Effect of C/H and C/O ratios on the arc discharge synthesis of titanium carbide nanoparticles in organic liquids

  • Negin Rahnemai Haghighi
  • Reza PoursalehiEmail author
Original Article


TiC nanoparticles were synthesized by submerged direct current (DC) arc discharge in liquid. Synthesis process was carried out in methanol, ethanol and acetone under inert atmosphere by applying 40 A between two pure titanium electrodes with vertical configuration. X-ray diffraction, field emission scanning electron microscopy and UV–visible spectroscopy were used for characterization of nanoparticles. In addition, plasma species were characterized via optical emission spectroscopy (OES). According to the obtained results, nanoparticle shape is spherical, and average particle size of nanoparticles is 28, 45 and 38 nm in methanol, ethanol and acetone, respectively. Although composition of nanoparticles in ethanol and acetone is single-phase of TiC, the presence of around 30% of rutile phase of TiO2 was observed in methanol. According to the OES observation, TiC nanoparticle formation mechanisms are discussed based on the decomposition of organic liquids in arc discharge zone, formation of some carbon species and reaction of this carbon-containing species with Ti species in plasma. In addition, C/H and C/O ratios play a critical role in formation and dominant phase of final product. These results demonstrate a simple and flexible method for rapid mass production of TiC and other refractory metal carbides nanoparticles in an appropriate organic liquid.


TiC nanoparticles Arc discharge Organic liquids Formation mechanism Optical emission spectroscopy 



The authors would like to acknowledge the financial support received from Tarbait Modares University, through grant #IG-39703.


