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Synthesis of pyrazol-quinazolinones and 2,3-dihydroquinazolin-4(1H)-ones using CoAl2O4 nanoparticles as heterogeneous catalyst

  • Fatemeh Ahmadian
  • Alireza Barmak
  • Esmali Ghaderi
  • Masoumeh Bavadi
  • Hossein Raanaei
  • Khodabakhsh NiknamEmail author
Original Paper
  • 10 Downloads

Abstract

The preparation and characterization of cobalt aluminate (CoAl2O4) magnetic nanoparticles and its application as a catalyst for the synthesis of a novel class of pyrazol-quinazolinones and 2,3-dihydroquinazolin-4(1H)-ones is described. The structure of the catalyst was studied by Fourier transform infrared spectroscopy, transmission electron microscopy, X-ray diffraction, and vibrating sample magnetometer analysis. The resulting cobalt aluminate (CoAl2O4) was an efficient catalyst and affords the desired products in good to excellent yields. Moreover, the catalyst could be easily recovered by magnetic separation and recycled for four times without significant loss of its catalytic activity.

Graphic abstract

2,3-Dihydroquinazolin-4(1H)-ones and a novel class of pyrazol-quinazolinones were synthesized through one-pot condensation reaction of isatoic anhydride, aromatic aldehydes, and amines using CoAl2O4 as nanoparticle heterogeneous catalyst in refluxing ethanol.

Keywords

CoAl2O4 nanoparticles Pyrazol-quinazolinones Heterogeneous catalyst Isatoic anhydride 2,3-Dihydroquinazolinones 

Notes

Acknowledgements

We are thankful to Persian Gulf University Research Council for partial support of this work.

Supplementary material

13738_2019_1729_MOESM1_ESM.doc (11.9 mb)
Supplementary material 1 (DOC 12206 kb)

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Copyright information

© Iranian Chemical Society 2019

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of SciencesPersian Gulf UniversityBushehrIran
  2. 2.Faculty of ChemistryBu-Ali Sina UniversityHamedanIran
  3. 3.Department of Physics, Faculty of SciencesPersian Gulf UniversityBushehrIran

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