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Fabrication of room temperature liquid petroleum gas sensor based on PAni–CNT–V2O5 hybrid nanocomposite

  • Heiner Albaris
  • Gurunathan KaruppasamyEmail author
Original Article
  • 4 Downloads

Abstract

Vanadium pentoxide (V2O5) nanoparticles have been synthesized by hydrothermal method. Polyaniline (PAni)—carbon nanotube (CNT)—V2O5 hybrid nanocomposite has synthesized by chemical polymerization of PAni in the presence of CNT—V2O5 nanocomposite. The band gap energy of the hybrid nanocomposite is calculated as 3.02 eV using UV–Vis absorption spectroscopy. Chemical composition and crystalline nature has been analyzed using fourier transform infrared spectroscopy and X-ray diffraction spectroscopy, respectively. Scanning electron microscope and transmission electron microscope are involved in the morphological analysis of the hybrid nanocomposite. Sensing electrodes are fabricated by spin coating of the sensing material on printed circuit board. The electrodes have been investigated for their sensing behavior towards oxygen, hydrogen and liquid petroleum gas (LPG) at room temperature. It has been observed that the electrode is selectively sensitive to the LPG with improved sensitivity (300%), response time (20 s) and recovery time (15 s) in the range of 10–50 ppm. The reproducibility of the response curve of the electrode is tested and it is 83.33% stable for the period of 50 days.

Keywords

Polyaniline Carbon nanotube Vanadium pentoxide Hybrid nanocomposite LPG sensing 

Notes

Acknowledgements

We gratefully acknowledge DST-PURSE and RUSA-II for their financial support in the form fellowship and other infrastructure, respectively.