  1. Abdelkader EM, Jelliss PA, Buckner SW (2015) Metal and metal carbide nanoparticle synthesis using electrical explosion of wires coupled with epoxide polymerization capping. Inorg Chem 54:5897–5906. CrossRefGoogle Scholar
  2. Abdullaeva Z, Omurzak E, Iwamoto C, Okudera H, Koinuma M, Takebe S, Sulaimankulova S, Mashimo T (2013) High temperature stable WC 1–x @C and TiC@C core–shell nanoparticles by pulsed plasma in liquid. RSC Adv 3:513–519. CrossRefGoogle Scholar
  3. Ali M, Basu P (2010) Mechanochemical synthesis of nano-structured TiC from TiO2 powders. J Alloys Compd 500:220–223. CrossRefGoogle Scholar
  4. Ashkarran AA, Iraji zad A, Mahdavi SM, Ahadian MM (2010) Photocatalytic activity of ZnO nanoparticles prepared via submerged arc discharge method. Appl Phys A 100:1097–1102. CrossRefGoogle Scholar
  5. Attri P, Kim YH, Park DH, Park JH, Hong YJ, Uhm HS, Kim K-N, Fridman A, Choi EH (2015) Generation mechanism of hydroxyl radical species and its lifetime prediction during the plasma-initiated ultraviolet (UV) photolysis, Sci Rep. Google Scholar
  6. Blanksby SJ, Ellison GB (2003) Bond dissociation energies of organic molecules. Acc Chem Res 36:255–263. CrossRefGoogle Scholar
  7. Capezzuto P, Cramarossa F, D’agostino R, Molinari E (1977) The decomposition of methane, ethane, ethylene and n-butane in electrical discharges of moderate pressures. Beitr Aus Plasmaphys 17:205–220. CrossRefGoogle Scholar
  8. De Bonis A, Santagata A, Galasso A, Laurita A, Teghil R (2017) Formation of Titanium Carbide (TiC) and TiC@C core-shell nanostructures by ultra-short laser ablation of titanium carbide and metallic titanium in liquid. J Colloid Interface Sci 489:76–84. CrossRefGoogle Scholar
  9. Farajimotlagh M, Poursalehi R, Aliofkhazraei M (2017) Synthesis mechanisms, optical and structural properties of η-Al2O3 based nanoparticles prepared by DC arc discharge in environmentally friendly liquids. Ceram Int. Google Scholar
  10. Fattahi M, Mohammady M, Sajjadi N, Honarmand M, Fattahi Y, Akhavan S (2015) Effect of TiC nanoparticles on the microstructure and mechanical properties of gas tungsten arc welded aluminum joints. J Mater Process Technol 217:21–29. CrossRefGoogle Scholar
  11. Fedorov LY, Karpov IV, Ushakov AV, Lepeshev AA (2015) Influence of pressure and hydrocarbons on carbide formation in the plasma synthesis of TiC nanoparticles. Inorg Mater 51:25–28. CrossRefGoogle Scholar
  12. Flaherty DW, Hahn NT, Ferrer D, Engstrom TR, Tanaka PL, Mullins CB (2009) Growth and characterization of high surface area titanium carbide. J Phys Chem C 113:12742–12752. CrossRefGoogle Scholar
  13. Gogotsi Y, Dash RK, Yushin G, Yildirim T, Laudisio G, Fischer JE (2005) Tailoring of nanoscale porosity in carbide-derived carbons for hydrogen storage. J Am Chem Soc 127:16006–16007. CrossRefGoogle Scholar
  14. Gu Y, Chen L, Li Z, Qian Y, Zhang W (2004) A simple protocol for bulk synthesis of TiC hollow spheres from carbon nanotubes. Carbon 42:235–238. CrossRefGoogle Scholar
  15. Gulbiński W, Mathur S, Shen H, Suszko T, Gilewicz A, Warcholiński B (2005) Evaluation of phase, composition, microstructure and properties in TiC/a–C:H thin films deposited by magnetron sputtering. Appl Surf Sci 239:302–310. CrossRefGoogle Scholar
  16. Guo L, Zhang Z, Sun H, Dai D, Cui J, Li M, Xu Y, Xu M, Du Y, Jiang N (2018) Direct formation of wafer-scale single-layer graphene films on the rough surface substrate by PECVD. Carbon 129:456–461. CrossRefGoogle Scholar
  17. Järvisalo J, Saris NE (1975) Action of propranolol on mitochondrial functions effects on energized ion fluxes in the presence of valinomycin. Biochem Pharmacol 24:1701–1705. CrossRefGoogle Scholar
