Detection of hydrocarbon microseepage-induced anomalies by spectral enhancements of Landsat 7 ETM+ images in part of Assam–Arakan Fold Belt, India
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Subsurface hydrocarbon traps are not correctly sealed, and hydrocarbons move vertically from the reservoir as invisible traces in the form of microseepages. Long-term hydrocarbon microseepages cause surface or near-surface alterations such as bleaching of red beds, enrichment of ferrous iron minerals and higher concentrations of clay and carbonate minerals in soils/rocks. Multi- and hyperspectral remote sensing data have successfully been used to detect such alterations in many parts of the world. In India, such studies have not been carried out till now. In this study, Landsat 7 ETM+ images have been used to find out hydrocarbon microseepage-bearing areas in part of Assam–Arakan Fold Belt in the northeastern part of India. Based on the spectral characteristics of the hydrocarbon microseepage-induced altered minerals, two spectral enhancement techniques, viz. principal component analysis (PCA) and band ratio analysis, have been carried out on the Landsat 7 ETM+ images. PCA reveals that three principal component images—1457PC3, 1345PC2 and 3457PC4—show relatively better enhancement for the hydrocarbon-bearing alteration areas. Again, band ratio analysis of the images indicates that ratio images—3/1, (2 + 5)/(3 + 4) and 7/5—show excellent spectral enhancement for the hydrocarbon-induced mineral alterations. The three PC images have been combined with the three band ratio images to find out probable hydrocarbon microseepage areas. The remote sensing-derived prospect areas have been validated with surface geochemical, seismic/geologic and gravity data available in the area.
KeywordsHydrocarbon microseepage Landsat 7 ETM+ images Spectral enhancement Principal component Band ratio Exploration
Hydrocarbon accumulations in the subsurface reservoirs are sealed by some impermeable cap rocks such as shale and evaporite. However, these caps as well as the overlying rock successions are not purely impervious in nature and the trapped hydrocarbons move vertically or near-vertically to the surface in the form of microseepages which are slow and invisible but widespread in nature (Etiope 2015; Price 1986; Schumacher 1999). The presence of microseepages is confirmed by the geochemical analyses of adsorbed or headspace gases extracted from surface soil/rock samples (Horvitz 1985; Tedesco 1995). The importance of occurrence of microseepages lies in the fact that they indicate the presence of hydrocarbons beneath the surface. Schumacher (2017) concluded that hydrocarbon microseepage study in combination with other conventional techniques can contribute substantially in fixing potential targets for exploration and thereby increases the chances of discovering new pools in unexplored areas with drastic reduction of exploration costs. In fact, many of the world’s great hydrocarbon reservoirs have been discovered by tracking the occurrence of microseepages on the surface.
It has long been observed that hydrocarbon microseepages create a reducing environment which induces several chemical and mineralogical changes in the rock or soil cover overlying the petroleum reservoirs (Price 1986, Tedesco 1995, Schumacher 1996, Saunders et al. 1999, Etiope and Martinelli 2002, Warren 2012). Satellite-based remote sensing holds a greater promise as a rapid and cost-effective means of detecting these anomalous diagenetic changes on the surface cover. Spectral remote sensing data have been successfully used in many parts of the world to detect the following three main types of hydrocarbon-induced mineralogical alterations: (1) bleaching of red beds: discoloration of red soils/rocks due to the chemically removal of ferric iron (Fe3+) and an increase in ferrous iron (Fe2+) content. Common ferric iron minerals in rocks and soils include hematite, goethite and limonite; (2) formation of clay minerals: development of clay minerals by the alteration of feldspars or micas; and (3) precipitation of carbonate minerals: formation of diagenetic carbonate minerals such as calcite or siderite as a byproduct of petroleum oxidation (Schumacher 1996; Asadzadeh and de Souza Filho 2017).
In the present study, Landsat 7 Enhanced Thematic Mapper Plus (ETM+) data have been used to detect the hydrocarbon microseepage-induced geochemical alterations of minerals present on the surface rocks/soils in part of Assam–Arakan Fold Belt (AAFB), northeast India. Two strong spectral enhancement techniques, viz. principal component analysis (PCA) and band indices on the six bands of Landsat 7 ETM+ (bands 1, 2, 3, 4, 5 and 7) in the visible, near-infrared and shortwave-infrared (VNIR and SWIR) wavelength region of the electromagnetic spectrum, have been used to figure out the potential areas of hydrocarbon-induced mineral alterations. The principal component (PC) and the band index images showing relatively better spectral enhancements for the said mineral alterations have been superimposed, and the most probable areas for hydrocarbon microseepages have been delineated. These delineated prospective areas for hydrocarbon occurrence have been validated with the surface geochemical, seismic, geologic and gravity studies.
Landsat data collection and preparation
Landsat 7 ETM+ image data for the study area were thoroughly searched, and a low cloud cover scene with path/row 136/043 acquired on 19-12-1999 was downloaded from www.earthexplorer.usgs.gov.in. The image acquisition time was so selected because during this time the weather of the region becomes dry and cold and also the growth of vegetation becomes minimum. The scene was in UTM projection (Zone + 46) and in 30-m spatial resolution.
