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Arabian Journal for Science and Engineering

, Volume 44, Issue 1, pp 111–121 | Cite as

Fabrication of Zinc Oxide/Polypyrrole Nanocomposites for Brilliant Green Removal from Aqueous Phase

  • Mengmeng ZhangEmail author
  • Liangliang Chang
  • Yuanyuan Zhao
  • Zehao Yu
Research Article - Chemistry
  • 52 Downloads

Abstract

Zinc oxide/polypyrrole (ZnO/PPy) nanocomposites were fabricated by a in situ polymerization method. The structures of the nanocomposites were analyzed by X-ray diffraction, Fourier transform infrared spectra, thermogravimetric analysis and transmission electron spectroscopy. Then, the capability of ZnO/PPy on the removal of brilliant green from aqueous phase was systematically studied. The ZnO/PPy showed high adsorption capacity toward brilliant green, and a maximum adsorption capacity of 140.8 mg/g at room temperature was achieved. The adsorption kinetics demonstrated a rapid brilliant green uptake by ZnO/PPy, and the experimental data were well fitted to the pseudo-second-order model. The equilibrium data obeyed the Langmuir model. Thermodynamic parameters of \(\Delta {G}^{0}\) and \(\Delta {H}^{0}\) verified the spontaneous and endothermic nature of the brilliant green adsorption onto ZnO/PPy. Furthermore, the regeneration experiments revealed that ZnO/PPy could be reused for at least five times without considerable decrease in their original adsorption capacity, showing potential applications in purification of dyeing effluents.

Keywords

Zinc oxide Polypyrrole Adsorption Brilliant green 

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Copyright information

© King Fahd University of Petroleum & Minerals 2018

Authors and Affiliations

  • Mengmeng Zhang
    • 1
    Email author
  • Liangliang Chang
    • 2
  • Yuanyuan Zhao
    • 2
  • Zehao Yu
    • 1
  1. 1.State Key Laboratory Breeding Base of Nuclear Resources and Environment, School of Chemical Biology and Materials ScienceEast China University of TechnologyNanchangPeople’s Republic of China
  2. 2.College of Chemical Engineering and Modern MaterialsShangluo UniversityShangluoPeople’s Republic of China

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