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Surface-enhanced Raman scattering (SERS) performance on salbutamol detection of colloidal multi-shaped silver nanoparticles

  • Tri Bao Ngoc Pham
  • Thi Thu Thao Bui
  • Vinh Quoc Tran
  • Vinh Quang Dang
  • Long Nguyen Hoang
  • Cong Khanh TranEmail author
Original Article
  • 12 Downloads

Abstract

Monitoring the surface-enhanced Raman scattering (SERS) ability of multi-shaped silver nanoparticles (MAgNPs) in comparison with silver nanospheres (AgNSs), we carried out the synthesis of MAgNPs from the AgNS seeds via the etching-growth process. The MAgNPs contained diverse anisotropic shapes such as hexagonal, circular, triangular and deformed plates as well as particles in the wide range of sizes from 30 to 250 nm. The SERS spectra of salbutamol (Sal) in the presence of colloid MAgNPs, showing higher sensitivity than AgNSs with a minimum detectable concentration of Sal, was determined at 2.5 and 1.25 ng/µL with colloid MAgNPs on glass and Si/SiO2 substrates, respectively. These results pointed out the shape of silver nanoparticles (AgNPs) and their plasmonic resonance strongly affected by SERS performance. This study contributed to the development of the further facile and low-cost method for the SERS detection of Sal based on AgNPs.

Keywords

Surface-enhanced Raman scattering Multi-shaped silver nanoparticles Salbutamol Colloid Anisotropic 

Abbreviations

SERS

Surface-enhanced Raman scattering

Sal

Salbutamol

NPs

Nanoparticles

MAgNPs

Multi-shaped silver nanoparticles

AgNPs

Silver nanoparticles

AgNSs

Silver nanospheres

TEM

Transmission electron microscopy

UV–Vis

Ultraviolet–visible

DI

Deionized

ICP-MS

Inductively coupled plasma-mass spectrometer

MO

Methyl orange

XRD

X-ray diffraction

δ

Bending vibration

ν

Stretching vibration

ν

Raman shift

RSD

The standard deviation

EF

Enhancement factor

ζ potential

Zeta potential

Notes

Acknowledgements

The authors acknowledge Mr. Khang Duy Vu Nguyen, Institute of Applied Material Science in HCM city for his help and good advice in all measurements also useful discussions in data analyses of Raman spectra and ICP-MS results. The many thanks would be given to Prof. Van Thanh Thi Tran, the University of Science in HCM city for material support. This research is funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under Grant number 103.03-2018.59.

Author contributions

The authors contributed equally in the manuscripts.

Compliance with ethical standards

Conflict of interest

The authors declare no competing of interests.

Supplementary material

13204_2019_1154_MOESM1_ESM.docx (2.6 mb)
Supplementary material 1 (DOCX 2700 kb)

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Copyright information

© King Abdulaziz City for Science and Technology 2019

Authors and Affiliations

  • Tri Bao Ngoc Pham
    • 1
  • Thi Thu Thao Bui
    • 1
  • Vinh Quoc Tran
    • 1
  • Vinh Quang Dang
    • 1
  • Long Nguyen Hoang
    • 2
  • Cong Khanh Tran
    • 1
    Email author
  1. 1.University of ScienceHo Chi Minh CityVietnam
  2. 2.International UniversityHo Chi Minh CityVietnam

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