The Landsat 7 ETM+ images were processed in Erdas Imagine and ArcGIS software. As the images were already geometrically corrected, no further correction was required. The study area was subset from the images with the co-ordinates 24°31′22.21″N/24°57′5.12″N and 92°37′37.89″E/93°07′23.59″E. Considering the difficulties in identifying mineral alterations in areas of dense vegetation and water bodies, these areas were converted into zero-pixel values using supervised classification.
Spectral image enhancements The following two powerful spectral enhancements have been carried out on the Landsat 7 ETM+ band images:
Principal component analysis (PCA)
Principal component analysis (PCA) is a statistical tool to identify patterns of similarities and differences from a dataset of high dimensions. The technique extracts information of variance by reducing the number of dimensions without much loss of information in the original dataset. In the field of remote sensing, PCA is widely used as an image enhancement tool to find out the amount of variance related to a particular feature from among two or more spectral band images. As the numbers of dimensions are significantly reduced in PCA, the resultant images become more informative and clear to visualize features which are difficult to identify in the original images. The first principal component (PC1) image represents the greatest amount of variability among the input images followed by the remaining amount of variability as second, third and so on (PC2, PC3….). Eigenvectors in PCA define the linear combinations of weighted input of images in the principal components, and the eigenvalues represent the measures of variance for a particular factor. Low eigenvalues indicate insignificant variance, and too low values are therefore sometimes ignored for analysis. The loadings in PCA are the correlation coefficients between the PC image and the input images. It is a measure of the importance (weight) of each input spectral band to the particular PC image (Sabins 1999; Gupta Ravi et al. 2013). Crosta technique of PCA has been used in the present study. This is a selective PCA which takes only those bands as input which are spectrally relevant to a specific target. It is, therefore, the target objects are mapped more elegantly and unequivocally in the resultant PC images. The Crosta PCA takes into account both the magnitude and sign of the eigenvector loadings to select only the relevant PC images (Loughlin 1991; Tangestani and Moore 2002).
Out of the six Landsat 7 ETM+ bands (bands 1, 2, 3, 4, 5 and 7), based on the characteristics spectral absorption features of the minerals associated with hydrocarbon microseepages, four bands were taken at a time for PCA composition. Thus, there were a total of 6C4, i.e., 15 different compositions. Among these, the PC images showing relatively better spectral enhancements have been selected for finding out the prospective areas of hydrocarbon microseepages.
- a.PC image indicating bleaching of red beds: Ferric iron (Fe3+) minerals show characteristics deep charge-transfer absorption in Landsat 7 ETM+ band 1, crystal field absorption in band 4 (near infrared) and reflectance in bands 3, 5 and 7 (Hunt 1977, Clark 1999; Rockwell 2013). These spectral properties have been used to find out areas of reduced concentration of ferric iron-bearing minerals by PCA. The principal component analysis reveals that the third PC image on bands 1, 4, 5 and 7 (1457PC3) displays the best spectral enhancement for ferric iron minerals (Fig. 4). As evident from Table 1, in PC image 1457PC3, the eigenvector loadings for bands 1 and 4 are negative (− 0.872 and − 0.053), while for band 5 and band 7 are positive (0.485 and 0.046). Therefore, ferric iron-rich areas in the PC image 1457PC3 appear as bright and ferric iron-poor, i.e., the bleached areas appear as dark pixels.Table 1
Eigenvector and eigenvalues of PCA on bands 1, 4, 5 and 7
Landsat 7 ETM+ band
- b.PC image showing the presence of ferrous iron (Fe2+) minerals: The presence of acidic or reducing agents in hydrocarbon microseepage-bearing areas favors the formation of ferrous iron (Fe2+) minerals such as pyrite, siderite, pyrrhotite and ferrihydrate by the reduction of ferric iron minerals (Schumacher 1996, Meer et al. 2002). Ferrous iron increases total reflected radiance in Landsat 7 ETM+ bands 1 and 3 and shows a broad absorption in band 4 (Meer et al. 2002, Zhang et al. 2011) and a falloff in reflectance from band 7 to band 5 (Liu 2000). These spectral characteristics have been used to detect ferrous iron-bearing areas in the principal component images. Principal component analysis indicates that the second PC image on bands 1, 3, 4 and 5 (1345PC2) produces relatively better enhancement for ferrous iron minerals (Fig. 5). In this image, the eigenvector loading for band 4 is positive (+ 0.947) and eigenvector loadings for bands 1, 3 and 5 are − 0.196, − 0.190 and − 0.168, respectively (Table 2). Therefore, ferrous iron-bearing areas will be represented as dark or low pixel values in this PC image. It is also to be noted that the brighter areas in this PC image are dominated by vegetation as revealed by the highly positive eigenvector loading for band 4.Table 2
Eigenvector and eigenvalues of PCA on bands 1, 3, 4 and 5
Landsat 7 ETM+ band
