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Composite Electrode Material Based on Electrochemically Reduced Graphene Oxide and Gold Nanoparticles for Electrocatalytic Detection of Ascorbic Acid

  • Arpad Szoke
  • Zoltan Zsebe
  • Graziella Liana TurdeanEmail author
  • Liana Maria MuresanEmail author
Original Research

Abstract

A nanostructured composite matrix containing gold nanoparticles (AuNPs), graphene oxide (GO), and Nafion was immobilized on the surface of a glassy carbon electrode (GCE) by drop casting. The GO was electrochemically reduced (erGO), in order to obtain a modified interface (GCE/AuNPs-erGO-Nafion) able to detect l-ascorbic acid (AA) at lower oxidation potentials with increased sensitivity. The obtained modified electrode was investigated by cyclic voltammetry, electrochemical impedance spectroscopy (EIS), and amperometry. The corroborated results showed that erGO and AuNPs at the interface act as a unique material having both high surface area (due to erGO) and high conductivity (due to AuNPs), being an effective electron transfer promoter in the electro-oxidation process of AA, lowering the oxidation potential of AA by ca. 0.400 V vs. Ag/AgCl,KClsat. The analytical parameters for AA detection at the modified GCE/AuNPs-erGO-Nafion electrode were determined by amperometry with a sensitivity of 39.07 ± 1.36 μA/mM and a detection limit of 2.76 μM AA (signal/noise ratio of 3). The GCE/AuNPs-erGO-Nafion-modified electrode is simple to prepare, reliable, and with high sensitivity and was applied successfully in the routine analysis of AA in pharmaceutical products.

Graphical Abstract

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Keywords

Electrochemically reduced graphene oxide Gold nanoparticles l-ascorbic acid 

Notes

Acknowledgments

The authors thank Dr. Katona Gabriel for the TEM measurements.

Supplementary material

12678_2019_543_MOESM1_ESM.doc (396 kb)
ESM 1 (DOC 395 kb)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Faculty of Chemistry and Chemical Engineering, Department of Chemical Engineering, Research Center of Electrochemistry and Non-Conventional Materials“Babeș Bolyai” UniversityCluj-NapocaRomania

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