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Ligand-based stoichiometric tuning in copper sulfide nanostructures and their catalytic ability

  • Mamta Jain
  • Dipak Gorakh Babar
  • Shivram S. GarjeEmail author
Original Article
  • 31 Downloads

Abstract

In this paper, we report the synthesis of copper sulfide (CuxS) nanoparticles (NPs) with different stoichiometry from different Cu(II) thiosemicarbazone complexes. The complexes were used as single-source precursors (SSPs). Solvothermal decomposition of SSPs at 198 °C temperature in the presence of ethylene glycol (EG) leads to the formation of CuxS NPs. Obtained NPs were characterized by different techniques like UV–visible and photoluminescence spectroscopy, Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). They are spherical in shape and shows good photoluminescence properties. The XRD patterns indicate that the solvothermal decomposition of different precursors results into the formation of NPs having different phases, viz., Cu2S, CuS, and mixed Cu2S/CuS. It is observed that the mixed-phase NPs show good photocatalytic activity towards degradation of Methylene Blue (MB) dye compared to other NPs. The composite of mixed Cu2S/CuS phase with carbon nanoparticles (CNPs) was prepared. It is further observed that this composite not only shows drastic increase in degradation of MB but also shows its sonocatalytic degradation.

Keywords

Thiosemicarbazone Single source precursors Copper sulphide nanoparticles Photo-catalysis Sono-catalysis 

Notes

Acknowledgements

DGB thanks to University Grants Commission, India for providing Dr. D. S. Kothari Postdoctoral Fellowship.

Compliance with ethical standards

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Supplementary material

13204_2018_915_MOESM1_ESM.doc (1.4 mb)
Supplementary material 1 (DOC 1412 KB)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of MumbaiMumbaiIndia

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