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Journal of the Iranian Chemical Society

, Volume 16, Issue 2, pp 293–299 | Cite as

Nickel-catalyzed denitrative etherification of activated nitrobenzenes

  • Fatemeh Zamiran
  • Arash GhaderiEmail author
Original Paper
  • 40 Downloads

Abstract

Electron-deficient nitrobenzenes were coupled with phenols/alcohols to form diaryl/alkyl aryl ethers by the aid of NiCl2 as the catalyst. The reactions were conducted under ligand- and oxidant-free conditions without the exclusion of air or moisture. The initial studies upon the mechanism of the reaction revealed two solvent-dependent approaches. In molten TBAB, SNAr mechanism seems to be predominated, while, in DMF, the reaction might include the radical species.

Keywords

Denitrative etherification Cross coupling Nickel Nitrobenzenes Green conditions 

Notes

Acknowledgements

The authors are thankful to INSF (Grant number: 95825781) and University of Hormozgan research council for the financial support.

Supplementary material

13738_2018_1510_MOESM1_ESM.docx (517 kb)
Supplementary material 1 (DOCX 516 KB)

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Copyright information

© Iranian Chemical Society 2018

Authors and Affiliations

  1. 1.Department of Chemistry, College of SciencesUniversity of HormozganBandar AbbasIran

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