References

  1. Adarsh Kaniyoor R, Imran Jafri T, Arockiadoss S, Ramaprabhu (2009) Nanostructured Pt decorated graphene and multi walled carbon nanotube based room temperature hydrogen gas sensor. Nanoscale 1:382–386.  https://doi.org/10.1039/b9nr00015a CrossRefGoogle Scholar
  2. Afsar MF, Rafiq MA, Tok AIY (2017) Two-dimensional SnS nanoflakes: synthesis and application to acetone and alcohol sensors. RSC Adv 7:21556.  https://doi.org/10.1039/c7ra03004e CrossRefGoogle Scholar
  3. Alkhatib MF, Mirghani ME, Qudsieh IY, Husain IA (2010) Immobilization of chitosan onto carbon nano tube for lead removal from water. J Appl Sci 10:2705–2708CrossRefGoogle Scholar
  4. Ates M, Karazehir T, Sezai Sarac A (2012) Conducting polymers and their applications. Curr Phys Chem 2:224–240.  https://doi.org/10.4028/www.scientific.net/MSF.42.207 CrossRefGoogle Scholar
  5. Barkade SS, Pinjari DV, Singh AK, Gogate PR, Naik JB, Sonawane SH, Ashokkumar M, Pandit AB (2013) Ultrasound assisted miniemulsion polymerization for preparation of polypyrrole–Zinc oxide (PPy/ZnO) functional latex for liquefied petroleum gas sensing. Ind Eng Chem Res 52:7704–7712.  https://doi.org/10.1021/ie301698g CrossRefGoogle Scholar
  6. Bulakhe RN, Patil SV, Deshmukh PR, Shinde NM, Lokhande CD (2013) Fabrication and performance of polypyrrole (Ppy)/TiO2 heterojunction for room temperature operated LPG sensor. Sens Actuators B 181:417–423.  https://doi.org/10.1016/j.snb.2013.01.056 CrossRefGoogle Scholar
  7. Carotta MC, Ferroni M, Gherardi S, Guidi V, Malagu` C, Martinelli G, Sacerdoti M, Di Vona ML, Licoccia S (2004) Thick-film gas sensors based on vanadium–titanium oxide powders prepared by sol–gel synthesis. J Eur Ceramic Soc 24:1409–1413.  https://doi.org/10.1016/S0955-2219(03)00418-7 CrossRefGoogle Scholar
  8. Dall’Acqua L, Tonin C, Peila R, Ferrero F, Catellani M (2004) Performances and properties of intrinsic conductive cellulose–polypyrrole textiles. Synth Met 146:213–221.  https://doi.org/10.1016/j.synthmet.2004.07.005 CrossRefGoogle Scholar
  9. Datsyuk V, Kalyva M, Papagelis K, Parthenios J, Tasis D, Siokou A, Kallitsis I, Galiotis C (2008) Chemical oxidation of multiwalled carbon nanotubes. CARBON 46:833–840.  https://doi.org/10.1016/j.carbon.2008.02.012 CrossRefGoogle Scholar
  10. Dexmer J, Leroy CM, Binet L, Heresanu V, Launois P, Steunou N, Coulon C, Maquet J, Brun N, Livage J, Backov R (2008) Vanadium oxide–PAni Nanocomposite-based macroscopic fibers: 1D alcohol sensors bearing enhanced toughness. Chem Mater 20:5541–5549.  https://doi.org/10.1021/cm800886v CrossRefGoogle Scholar
  11. Dhawale DS, Salunkhe RR, Patil UM, Gurav KV, More AM, Lokhande CD (2008) Room temperature liquefied petroleum gas (LPG) sensor based on p-polyaniline/n-TiO2 heterojunction. Sens Actuators B 134:988–992.  https://doi.org/10.1016/j.snb.2008.07.003 CrossRefGoogle Scholar
  12. Divya Haridas V, Gupta K, Sreenivas (2008) Enhanced catalytic activity of nanoscale platinum islands loaded onto SnO2 thin film for sensitive LPG gas sensors. Bull Mater Sci 31:397–400.  https://doi.org/10.1007/s12034-008-0062-9 CrossRefGoogle Scholar
  13. Farahmandjou M, Abaeiyan N (2017) Chemical synthesis of vanadium oxide (V2O5) nanoparticles prepared by sodium metavanadate. J Nanomed Res 5:00103CrossRefGoogle Scholar
  14. Fu H, Jiang X, Yang X, Yu A, Su D, Wang G (2012) Glycothermal synthesis of assembled vanadium oxide nanostructures for gas sensing. J Nanopart Res 14:871.  https://doi.org/10.1007/s11051-012-0871-z CrossRefGoogle Scholar
  15. Gadyal MA, K.S.Venkatesh (2016) Nonionic surfactant impact on polyaniline-graphite nanocomposites. J Appl Phys 8:62–65.  https://doi.org/10.9790/4861-0802016265 Google Scholar
  16. Huang J, Virji S, Weiller BH, Kaner RB (2002) Polyaniline Nanofibers: facile synthesis and chemical sensors. J Am Chem Soc 125:314–315.  https://doi.org/10.1021/ja028371y CrossRefGoogle Scholar
  17. Huiling Tai Y, Jiang G, Xie J, Yu X, Chen (2007) Fabrication and gas sensitivity of polyaniline–titanium dioxide nanocomposite thin film. Sens Actuators B 125:644–650.  https://doi.org/10.1016/j.snb.2007.03.013 CrossRefGoogle Scholar
  18. Jang WK, Yun J, Kim H-I, Lee Y-S (2012) Improvement in ammonia gas sensing behavior by polypyrrole/multi-walled carbon nanotubes composites. Carbon Lett 13:88–93.  https://doi.org/10.5714/CL.2012.13.2.088 CrossRefGoogle Scholar
  19. Junfeng Liu X, Wang Q, Peng Y, Li (2005a) Vanadium pentoxide nanobelts: highly selective and stable ethanol sensor materials. Adv Mater 17:764–767.  https://doi.org/10.1002/adma.200400993 CrossRefGoogle Scholar
  20. Junfeng Liu X, Wang Q, Peng Y, Li (2005b) Vanadium pentoxide nanobelts: highly selective and staable ethanol sensor materials. Adv Mater 17:764–767.  https://doi.org/10.1016/j.snb.2005.10.012 CrossRefGoogle Scholar
