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Silver nanoparticles with reduced graphene oxide for surface-enhanced vibrational spectroscopy of DNA constituents

  • Siim Heinsalu
  • Olena Fesenko
  • Aleksei Treshchalov
  • Serhii Kovalchuk
  • Andrii Yaremkevych
  • Vladyslav Kavelin
  • Leonid Dolgov
Original Article
  • 5 Downloads

Abstract

Composite of silver nanoparticles with reduced graphene oxide flakes is proposed for surface enhanced vibrational spectroscopy, particularly for detection of adenine and thymine as constituents of deoxyribonucleic acid. Composite was formed by original method implying simultaneous reduction of silver ions and graphene oxide by discharge plasma at the gas–liquid interface. Combination of nanosized silver with reduced graphene oxide provided greater enhancement of Raman light scattering and infrared light absorption in comparison with separately used components. Addition of the composite to water solutions of adenine and thymine allowed detection of these analytes at micromolar concentrations. Composite of nano-silver with reduced graphene oxide can be prospective for surface enhanced spectroscopy as an alternative to the expensive lithographically prepared noble metal substrates.

Keywords

Surface Enhanced Raman Scattering (SERS) Surface Enhanced InfraRed Absorption (SEIRA) Silver nanoparticles Reduced graphene oxide Adenine Thymine Discharge plasma 

Notes

Acknowledgements

This work was supported by FP7 Marie Curie ILSES project no. 612620 and NATO SPS project NUKR.SFPP984702.

Supplementary material

13204_2018_924_MOESM1_ESM.docm (386 kb)
Supplementary material 1 (DOCM 386 KB)

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Copyright information

© King Abdulaziz City for Science and Technology 2018

Authors and Affiliations

  1. 1.Faculty of Science and Engineering, Waseda UniversityTokyoJapan
  2. 2.Institute of PhysicsUniversity of TartuTartuEstonia
  3. 3.Institute of PhysicsNAS of UkraineKievUkraine
  4. 4.Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen UniversityGuangzhouPeople’s Republic of China

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