One-pot synthesized porphyrin-based polymer supported gold nanoparticles as efficient catalysts for alkyne hydration and alcohol oxidation in water
- 42 Downloads
The construction of porous organic polymer from 5,10,15,20-tetraphenylporphyrin (TPP) was described using one-pot Friedel-Crafts alkylation reaction. Au was simultaneously loaded on the porphyrin-based polymer denoted as Au/KAPs(DCM-TPP). This polymer-supported Au was fully characterized by many physicochemical methods. It was found to possess BET surface area of 796 m2 g−1, good thermal stability above 250 °C and Au nanoparticles with an average size of 8 nm. It was used as an efficient heterogeneous catalyst for alkyne hydration and alcohol oxidation in water. This Au catalyst exhibited excellent catalytic efficiency and recycling performance without loss of activity at least five times. A new strategy to synthesize polymer-supported Au nanoparticle catalyst was finally provided.
KeywordsPorphyrin-based polymer Gold nanoparticles Alkyne hydration Alcohol oxidation
We are also grateful to the Analytical and Testing Center of Huazhong University of Science and Technology, ATC School of Chemistry and Chemical Engineering, HUST, Wuhan, China.
This work was supported by the National Natural Science Foundation of China (21473064) and Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education Foundation (CHCL15001).
- 23.Dou Z, Xu L, Zhi Y, Zhang Y, Xia H, Mu Y, Liu X (2016) Metalloporphyrin-based hypercrosslinked polymers catalyze hetero-Diels–Alder reactions of unactivated aldehydes with simple dienes: a fascinating strategy for the construction of heterogeneous catalysts. Chem Eur J 22:9919–9922CrossRefGoogle Scholar
- 31.Schieβl J, Schulmeister J, Doppiu A, Wörner E, Rudolph M, Karch R, Hashmi ASK (2018) An industrial perspective on counter anions in gold catalysis: on alternative counter anions. Adv Synth Catal 360:3949−3959Google Scholar