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One-pot synthesis and shape control of metal selenides, sulfides and oxides with oxalic acid as the reducing reagent

  • Hua LinEmail author
  • Shijie He
  • Dingyu Liu
  • Jian Zou
  • Lu Li
  • Yanlong Ma
  • Qing Li
Original Article
  • 16 Downloads

Abstract

One specific method is often limited within the synthesis of one specific material like metal chalcogenides, the hot topics in nanomaterials since decades ago, which raises the cost of production if manufactured in industry. Here 23 compounds, including individual components and composites, have been synthesized through the same hydrothermal method with oxalic acid as the reducing reagent. What is more, shape-/composition-controlled synthesis of CdSe, vanadium oxides, and nickel sulfides have also been realized by simply controlling the amount of oxalic acid used in each synthesis. The method developed here is inspiring for the synthesis of other nanomaterials and the shape-/composition-controlled synthesis provides a simple strategy for the surfactant-free shape engineering of nanomaterials and enriches the knowledge about crystal growth.

Keywords

Metal chalcogenides One-pot synthesis Hydrothermal method Shape control 

Notes

Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities Key Project (Grant No. XDJK2017B062) and the National Science Foundation for Young Scientists of China (Grant No.51605392).

Supplementary material

13204_2019_954_MOESM1_ESM.docx (3.4 mb)
Supplementary material 1 (DOCX 3441 KB)

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Copyright information

© King Abdulaziz City for Science and Technology 2019

Authors and Affiliations

  1. 1.Faculty of Materials and EnergySouthwest UniversityChongqingChina
  2. 2.School of Chemistry and Chemical EngineeringSouthwest UniversityChongqingChina
  3. 3.College of Materials Science and EngineeringChongqing University of TechnologyChongqingChina

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