  18. Jiao J, Seraphin S (1998) Carbon encapsulated nanoparticles of Ni, Co, Cu, and Ti. J Appl Phys 83:2442–2448. CrossRefGoogle Scholar
  19. Kelly KL, Coronado E, Zhao LL, Schatz GC (2003) The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J Phys Chem B 107:668–677. CrossRefGoogle Scholar
  20. Kim JM, Park JS, Yun HS (2014) Microstructure and mechanical properties of TiC nanoparticle-reinforced iron-matrix composites. Strength Mater 46:177–182. CrossRefGoogle Scholar
  21. Leconte Y, Maskrot H, Herlin-Boime N, Porterat D, Reynaud C, Swiderska-Sroda A, Grzanka E, Gierlotka S, Palosz B (2005) Elaboration of SiC, TiC, and ZrC nanopowders by laser pyrolysis: from nanoparticles to ceramic nanomaterials. Glass Phys Chem 31:510–518. CrossRefGoogle Scholar
  22. Leconte Y, Maskrot H, Combemale L, Herlin-Boime N, Reynaud C (2007) Application of the laser pyrolysis to the synthesis of SiC, TiC and ZrC pre-ceramics nanopowders. J Anal Appl Pyrolysis 79:465–470. CrossRefGoogle Scholar
  23. Li X, Liu L, Ge S, Shen S, Song J, Zhang Y, Li P (2001) The preparation of Ti(C,N,O) nanoparticles using binary carbonaceous titania aerogel. Carbon 39:827–833. CrossRefGoogle Scholar
  24. Liu F, Wang W, Wang S, Zheng W, Wang Y (2007) Diagnosis of OH radical by optical emission spectroscopy in a wire-plate bi-directional pulsed corona discharge. J Electrost 65:445–451. CrossRefGoogle Scholar
  25. Lynch DW, Olson CG, Peterman DJ, Weaver JH (1980) Optical properties of Ti C x (0.64 ≤ x ≤ 0.90) from 0.1 to 30 eV. Phys Rev B 22:3991–3997. CrossRefGoogle Scholar
  26. Molina-Jordá JM (2016) Mesophase pitch-derived graphite foams with selective distribution of TiC nanoparticles for catalytic applications. Carbon 103:5–8. CrossRefGoogle Scholar
  27. Narengerile N, Nishioka H, Watanabe T (2011) Mechanisms of decomposition of organic compounds by water plasmas at atmospheric pressure. Jpn J Appl Phys 50:08JF13. CrossRefGoogle Scholar
  28. Nishioka H, Saito H, Watanabe T (2009) Decomposition mechanism of organic compounds by DC water plasmas at atmospheric pressure. Thin Solid Films 518:924–928. CrossRefGoogle Scholar
  29. Oyeyemi VB, Keith JA, Carter EA (2014) Trends in bond dissociation energies of alcohols and aldehydes computed with multireference averaged coupled-pair functional theory. J Phys Chem A 118:3039–3050. CrossRefGoogle Scholar
  30. Paramsothy M, Chan J, Kwok R, Gupta M (2012) TiC Nanoparticle addition to enhance the mechanical response of hybrid magnesium alloy. J Nanotechnol 2012: 1–9. Google Scholar
  31. Reddy KR, Sin BC, Ryu KS, Kim JC, Chung H, Lee Y (2009) Conducting polymer functionalized multi-walled carbon nanotubes with noble metal nanoparticles: synthesis, morphological characteristics and electrical properties. Synth Met 159:595–603. CrossRefGoogle Scholar
  32. Reyes-Coronado D, Rodríguez-Gattorno G, Espinosa-Pesqueira ME, Cab C, de Coss R, Oskam G (2008) Phase-pure TiO2 nanoparticles: anatase, brookite and rutile. Nanotechnology 19:145605. CrossRefGoogle Scholar
  33. Saha MC, Kabir ME, Jeelani S (2008) Enhancement in thermal and mechanical properties of polyurethane foam infused with nanoparticles. Mater Sci Eng A 479:213–222. CrossRefGoogle Scholar
  34. Saito G, Akiyama T (2015) Nanomaterial synthesis using plasma generation in liquid. J Nanomater 2015:1–21. CrossRefGoogle Scholar
  35. Sarkar D, Chu M, Cho S-J, Kim YI, Basu B (2009) Synthesis and morphological analysis of titanium carbide nanopowder. J Am Ceram Soc 92:2877–2882. CrossRefGoogle Scholar
  36. Shi X, Nguyen TA, Suo Z, Liu Y, Avci R (2009) Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating. Surf Coat Technol 204:237–245. CrossRefGoogle Scholar