  21. Kondawar SB, Patil PT, Agrawal SP (2014) Chemical vapour sensing properties of electrospun nanofibers of polyaniline/ ZnO nanocomposites. Adv Mat Lett 5:389–395.  https://doi.org/10.5185/amlett.2014.amwc.1037 CrossRefGoogle Scholar
  22. Lin Jin J, Li L, Liu Z, Wang X, Zhang (2018) Facile synthesis of carbon dots with superior sensing ability. Appl Nanosci.  https://doi.org/10.1007/s13204-018-0755-3 Google Scholar
  23. Machappa T, Sasikala M, Ambika Prasad MVN (2010) Design of gas sensor setup and study of gas (LPG) sensing behavior of conducting polyaniline/magnesium chromate (MgCrO4) composites. IEEE Sens J 10:807–813.  https://doi.org/10.1109/JSEN.2009.2034627 CrossRefGoogle Scholar
  24. Mahalingam Shanmugam A, Alsalme A, Alghamdi, Jayavel R (2015) Enhanced photocatalytic performance of the graphene–V2O5 nanocomposite in the degradation of methylene blue dye under direct sunlight. ACS Appl Mater Interfaces 7:14905–14911.  https://doi.org/10.1021/acsami.5b02715 CrossRefGoogle Scholar
  25. Majid Farahmandjou N Abaeyan (2016) Simple Synthesis of Vanadium Oxide (V2O5) Nanorods in Presence of CTAB Surfactant. Colloid Surface Science 1:10–13.  https://doi.org/10.11648/j.css.20160101.13 Google Scholar
  26. Manoj K, Ram O, Yavuz M, Aldissi (2005) NO2 gas sensing based on ordered ultrathin films of conducting polymer and its nanocomposite. Synth Met 151:77–84.  https://doi.org/10.1016/j.synthmet.2005.03.021 CrossRefGoogle Scholar
  27. Martínez-Barrera FNavarro-Pardo,G, Martínez-Hernández AL, Castaño VM, Rivera-Armenta JL, Medellín-Rodríguez F, Velasco-Santos C (2013) Effects on the thermo-mechanical and crystallinity properties of nylon 6,6 electrospun fibres reinforced with one dimensional (1D) and two dimensional (2D). Carbon Mater 6:3494–3513  https://doi.org/10.3390/ma6083494 Google Scholar
  28. Mohammed Afzal, PSNaik, SS.Suryavanshi, LINadaf (2015) Design and fabrication of low cost and miniaturized setup for gas sensor. J Appl Phys 7:39–45.  https://doi.org/10.9790/4861-07233945 Google Scholar
  29. Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205.  https://doi.org/10.1021/ma060733p CrossRefGoogle Scholar
  30. Qin Y, Liu GFan,K, Ming Hu (2014) Vanadium pentoxide hierarchical structure networks for high performance ethanol gas sensor with dual working temperature characteristic. Sens Actuators B 190:141–148.  https://doi.org/10.1016/j.snb.2013.08.061 CrossRefGoogle Scholar
  31. Ram MK, Yavuz O, Lahsangah V, Aldissi M (2005) CO gas sensing from ultrathin nano-composite conducting polymer film. Sens Actuators B 106:750–757.  https://doi.org/10.1016/j.snb.2004.09.027 CrossRefGoogle Scholar
  32. Ramanujan ATesRKannan, Thangavel S, Gopalakrishan S, Raghavan N, Venugopal G (2015) Facile synthesis of vanadium-pentoxide nanoparticles and study on their electrochemical, photocatalytic properties. J Nanosci Nanotechnol 15:3802–3808.  https://doi.org/10.1166/jnn.2015.9543 CrossRefGoogle Scholar
  33. Richa S (2014) Nanocomposite ZnNb2O6 thick film as room temperature liquefied petroleum gas (LPG) sensor. Am J Sens Tech 2:25–28.  https://doi.org/10.12691/ajst-2-2-3 Google Scholar
  34. Sharada Thakur P Patil (2016) Enhanced LPG sensing-performance at room temperature of poly (o-anisidine)-CeO2 nanocomposites. RSC Adv 6:45768–45782.  https://doi.org/10.1039/C6RA02955H CrossRefGoogle Scholar
  35. Swati Sharma M Madou (2012) A new approach to gas sensing with nanotechnology. Phil Trans R Soc A 370:2448–2473.  https://doi.org/10.1098/rsta.2011.0506 CrossRefGoogle Scholar
  36. Tao Qian X, Zhou C, Yu S, Wu J, Shen (2013) Highly dispersed carbon nanotube/polypyrrole core/shell composites with improved electrochemical capacitive performance. J Mater Chem A 1:15230.  https://doi.org/10.1039/c3ta13624h CrossRefGoogle Scholar
  37. Vasilios Georgakilas P, Dallas D, Niarchos N, Boukos C Trapalis (2009) Polypyrrole/MWNT nanocomposites synthesized through interfacial polymerization. Synth Met 159:632–636.  https://doi.org/10.1016/j.synthmet.2008.12.007 CrossRefGoogle Scholar
  38. Zhao X, Zhang Z, Yang F, Fu Y, Lai Y, Li J (2015) Core-shell structured SnO2 hollow spheres-polyaniline composites as anode for sodium-ion batteries. RSC Adv 5:31465–31471.  https://doi.org/10.1039/C5RA02834E CrossRefGoogle Scholar
  39. Zhongcheng Gong S, Karandikar X, Zhang V, Kotipalli Y, Lvov L Que (2010) Composite nanomaterial thin film-based biosensors. IEEE Sens.  https://doi.org/10.1109/ICSENS.2010.5690979 Google Scholar

Copyright information

© King Abdulaziz City for Science and Technology 2019

Authors and Affiliations

  1. 1.Nano Functional Materials Lab, Department of Nanoscience and TechnologyAlagappa UniversityKaraikudiIndia

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