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Magnetic mesoporous poly-melamine–formaldehyde: an efficient and recyclable catalyst for straightforward one-pot synthesis of imidazo[1,2-a]pyridines

  • Mohammad Heydari
  • Najmedin AziziEmail author
  • Zohreh Mirjafari
  • Mohammad Mahmoudi Hashemi
Original Paper
  • 11 Downloads

Abstract

Magnetically separable mesoporous poly-melamine–formaldehyde nanocomposite (Fe3O4@mPMF) has been synthesized and characterized by FTIR spectroscopy, SEM, XRD spectroscopy and EDS. The magnetically separable Fe3O4@mPMF catalyst had excellent efficiency for the synthesis a wide diversity of imidazo[1,2-a]pyridines by a three-component reaction of a 2-aminopyridine, aldehyde and isocyanide in good-to-excellent yields within a short reaction time, through an environmental friendliness and straightforward procedure. The nanocomposite that is easily recoverable and also found to be reusable can be recovered and reused when the reaction is completed for several times without distinct deterioration in catalytic activity.

Graphic abstract

Keywords

Fe3O4@mPMF Groebke reaction Imidazo[1,2-a]pyridines Green chemistry Isocyanide reaction 

Notes

Acknowledgements

The financial support of this work provided by Chemistry and Chemical Engineering Research Center of Iran and Science and Research Branch of Islamic Azad University is gratefully appreciated.

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Copyright information

© Iranian Chemical Society 2019

Authors and Affiliations

  • Mohammad Heydari
    • 1
  • Najmedin Azizi
    • 2
    Email author
  • Zohreh Mirjafari
    • 1
  • Mohammad Mahmoudi Hashemi
    • 1
  1. 1.Department of Chemistry, Science and Research BranchIslamic Azad UniversityTehranIran
  2. 2.Chemistry and Chemical Engineering Research Center of IranTehranIran

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