J, Wang Z, Li X (2016) Biochar prepared from co-pyrolysis of municipal sewage sludge and tea waste for the adsorption of methylene blue from aqueous solutions: kinetics, isotherm, thermodynamic and mechanism. J Mol Liq 220:432–441CrossRefGoogle Scholar
  16. Freundlich H (1906) Über die adsorption in Lösungen. Z Phys Chem 57(57):385–470Google Scholar
  17. Frišták V, Micháleková-Richveisová B, Víglašová E, Ďuriška L, Galamboš M, Moreno-Jimenéz E, Pipíška M, Soja G (2017) Sorption separation of Eu and As from single-component systems by Fe-modified biochar: kinetic and equilibrium study. J Iran Chem Soc 14(3):521–530CrossRefGoogle Scholar
  18. Galhetas M, Mestre AS, Pinto ML, Gulyurtlu I, Lopes H, Carvalho AP (2014) Chars from gasification of coal and pine activated with K2CO3: acetaminophen and caffeine adsorption from aqueous solutions. J Colloid Interface Sci 433:94–103CrossRefGoogle Scholar
  19. Gan Q, Allen S, Matthews R (2004) Activation of waste MDF sawdust charcoal and its reactive dye adsorption characteristics. Waste Manag 24(8):841–848CrossRefGoogle Scholar
  20. Kaçan E, Kütahyalı C (2012) Adsorption of strontium from aqueous solution using activated carbon produced from textile sewage sludges. J Anal Appl Pyrol 97:149–157CrossRefGoogle Scholar
  21. Kim T-H, Park C, Shin E-B, Kim S (2004) Decolorization of disperse and reactive dye solutions using ferric chloride. Desalination 161(1):49–58CrossRefGoogle Scholar
  22. Koh J (2011) Dyeing with disperse dyes. Textile Dyeing, InTechGoogle Scholar
  23. Kong L, Xiong Y, Tian S, Luo R, He C, Huang H (2013) Preparation and characterization of a hierarchical porous char from sewage sludge with superior adsorption capacity for toluene by a new two-step pore-fabricating process. Bioresour Technol 146:457–462CrossRefGoogle Scholar
  24. Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40(9):1361–1403CrossRefGoogle Scholar
  25. Lehmann J, Gaunt J, Rondon M (2006) Bio-char sequestration in terrestrial ecosystems—a review. Mitig Adapt Strat Glob Change 11(2):403–427CrossRefGoogle Scholar
  26. Leyva-Ramos R, Rivera-Utrilla J, Medellin-Castillo N, Sanchez-Polo M (2010) Kinetic modeling of fluoride adsorption from aqueous solution onto bone char. Chem Eng J 158(3):458–467CrossRefGoogle Scholar
  27. Liu Z, Zhang F-S, Wu J (2010) Characterization and application of chars produced from pinewood pyrolysis and hydrothermal treatment. Fuel 89(2):510–514CrossRefGoogle Scholar
  28. Lu G, Low J, Liu C, Lua A (1995) Surface area development of sewage sludge during pyrolysis. Fuel 74(3):344–348CrossRefGoogle Scholar
  29. Lucaci D, Duţă A (2009) Comparative adsorption of copper on oak, poplar and willow sawdust. Bull Transilv Univ Braşov 2:51Google Scholar
  30. Martins AF, Cardoso ADL, Stahl JA, Diniz J (2007) Low temperature conversion of rice husks, eucalyptus sawdust and peach stones for the production of carbon-like adsorbent. Biores Technol 98(5):1095–1100CrossRefGoogle Scholar
  31. Medellin-Castillo N, Leyva-Ramos R, Padilla-Ortega E, Perez RO, Flores-Cano J, Berber-Mendoza M (2014) Adsorption capacity of bone char for removing fluoride from water solution. Role of hydroxyapatite content, adsorption mechanism and competing anions. J Ind Eng Chem 20(6):4014–4021CrossRefGoogle Scholar
  32. Mohan D, Sarswat A, Ok YS, Pittman CU (2014) Organic and inorganic contaminants removal from water with biochar, a renewable, low cost and sustainable adsorbent–a critical review. Bioresour Technol 160:191–202CrossRefGoogle Scholar
  33. Mui EL, Cheung W, Valix M, McKay G (2010) Dye adsorption onto char from bamboo. J Hazard Mater 177(1):1001–1005CrossRefGoogle Scholar
  34. Poinern GEJ, Senanayake G, Shah N, Thi-Le XN, Parkinson GM, Fawcett D (2011) Adsorption of the aurocyanide, complex on granular activated carbons derived from macadamia nut shells—a preliminary study. Miner Eng 24(15):1694–1702CrossRefGoogle Scholar
  35. Rajec P, Rosskopfová O, Galamboš M, Frišták V, Soja G, Dafnomili A, Noli F, Đukić A, Matović L (2016) Sorption and desorption of pertechnetate on biochar under static batch and dynamic conditions. J Radioanal Nucl Chem 310(1):253–261CrossRefGoogle Scholar
  36. Redlich O, Peterson DL (1959) A useful adsorption isotherm. J Phys Chem 63(6):1024CrossRefGoogle Scholar
  37. Šćiban M, Klašnja M (2003) Optimization of usage of wood sawdust as adsorbent of heavy metal ions from water. ISIRR 3:51–56Google Scholar
  38. Singh KP, Mohan D, Sinha S, Tondon G, Gosh D (2003) Color removal from wastewater using low-cost activated carbon derived from agricultural waste material. Ind Eng Chem Res 42(9):1965–1976CrossRefGoogle Scholar
  39. Viglašová E, Daňo M, Galamboš M, Rosskopfová O, Rajec P, Novák I (2016) Column studies for the separation of 99mTc using activated carbon. J Radioanal Nucl Chem 307(1):591–597CrossRefGoogle Scholar
  40. Weng C-H, Lin Y-T, Tzeng T-W (2009) Removal of methylene blue from aqueous solution by adsorption onto pineapple leaf powder. J Hazard Mater 170(1):417–424CrossRefGoogle Scholar
  41. Wong Y, Szeto Y, Cheung W, McKay G (2004) Adsorption of acid dyes on chitosan—equilibrium isotherm analyses. Process Biochem 39(6):695–704CrossRefGoogle Scholar
  42. Yagub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Coll Interface Sci 209:172–184CrossRefGoogle Scholar
  43. Yi S, Gao B, Sun Y, Wu J, Shi X, Wu B, Hu X (2016) Removal of levofloxacin from aqueous solution using rice-husk and wood-chip biochars. Chemosphere 150:694–701CrossRefGoogle Scholar

Copyright information

© Islamic Azad University (IAU) 2018

Authors and Affiliations

  1. 1.Department of Environmental EngineeringAnadolu UniversityEskisehirTurkey
  2. 2.Department of Chemical EngineeringAnadolu UniversityEskisehirTurkey

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