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New, stable and reusable magnetic Fe3O4/PEG@CPTMS-thioaminophenol@Ni nanocatalyst for the synthesis of dispiro-cyclopropanes’s Meldrum’s acid

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Abstract

Magnetic Fe3O4/PEG@CPTMS-thioaminophenol@Ni nanocatalyst as a heterogeneous, stable and reusable nanocatalyst was formed. This nanocatalyst was characterized by FT-IR, XRD, TGA, ICP, SEM, EDS and VSM techniques and was used for six times without decreasing activity. This nanocatalyst was used successfully for the synthesis of 3,3,10,10-tetramethyl-13-aryl(alkyl)-2,4,9,11-tetraoxadispiro[5.0.57.16]tridecane-1,5,8,12-tetraones (dispiro-cyclopropane’s based on Meldrum’s acid) by the reaction of various aldehydes and Meldrum’s acid in the presence of triethylamine and cyanogen bromide in excellent yield.

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Correspondence to Nader Noroozi Pesyan.

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Noroozi Pesyan, N., Bibak, S. & Aalinejad, M. New, stable and reusable magnetic Fe3O4/PEG@CPTMS-thioaminophenol@Ni nanocatalyst for the synthesis of dispiro-cyclopropanes’s Meldrum’s acid. J IRAN CHEM SOC 17, 411–422 (2020). https://doi.org/10.1007/s13738-019-01775-3

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Keywords

  • Fe3O4
  • Dispiro-cyclopropane
  • Meldrum’s acid
  • 2-Amino thiophenol