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Sulfonated Cross-Linked Poly(ether ether ketone) Films with Wrinkled Structures: Preparation and Vanadium Ions Permeability

  • Abdul G. Al LafiEmail author
  • Reem Hasan
  • Nedal Al-Kafri
Article
  • 7 Downloads

Abstract

Wrinkling patterns were fabricated by sulfonation of ion irradiated poly(ether ether ketone) (PEEK). A variety of wrinkling patterns in the micrometer to sub-micrometer range were observed and were controlled by the adsorbed dose and dose rate of the irradiated ions as well as the sulfonation time. Because of the properties of these micro-textured membranes, they are promising for a broad range of applications. In particular, the cross-linked membranes had a very low permeability of vanadium ions, i.e. 1.5 × 10−7 cm2 min−1 due to their wrinkled structures in combination with the Donnan exclusive effect.

Keywords

ion irradiation sulfonation poly(ether ether ketone) wrinkled structure permeability vanadium ion 

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Notes

Acknowledgments

The authors thank Prof. James N. Hay and Prof. David J. Parker for allowing the use of irradiation facility. Thanks are also due to Prof. I. Othman; the DG of the AEC of Syria and Prof. Z Ajji the Head of Chemistry Department for their support. The authors would also like to thank T. Hassan and J. Abo Hlal for their technical supports.

Supplementary material

13233_2019_7166_MOESM1_ESM.pdf (414 kb)
Calculation of degree of sulfonation, DS and the ion exchange capacity, IEC from 1H NMR spectra

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Copyright information

© The Polymer Society of Korea and Springer 2019

Authors and Affiliations

  1. 1.Department of ChemistryAtomic Energy CommissionDamascusSyrian Arab Republic
  2. 2.Department of PhysicsAtomic Energy CommissionDamascusSyrian Arab Republic

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