- c.PC image indicating clay and carbonate mineral abundances: Clay and carbonate minerals exhibit diagnostic absorption features in Landsat 7 ETM+ band 7 and high reflectance in band 5 (Hunt 1977; Goetz and Rowan 1983). Principal component analysis containing bands 5 and 7 shows that the fourth PC image on bands 3, 4, 5 and 7 (3457PC4) has good spectral enhancement for clay and carbonate minerals (Fig. 6). In this PC image, the eigenvector loadings for band 7 and band 5 are 0.878 and − 0.372, respectively (Table 3). As the eigenvector loadings for band 7 and band 5 are positive and negative, respectively, clay and carbonate mineral abundance in this PC image will appear as dark or low pixel values.Table 3
Eigenvector and eigenvalues of PCA on band 3, 4, 5 and 7
Landsat 7 ETM+ band
Band ratio analysis
Band arithmetic is one of the robust tools in enhancing remote sensing images. Band ratio analysis is very effective to highlight some selective features and has been used widely in geology as well as hydrocarbon microseepage detection (Abrams et al. 1983; Abrams 1984; Sabins 1997; Almeida-Filho et al. 1999, 2002; Tangestani and Moore 2000; Meer et al. 2002; Kariuki et al. 2004; Zhang et al. 2007, 2009, 2011). Based on the spectral characteristics (especially the absorption features) of hydrocarbon microseepage-induced mineralogical alterations, three band ratios have been calculated:
- a.Ferric iron (Fe3+) index: Landsat 7 ETM+ band 3/band 1 ratio is the standard index for ferric iron minerals. Higher values (brighter areas) in the index image represent ferric iron-bearing areas, while ferric iron-poor areas are represented by darker pixels. It is therefore, areas characterized by bleaching of red beds are represented by relatively darker or lower pixels values in this band ratio image. The ferric iron index band ratio image for the study area is shown in Fig. 7.
- b.Ferrous iron (Fe2+) index: Landsat 7 ETM+ compound band ratio (2 + 5)/(3 + 4) described by Rockwell (2013) has been used to indicate ferrous iron-bearing areas. Higher pixel values in the image represent areas of ferrous iron-bearing minerals. The ferrous iron index image of the study area is shown in Fig. 8.
- c.Clay and carbonate minerals index: The ratio index of band 7/band 5 has been used to find out clay and carbonate-bearing areas in the area under study. Clay and carbonate-bearing areas in the index image are represented by low pixel values. The band ratio image displaying distribution of clay and carbonate minerals for the area is shown in Fig. 9.
Hydrocarbon prospect identification
Validation of the remote sensing analysis through surface geochemical, seismic/geologic and gravity data
Surface geochemical studies
Adsorbed gas analysis of samples from hydrocarbon microseepage prospect and non-prospect regions
Microseepage prospective zones
Microseepage prospective zones
Total C2–C5 (ppm)
Total C2–C5 (ppm)
Total C2–C5 (ppm)
Table 4 clearly shows that 21 out of 37 (57%) prospect areas and 2 out of 8 (25%) non-prospect areas contain C2–C5 components of hydrocarbon. Therefore, it is evident that majority of the remote sensing-derived prospect areas are hydrocarbon microseepage-bearing.
In the present study, remote sensing-based spectral enhancements of Landsat 7 ETM+ images have been used to identify hydrocarbon microseepage-induced mineral alterations, viz. bleaching of red beds, enrichment of ferrous iron, clay and carbonate minerals in surface soils/rocks in part of a petroleum-producing basin. Principal component and band ratio analyses reveal that PC images—1457PC3, 1345PC2, 3457PC4—and band index images—3/1, (2 + 5)/(3 + 4) and 7/5—exhibit good spectral enhancements for the hydrocarbon microseepage-induced alterations. Adsorbed gas analysis for lighter hydrocarbons (C2–C5) confirms that majority of the prospect areas derived by remote sensing studies contain hydrocarbon microseepages. Seismic, geologic and gravity data also support the presence of hydrocarbon-bearing structures on the remote sensing-based prospect areas. This study, therefore, reinforces the concept of remote sensing-based detection of hydrocarbon microseepage-induced alterations in surface soils/rocks in a petroliferous basin characterized by heavy rainfall and substantiates the potential use of remote sensing in minimizing exploration risks. Therefore, it can be concluded that remote sensing mineral alteration mapping can be used effectively to narrow down the search areas for hydrocarbons at the initial stage of exploration. Nevertheless, it is important to remember that remote sensing is only an aid in hydrocarbon exploration and the success of exploration becomes high when remote sensing study is integrated with conventional geophysical techniques like seismics, gravity, magnetics, etc.
The authors are grateful to the Department of Applied Geology, Indian Institute of Technology (Indian School of Mines), Dhanbad, for providing necessary infrastructural facilities to carry out the laboratory studies. The authors also express their deep gratitude to the anonymous reviewers for their critical comments and reviews. The views expressed in this article are of the authors own and do not represent the organizations they belong.
Compliance with ethical standards
Conflict of interest
The authors declare that they have no conflict of interest.
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