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Journal of the Iranian Chemical Society

, Volume 16, Issue 2, pp 385–392 | Cite as

Fabrication of ZIF-8 based on lignin with high yield for dye removal from water

  • Wenjing XuEmail author
  • Yizhen Chen
  • Jianxun Kang
  • Baojun Li
Original Paper
  • 37 Downloads

Abstract

The hybrid nanocomposites ZIF@L composed of Zn-based MOFs (ZIF-8) and lignin were successfully synthesized via a simple one-step method at room temperature. The yield of the hybrid nanocomposites ZIF@L were up to 52% and the synthesis time was greatly shortened. Characterization using FT-IR, XRD, SEM and N2-sorption analysis indicated that ZIF@L composites exhibited rhombic dodecahedral structure such as the parent ZIF-8 synthesized in the absence of lignin and the incorporation of lignin did not destroy the framework integrity of ZIF-8. The ZIF@L composites were used to remove methyl violet (MV). The ZIF@L nanocomposites had a remarkable improvement in adsorption capacity of MV compared with the parent ZIF-8. The modified Langmuir model fitted better the equilibrium data of MV adsorption on the ZIF@L-4 composite and the maximum adsorption capacity of MV is 1001.2 mg g−1. The pseudo-second-order model could describe well the kinetics process of MV dye onto the prepared adsorbents.

Keywords

Metal–organic frameworks ZIF-8 Lignin Adsorption Dye 

Notes

Acknowledgements

This work was supported by Foundation of Henan Scientific and Technological Committee (no. 182102210420).

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Copyright information

© Iranian Chemical Society 2018

Authors and Affiliations

  1. 1.School of ScienceJiaozuo Engineering Technology Research Center of Separation and Adsorption Materials, Jiaozuo Teachers CollegeJiaozuoPeople’s Republic of China
  2. 2.College of Chemistry and Molecular EngineeringZhengzhou UniversityZhengzhouPeople’s Republic of China

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