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Journal of the Iranian Chemical Society

, Volume 16, Issue 2, pp 219–229 | Cite as

Fe(III)–oxalate-mediated solar degradation of furfural in the presence of persulfate: operational parameters and artificial neural network modeling

  • Ali Akbar Babaei
  • Ali Reza Rahmani
  • Fahime Zamani
  • Halime AlmasiEmail author
Original Paper
  • 51 Downloads

Abstract

Furfural is an organic matter which is commonly used in solid resin plastic production and paper manufacturing. In this study, the removal of furfural was carried out using oxalate (OX) and activated persulfate (PS) with Fe(III). The effect of pH, Fe(III) dosage, OX ion dosage, species radicals, the molar ratio of citric acid, coexisting substances, environmental applications, reaction mechanisms, and intermediates compound on the removal of furfural were investigated. In addition, artificial neural network (ANN) model was designed to determine the optimum value and importance of the effective variables to attain the higher efficiency. This study indicates the application of ANN for prediction of performances in competitive advance oxidation process. Intermediate compounds were identified, including ferulic acid –CO2, 2-furfural, oxime-, methoxy-phenyl, 2,2′-bifuran, and cyclohexasiloxane. The higher degradation efficiency was 85.8%, which was obtained at furfural 40 mg/L, Fe 0.002 g, PS 0.05 g, pH 4, and the molar ratio of citric acid: 1:1. Comparison between the photodegradation efficiency of experimental results and the predicted results of the designed ANN models showed that both processes have almost equal efficiency.

Graphical abstract

Keywords

Oxalate Fe(III) Furfural Solar Persulfate Neural network 

Abbreviations

AOPs

Advanced oxidation processes

ISCO

In situ chemical oxidation

SRAOPs

Sulfate radical-based advanced oxidation processes

PS

Persulfate

SO4−·

Sulfate radical

EtOH

Ethanol

T-BuOH (TBA)

Tert-butyl alcohol

CA

Citric acid

NOM

Natural organic matters

OH·

Hydroxyl radical

Notes

Acknowledgements

This research was sponsored by the Research Department at Ahvaz Jundishapur University of Medical Sciences (Grant number: 95s91). The researchers express their heartfelt gratitude to everyone involved in this study.

Compliance with ethical standards

Conflict of interest

The authors declare that there are no conflicts of interest.

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Copyright information

© Iranian Chemical Society 2018

Authors and Affiliations

  • Ali Akbar Babaei
    • 1
  • Ali Reza Rahmani
    • 2
  • Fahime Zamani
    • 2
  • Halime Almasi
    • 1
    Email author
  1. 1.Department of Environmental Health Engineering, Student Research CommitteeAhvaz Jundishapur University of Medical SciencesAhvazIran
  2. 2.Department of Environmental Health Engineering, Faculty of Health and Research Center for Health SciencesHamadan University of Medical ScienceHamadanIran

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