  37. Sunka P, Babický V, Clupek M, Lukes P, Simek M, Schmidt J, Cernák M (1999) Generation of chemically active species by electrical discharges in water. Plasma Sources Sci Technol 8:258–265. CrossRefGoogle Scholar
  38. Taguchi T, Yamamoto H, Shamoto S (2007) Synthesis and characterization of single-phase TiC nanotubes, TiC nanowires, and carbon nanotubes equipped with TiC nanoparticles. J Phys Chem C 111:18888–18891. CrossRefGoogle Scholar
  39. Tian Y, Wu P, Wu X, Jiang X, Xu K, Hou X (2013) Corona discharge radical emission spectroscopy: a multi-channel detector with nose-type function for discrimination analysis. Analyst 138:2249. CrossRefGoogle Scholar
  40. Tian H, Huang F, Zhu Y, Liu S, Han Y, Jaroniec M, Yang Q, Liu H, Lu GQM, Liu J (2018) The development of Yolk–Shell-structured Pd&ZnO@ carbon submicroreactors with high selectivity and stability. Adv Funct Mater. Google Scholar
  41. Tilaki RM, Iraji zad A, Mahdavi SM (2006) Stability, size and optical properties of silver nanoparticles prepared by laser ablation in different carrier media. Appl Phys A 84:215–219. CrossRefGoogle Scholar
  42. Wang B, Zhang Z, Cui J, Jiang N, Lyu J, Chen G, Wang J, Liu Z, Yu J, Lin C (2017) In situ TEM study of interaction between dislocations and a single nanotwin under nanoindentation. ACS Appl Mater Interfaces 9:29451–29456. CrossRefGoogle Scholar
  43. Watanabe T, Nishioka H (2012) Role of CH, CH3, and OH radicals in organic compound decomposition by water plasmas. Plasma Chem Plasma Process 32:123–140. CrossRefGoogle Scholar
  44. Wen J, Yao Y, Shao W, Li Y, Liao X, Huang Z, Yin G (2011) Preparation of hollow TiC nanoparticles by the two-stage refluxing method. Mater Lett 65:1420–1422. CrossRefGoogle Scholar
  45. Yang T, Wei L, Jing L, Liang J, Zhang X, Tang M, Monteiro MJ, Chen Y, Wang Y, Gu S, Zhao D, Yang H, Liu J, Lu GQM (2017) Dumbbell-shaped bi-component mesoporous janus solid nanoparticles for biphasic interface catalysis. Angew Chem Int Ed 56:8459–8463. CrossRefGoogle Scholar
  46. Zhang Z, Wang Y, Frenzel J (2010) Ancient technology/novel nanomaterials: casting titanium carbide nanowires. Cryst Eng Comm 12:2835. CrossRefGoogle Scholar
  47. Zhang Z, Huo F, Zhang X, Guo D (2012) Fabrication and size prediction of crystalline nanoparticles of silicon induced by nanogrinding with ultrafine diamond grits. Scr Mater 67:657–660. CrossRefGoogle Scholar
  48. Zhang Z, Wang B, Kang R, Zhang B, Guo D (2015) Changes in surface layer of silicon wafers from diamond scratching. CIRP Ann 64:349–352. CrossRefGoogle Scholar
  49. Zhang Z, Wang B, Zhou P, Guo D, Kang R, Zhang B (2016a) A novel approach of chemical mechanical polishing using environment-friendly slurry for mercury cadmium telluride semiconductors. Sci Rep 6:22466. CrossRefGoogle Scholar
  50. Zhang Z, Wang B, Huang S, Wen B, Yang S, Zhang B, Lin CT, Jiang N, Jin Z, Guo D (2016b) A novel approach to fabricating a nanotwinned surface on a ternary nickel alloy. Mater Des 106:313–320. CrossRefGoogle Scholar
  51. Zhang Z, Wang B, Zhou P, Kang R, Zhang B, Guo D (2016c) A novel approach of chemical mechanical polishing for cadmium zinc telluride wafers. Sci Rep 6:26891. CrossRefGoogle Scholar
  52. Zhang Z, Shi Z, Du Y, Yu Z, Guo L, Guo D (2018) A novel approach of chemical mechanical polishing for a titanium alloy using an environment-friendly slurry. Appl Surf Sci 427:409–415. CrossRefGoogle Scholar
  53. Zhang Z, Cui J, Zhang J, Liu D, Yu Z, Guo D (2019) Environment friendly chemical mechanical polishing of copper. Appl Surf Sci 467:5–11. CrossRefGoogle Scholar

Copyright information

© King Abdulaziz City for Science and Technology 2019

Authors and Affiliations

  1. 1.Department of Materials EngineeringTarbiat Modares UniversityTehranIran

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